CAS: 940-61-4; (E)-3-(P-Tolyl)Acrylic Acid
该化合物是一种有机化合物,其特征为丙烯酸结构,其特点是一个乙烯基组和一个碳酸功能组,该化合物一般是无色的,可粉黄,具有一种特质的气味,在有机溶剂中可溶解,水溶解度有限.(E)配置表明,双联产周围的替代成分在对面,可影响其再活动性和物理特性. 2-丙烯酸,3-4-甲基苯基,用于各种用途,包括在聚合合成中用作单聚物,特别是在涂料,粘合剂和塑料的生产中.它的活性允许它参与聚合反应,使其在具有特定机械和热特性的材料的开发过程中具有价值.此外,它可能在有机合成领域应用,并作为其他化学化合物制造的中间体.在进行这种处理时,应当采取安全防范措施.
物理性质
上下游产品
acetic anhydride 4-methyl-benzaldehyde 2-Iodo-3-p-tolyl-propionic acid methyl ester para-bromotoluene [4-(3-p-Tolyl-propionylamino)-phenoxy]-acetic acid N-((E)-2-p-Tolyl-vinyl)-formamide p-tolyl-isoxazolidin-5-one2-hydroxy-3-p-tolyl-isoxazolidin-5-one 3-hydroxy-3-(4'-methylphenyl)propionic acid合成工艺路线路线简述
- 624-31-7 = 940-61-4
反应条件:1.1 Reagents: Triethylamine Catalysts: Palladium (Complexes With [(Aminoethyl)Amino]Cellulose) Solvents: Water; 6 H,80 °C
标题:Preparation Of Palladium Complex Supported By Ethylenediamine Cellulose And Its Catalytic Behavior For Heck Reaction
作者:Xu,Ying; Zhao,Qinglan; Zhang,Lei; Jin,Jinghua; Cui,Yuanchen
参考文献:Huaxue Yanjiu 日期:2008 卷标:19(4) 页码:73-77]
624-31-7 = 940-61-4
反应条件:1.1 Reagents: Triethylamine Catalysts: Ethylenediamine,Palladium,Polyacrylonitrile; 20 Min,120 °C
标题:Functional Fiber With Bis (N-Heterocyclic Carbene) Structure Prevents Pd(0) Nanoparticle Agglomeration For An Efficient And Recyclable Heck Reaction
作者:Zhang,Haonan; Liang,Wenlong; Xiao,Jian; Zhao,Jinhao
参考文献:Chemical Engineering Journal (Amsterdam 日期:2023 卷标:455]
76557-94-3 = 940-61-4
反应条件:1.1 Reagents: Triethylamine Catalysts: Dichlorobis(Triphenylphosphine)Palladium Solvents: Water,1-Butyl-3-Methylimidazolium Hexafluorophosphate; 10 H,20 Bar,100 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; Acidified
标题:Stereoselective Hydroxycarbonylation Of Vinyl Bromides To α,β-Unsaturated Carboxylic Acids In The Ionic Liquid [bmim]Pf6
作者:Zhao,Xiaodan; Alper,Howard; Yu,Zhengkun
参考文献:Journal Of Organic Chemistry 日期:2006 卷标:71(10) 页码:3988-3990]
141-82-2 + 104-87-0 = 940-61-4
反应条件:1.1 Reagents: Pyridine Solvents: Dimethylformamide; 3 - 12 H,90 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; Ph 1,0 °C
标题:Copper-Catalyzed Aerobic Aminooxygenation Of Cinnamyl N-Alkoxycarbamates Via Substrate-Promoted Catalyst Activation
作者:Mcnichol,Caitlyn P.; Decicco,Ethan M.; Canfield,Amanda M.; Carstairs,Daniel P.; Paradine,Shauna M.
参考文献:Acs Catalysis 日期:2023 卷标:13(10) 页码:6568-6573]
141-82-2 + 104-87-0 = 940-61-4
反应条件:1.1 Catalysts: Piperidine Solvents: Pyridine; 85 °C; 6 H,85 °C; 85 °C -> Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; Neutralized,Cooled
标题:Synthesis And Bioactivities Of Novel Piperazine-Containing 1,5-Diphenyl-2-Penten-1-One Analogues From Natural Product Lead
作者:Xu,Gaofei; Yang,Xinling; Jiang,Biaobiao; Lei,Peng; Liu,Xili; Et Al
参考文献:Bioorganic & Medicinal Chemistry Letters 日期:2016 卷标:26(7) 页码:1849-1853]
141-82-2 + 104-87-0 = 940-61-4
反应条件:1.1 Catalysts: Lithium Chloride; 6 Min
标题:Microwave-Assisted Solvent-Free Synthesis Of Trans-Cinnamic Acids Using Lithium Chloride As Catalyst
作者:Mogilaiah,K.; Reddy,G. Randheer
参考文献:Synthetic Communications 日期:2004 卷标:34(2) 页码:205-210]
141-82-2 + 104-87-0 = 940-61-4
反应条件:1.1 Reagents: Ammonium Acetate1.2 Reagents: Water
标题:Non Solvent Reaction: Ammonium Acetate Catalyzed Highly Convenient Preparation Of Trans-Cinnamic Acids
作者:Kumar,H. M. Sampath; Subbareddy,B. V.; Anjaneyulu,S.; Yadav,J. S.
参考文献:Synthetic Communications 日期:1998 卷标:28(20) 页码:3811-3815]
141-82-2 + 104-87-0 = 940-61-4
反应条件:1.1 Catalysts: Piperidine Solvents: Pyridine; Overnight,115 °C; 115 °C -> Rt1.2 Reagents: Water; Cooled1.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 3 - 4
标题:Synthesis And Biological Evaluation Of N-(4-Phenylthiazol-2-Yl)Cinnamamide Derivatives As Novel Potential Anti-Tumor Agents
作者:Luo,Yong; Zhu,Yongxia; Ran,Kai; Liu,Zhihao; Wang,Ningyu; Et Al
参考文献:Medchemcomm 日期:2015 卷标:6(6) 页码:1036-1042]
624-31-7 = 940-61-4
反应条件:1.1 Reagents: Tributylamine Catalysts: Palladium Solvents: Dimethylformamide; 7 H,90 °C; 90 °C -> Rt1.2 Reagents: Sodium Carbonate Solvents: Water; 20 Min,Rt1.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 1 - 2,Rt
标题:Preparation Of Pd Nanoparticles Deposited On A Polyaniline/multiwall Carbon Nanotubes Nanocomposite And Their Application In The Heck Reaction
作者:Nie,Guangrui; Zhang,Lei; Cui,Yuanchen
参考文献:Reaction Kinetics 日期:2013 卷标:108(1) 页码:193-204]
141-82-2 + 104-87-0 = 940-61-4
反应条件:1.1 Catalysts: Dabco Solvents: Dimethylformamide; 75 Min,100 - 110 °C
标题:A Simple And Straightforward Synthesis Of Cinnamic Acids And Ylidene Malononitriles Via Knoevenagel Condensation Employing Dabco As Catalyst
作者:Nagalakshmi,K.; Diwakar,B. S.; Govindh,B.; Reddy,P. Gopal; Venu,R.; Et Al
参考文献:Asian Journal Of Chemistry 日期:2017 卷标:29(7) 页码:1561-1564]
1031434-37-3 = 940-61-4
反应条件:1.1 Reagents: 1,8-Diazabicyclo[5.4.0]Undec-7-Ene,2-(Dimethylamino)Ethanethiol Hydrochloride Solvents: Acetonitrile; 15 Min,Rt1.2 Reagents: Hydrochloric Acid Solvents: Diethyl Ether,Water; Rt
标题:(1-Nosyl-5-Nitroindol-3-Yl)Methyl Ester: A Novel Protective Group For Carboxylic Acids
作者:Nishimura,Takuya; Yamada,Kouhei; Takebe,Tohru; Yokoshima,Satoshi; Fukuyama,Tohru
参考文献:Organic Letters 日期:2008 卷标:10(12) 页码:2601-2604]
624-31-7 = 940-61-4
反应条件:1.1 Reagents: Potassium Hydroxide Catalysts: Palladium Oxide (Pdo) Solvents: Water; 5 H,90 °C1.2 Reagents: Hydrochloric Acid Solvents: Water
标题:Linear Polystyrene-Stabilized Pdo Nanoparticle-Catalyzed Mizoroki-Heck Reactions In Water
作者:Ohtaka,Atsushi; Yamaguchi,Tomohiro; Teratani,Takuto; Shimomura,Osamu; Nomura,Ryoki
参考文献:Molecules 日期:2011 卷标:16 页码:9067-9076]
= 940-61-4
反应条件:1.1 Reagents: Potassium Tert-Butoxide Solvents: Water; 10 Min,Rt1.2 Catalysts: (Sp-4-3)-Dibromo[rel-1,3-Dihydro-1-Methyl-3-[[(1R,2S)-1-(Phenylmethyl)-2-Pyrroli...; 24 H,120 °C; 120 °C -> Rt1.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 1,Rt
标题:N-Heterocyclic Carbene-Pd(Ii) Complex Derived From Proline For The Mizoroki-Heck Reaction In Water
作者:Tang,Yi-Qiang; Chu,Chun-Yan; Zhu,Lei; Qian,Bin; Shao,Li-Xiong
参考文献:Tetrahedron 日期:2011 卷标:67(49) 页码:9479-9483]
141-82-2 + 104-87-0 = 940-61-4
反应条件:1.1 Catalysts: Piperidine Solvents: Pyridine; 3 H,Rt
标题:Design,Synthesis And Evaluation Against Chikungunya Virus Of Novel Small-Molecule Antiviral Agents
作者:Tardugno,Roberta; Giancotti,Gilda; De Burghgraeve,Tine; Delang,Leen; Neyts,Johan; Et Al
参考文献:Bioorganic & Medicinal Chemistry 日期:2018 卷标:26(4) 页码:869-874]
141-82-2 + 104-87-0 = 940-61-4
反应条件:1.1 Catalysts: Piperidine Solvents: Pyridine; 85 °C; 6 H,85 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; 85 °C -> Rt; Neutralized,Cooled
标题:Synthesis And Fungicidal Activity Study Of Novel Daphneolone Analogs With 2,6-Dimethylmorpholine
作者:Xu,Gao-Fei; Yang,Xin-Ling; Lei,Peng; Liu,Xi-Li; Zhang,Xue-Bo; Et Al
参考文献:Chinese Chemical Letters 日期:2016 卷标:27(4) 页码:555-558]
= 940-61-4
反应条件:1.1 Reagents: Potassium Hydroxide Catalysts: Tetrabutylammonium Bromide,Palladium Solvents: Water; 5 H,90 °C; 10 Min,90 °C -> 20 °C
标题:Application Of 'Boomerang' Linear Polystyrene-Stabilized Pd Nanoparticles To A Series Of C-C Coupling Reactions In Water
作者:Ohtaka,Atsushi; Okagaki,Toshiyuki; Hamasaka,Go; Uozumi,Yasuhiro; Shinagawa,Tsutomu; Et Al
参考文献:Catalysts 日期:2015 卷标:5(1) 页码:106-118]
141-82-2 + 104-87-0 = 940-61-4
反应条件:1.1 Catalysts: Bismuth Trichloride; 3.5 Min,Heated
标题:Bismuth(Iii) Chloride-Mediated,Efficient,Solvent-Free,Mwi-Enhanced Doebner Condensation For The Synthesis Of (E)-Cinnamic Acids
作者:Kumar,Dhruva; Sandhu,Jagir S.
参考文献:Synthetic Communications 日期:2010 卷标:40(13) 页码:1915-1919]
624-31-7 = 940-61-4
反应条件:1.1 Reagents: Tributylamine Catalysts: Diethylenetriamine,Tetrabutylammonium Chloride,Palladium Solvents: Dimethylformamide; 12 H,120 °C1.2 Reagents: Sodium Carbonate Solvents: Water; 10 Min,Cooled
标题:Synthesis Of Lignin-Amine Supported Palladium Catalysts For Heck Reaction
作者:Wu,Yufeng; Zhang,Lei; Cui,Yuanchen; Liu,Jiangsheng; Yang,Shuai
参考文献:Shiyou Huagong 日期:2009 卷标:38(7) 页码:733-738]
624-31-7 = 940-61-4
反应条件:1.1 Reagents: Tributylamine Catalysts: Palladium (Silica-Supported Complex With Poly[(3-Mercaptopropyl)Siloxane]) Solvents: P-Xylene
标题:Silica-Supported Poly[(γ-Mercaptopropyl)Siloxane] Palladium(0) Complex. A Highly Active And Stereoselective Catalyst Of Arylation Of Styrene And Acrylic Acid
作者:Cai,Ming Zhong; Song,Cai Sheng; Huang,Xian
参考文献:Synthesis 日期:1997 卷标:(5) 页码:521-523]
56578-35-9 = 940-61-4
反应条件:1.1 Reagents: Sodium Carbonate,Oxygen Catalysts: Molybdate(4-),Cupratehexa-μ3-Hydroxyhexa-μ-Oxododecaoxohexa-,Ammonium (1:4) Solvents: Water; 12 H,50 °C
标题:An Efficient Aerobic Oxidation Protocol Of Aldehydes To Carboxylic Acids In Water Catalyzed By An Inorganic-Ligand-Supported Copper Catalyst
作者:Yu,Han; Ru,Shi; Zhai,Yongyan; Dai,Guoyong; Han,Sheng; Et Al
参考文献:Chemcatchem 日期:2018 卷标:10(6) 页码:1253-1257
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参考DOI号:10.1021/ol8008655
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