CAS: 10294-28-7; Gold(Iii) Bromide

该化合物是一种无机化合物,其特点是在+3氧化状态下形成黄金,其性质似乎是深褐或黑的固体,以其反应性而著称,特别是在水分可导致水解的情况下.金三溴化物通常通过黄金与溴在高温下的反应合成.它溶解于有机溶剂中,但溶解于水中.该化合物在各种化学应用中都有意义,包括催化和其他金化合物的前体.其特性包括一个相对较高的熔点,以及能够与各种离心化合物形成复合体.由于其反应性,处理金三溴化物需要谨慎行事,因为它在脱腐时会释放有毒的溴蒸气.总的来说,金三溴化物是协调化学和材料科学领域的一个重要化合物.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号7440-57-5 金 | CAS号50960-82-2 氯羰基金(I) | CAS号7726-95-6 溴素 | CAS号13453-07-1 三氯化金 | CAS号7789-61-9 溴化锑(III) | CAS号7789-69-7 五溴化磷 | CAS号7726-95-6 溴素 | CAS号134789-10-9 bromomethanone,... | CAS号7440-57-5 金

合成工艺路线路线简述

    📜金置于溴体系中,用 乙醚 用作溶剂,化学反应生成溴化金
    参考文献:Doering,T.,1900,Vol. 59,P. 49-51
    标题:Doering,T.,1900,Vol. 59,P. 49-51

    专利信息


    专利号:US-8641798-B2
    优先权日:2010-07-13
    标 题 :One-step synthesis of monodisperse AU-CU nanocubes
    发明人:HIGHT-WALKER ANGELA R; LIU YONGLIN
    权利人:HIGHT-WALKER ANGELA R; LIU YONGLIN; US OF AMERICA AS REPRESENTED BY THE SECRETARY OF COMMERCE NIST
    摘要:A one-step process for synthesizing gold-copper bimetallic nanocubes. The process comprises the step of simultaneously reducing a copper II salt and a gold halide by 1,2-hexadecanediol in diphenyl ether, and 1-dodecanethiol as well as surfactants 1-adamantanecarboxylic acid and 1-hexadecylamine. The copper II salt may be copper (II) acetylacetonate, copper chloride, copper sulfate, or copper phosphate. The gold halide may be chloroauric acid, gold chloride, gold bromide, or tetrabromoauric acid. The reduction may occur at a temperature between about 160 and 180 degrees Celsius. The copper II salt may be copper (II) acetylacetonate and the gold halide may be chloroauric acid.

    专利号:US-10758983-B1
    优先权日:2018-04-17
    标题:Concentrated synthesis of monodispersed gold nanorods
    发明人:VAIA RICHARD A; PARK KYOUNGWEON
    权利人:US GOV AIR FORCE
    摘要:A method for synthesizing nanostructures includes introducing a solution of seed crystals into an initial growth solution to form a nanostructure synthesis mixture. The initial growth solution includes a precursor material and a reducing agent in a surfactant solution. Growth of nanostructures in the nanostructure synthesis mixture is monitored during a period of anisotropic growth of the nanostructures to determine a shift from stage II growth of the nanostructures to stage III growth of the nanostructures. The shift from stage II growth to stage III growth is identified, and after identifying the shift, a second growth solution is added to the nanostructure synthesis mixture coincident in time with the shift. The second growth solution includes the precursor material and the reducing agent in the surfactant solution.

    专利号:US-9822053-B2
    优先权日:2016-01-28
    标题:Single step conversion of N-butyraldehyde to 2-ethylhexanal
    发明人:BOPPANA Venkata Bharat; HAMPTON JR KENNETH WAYNE; LIU ZHUFANG; SUMNER JR CHARLES EDWAN; TUSTIN GERALD C; STEINMETZ GUY RALPH; STEFFEY MELISSA PAGE
    权利人:EASTMAN CHEM CO
    摘要:Disclosed is a method of making and using a titania supported palladium catalyst for the single step synthesis of 2-ethylhexanal from a feed of n-butyraldehyde. This titania supported palladium catalyst demonstrates high n-butyraldehyde conversion but also produces 2-ethylhexanal in an appreciable yield with maintained activity between runs. This method provides a single step synthesis of 2-ethylhexanal from n-butyraldehyde with a catalyst that can be regenerated that provides cleaner downstream separations relative to the traditional caustic route.

    专利号:EP-0530187-B1
    优先权日:1990-05-01
    标 题 :Synthesis of dialkyl gold (iii) beta-diketonates

    专利号:WO-9117167-A1
    优先权日:1990-05-01
    标题 :Synthesis of dialkyl gold (iii) beta-diketonates

    专利号:US-5023360-A
    优先权日:1990-05-01
    标题:Simplified synthesis of dialkylgold(III) β-diketonates
    发明人:BAUM THOMAS H; BROCK PHILLIP J; DAWSON DANIEL J
    权利人:IBM
    摘要:Dialkyl gold(III) β-diketonates are synthesized in a two-step, one-pot process using a gold trihalide, an alkyl lithium compound and a β-diketone.

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Gandon, V.; Thorimbert, S.; Malacria, M., Science of Synthesis, (2009) 46, 206.
    摘要:Hopkinson, M. N.; Gouverneur, V., Science of Synthesis Knowledge Updates, (2011) 2, 106.
    摘要:Qian, D.; Zhang, J., Science of Synthesis Knowledge Updates, (2017) 1, 8.
    摘要:Qian, D.; Zhang, J., Science of Synthesis Knowledge Updates, (2017) 1, 2.
    摘要:Celik, I.; Hummel, S.; Kirsch, S. F., Science of Synthesis Knowledge Updates, (2019) 1, 45.
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