CAS: 15545-48-9; Chlorotoluron

该化合物是一种选择性的,系统的除草剂,属于苯尿素类,主要用于对谷物作物(如小麦和大麦)中的年青草和大叶杂草进行出血前和出血后控制,其作用方式是干扰光电系统II的电子运输,从而抑制光合作用.氯甲草胺因其残留活动,提供扩大的除草控制及其与综合虫害管理系统的兼容性而受到重视.它通过微生物活动表现出适度的土壤流动性和降解,最大限度地减少长期环境持久性.该化合物对黑草和小麦等主要杂草品种有效,使其成为可持续作物保护的可靠选择.适当应用可以确保谷物在管理抗药风险时具有选择性.

结构式图片

相似化合物

587-34-8 330-54-1 13142-64-8

欧盟法规

统一分类与标签ECHA物质工作场所安全标识要求ECHA物质化妆品禁用物质清单C&L通报食品接触材料-禁用CMR物质欧盟农药活性物质REACH预注册废弃物危险特性清单

上下游产品

CAS号28479-22-3 3-氯-4-甲基苯基异氰酸酯 | CAS号124-40-3 二甲胺 | CAS号74-89-5 氨基甲烷 | CAS号13142-64-8 Urea,(3-chloro-... | CAS号22175-22-0 1-(3-氯-4-甲基)-3-甲基尿素 | CAS号59587-00-7 N'-(3-chloro-4-... | CAS号59587-03-0 N'-(3-chloro-4-... | CAS号59587-01-8 2-氯-4-[(二甲基氨基甲酰... | CAS号124-40-3 二甲胺 | CAS号95-74-9 3-氯对甲苯胺 | CAS号7260-94-8 dimethylcarbami... | CAS号28479-22-3 3-氯-4-甲基苯基异氰酸酯

合成工艺路线路线简述

    3-氯-4-甲基苯基异氰酸酯,二甲基-D6-胺盐酸盐置于三乙胺体系中,用 1,4-二氧六环 用作溶剂,化学反应 16.33H,以86%的收率获得绿麦隆
    参考文献:苯脲类除草剂或氘代标记的苯脲类除草剂的 合成方法
    标题:苯脲类除草剂或氘代标记的苯脲类除草剂的 合成方法
    摘要:本发明涉及一种苯脲类除草剂或氘代标记的苯脲类除草剂(式(I)化合物)的合成方法,所述式(I)化合物由式(II)化合物在有机碱存在时与二甲胺盐或d6‑二甲胺盐反应获得.该合成方法避免了取代的苯基异氰酸酯与水或醇发生的副反应,减少了二甲胺或二甲胺‑d6的泄露,操作简单,对设备要求低,成本低,收率高,副产物少.

    海关参考信息

    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:US-11919928-B2
    优先权日:2016-03-16
    标题 :Method for producing dihydrotentoxin
    发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
    权利人:KUMIAI CHEMICAL INDUSTRY CO
    摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

    专利号:ES-2717283-T3
    优先权日:2012-07-24
    标 题:Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and herbicides inhibitors of VLCFA synthesis and synthesis of fatty acids / lipids
    厦门优孚利生物医药科技有限公司
    ⚠️ 未注册 · 未认证企业
    ⚠️ 该商家尚未完成注册及企业认证,请用户仔细辨别,谨慎交易。
    数据来源于公开网络搜索,平台未作核实,请自行辨别。
    🏢敬请 企业认领
    🏬开设公司展台
    📢获取免费会员权益
    🎖️点亮专属注册企业标签
    📇展现公司完整信息 样本查看立即注册认领 →
    网址: http://www.ufreechem.com
    企业联系电话:0592-6519005👤
    📞厦门优孚利生物医药科技有限公司 ⚠️参考联系方式
    联系人:林经理
    电话:0592-6519005
    手机:18030020027;13616030264
    传真:0592-6519005
    邮箱:U-FREE2018@ufreechem.com
    通信地址: 厦门市海沧区新园路120号3层01单元
    邮编:
    🆔 联系时候可告知是从"百琢研"平台获取的信息.
    ⚠️ 声明: 该企业未认证、未认领,请自行辨别信息的真实性和可靠性。咨询或交易时请注意风险评估与信息核实,百琢研不参与任何交易。企业认领注册入口→

    地址:厦门市海沧区新园路120号3层01单元
    ⚠️ 未注册 · 未认证企业
    注册入口 备注: 📌 数据来源说明:本展台内容基于各搜索引擎等公开数据整理,仅作展示用途。请用户自行辨别
    ✉️ 若企业需抹除展台内容或有异议, 请通过页面底部联系方式告知我们,我们会尽快处理。
    第 1 / 1 页

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Bányiová K, Čupr P, Kohoutek J. An experimentally refined tool to assess the risks of the human dermal exposure to herbicide chlorotoluron. Environ Sci Pollut Res Int. 2015 Jul;22(14):10713-20. doi: 10.1007/s11356-015-4252-x. Epub 2015 Mar 11. doi: 10.1016/j.pestbp.2013.12.003. Epub 2014 Jan 3. doi: 10.1002/ps.3377. Epub 2012 Aug 27. doi: 10.1002/etc.341. Epub 2010 Oct 7. doi: 10.1002/jssc.200900444. doi: 10.1016/j.envpol.2009.09.019. Epub 2009 Oct 12. doi: 10.1016/j.envpol.2009.04.019. Epub 2009 May 22. doi: 10.1007/s00128-008-9430-9. Epub 2008 Apr 10. doi: 10.1080/15376510701533921. Epub 2007 Apr 25. doi: 10.1080/15376510601166384. doi: 10.1007/s001220050380.

    合成参考文献


    摘要:Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel, Perkow, W., Berlin, Verlag Paul Parey, 1971-1976, -(-), 1971/1976
    摘要:Khigiena i Zdraveopazvane. Hygiene and Sanitation., 22(362), 1979
    摘要:Tomlin C; The Pesticide Manual. 10th ed. Bath, UK: The Bath Press. p. 196 (1994)
    摘要:Kearney, P.C., and D. D. Kaufman (eds.) Herbicides: Chemistry, Degredation and Mode of Action. Volumes 1 and 2. 2nd ed. New York: Marcel Dekker, Inc., 1975., p. 237
    摘要:Hartley, D. and H. Kidd (eds.). The Agrochemicals Handbook. Old Woking, Surrey, United Kingdom: Royal Society of Chemistry/Unwin Brothers Ltd., 1983., p. A094/Oct 83
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知