CAS: 78603-97-1; (S)-2-Amino-4-Methyl-1,1-Diphenylpentan-1-Ol
该化合物是一种化学化合物,具有氨和酒精的典型特征;该物质具有手性中心,有助于其立体化学和潜在的生物活动;氨基氨基化合物的存在表明,它可能参与氢结合,影响其溶解性和反应性;其结构中的苯基和苯基化合物表明,该物质可能具有疏水特性,可能影响其与生物膜和其他有机化合物的相互作用;此外,该化合物的分子结构表明,鉴于其与各种生物目标相互作用的能力,该物质的分子结构可能被用于制药或作为生物化学探测器.其具体的物理特性,如熔点,沸点和溶性,需要通过实验来确定,因为它们可能因环境条件和其他物质的存在而有所不同.总体而言,该混合物的独特结构将它定位为合成化学和药用化学两方面都感兴趣的对象.
- 英文名称(S)-2-Amino-4-Methyl-1,1-Diphenylpentan-1-Ol
- 中文名称(S)-2-氨基-4-甲基-1,1-二苯戊烷-1-醇
- IUPAC名称(2S)-2-amino-4-methyl-1,1-diphenylpentan-1-ol
- 其它别名(S)-(-)-2-氨-4-甲基-1,1-联苯-1-丙醇; (S)-(-)-2-Amino-4-Methyl-1,1-Diphenyl-1-Pentanol
- CAS编号78603-97-1
- MFCD编号:MFCD03093529
- EINECS号:623-448-4
- 分子式:C18H23NO分子量:269.38
- 产品CID: 1780738
- 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物
相似化合物
78603-95-9 86695-06-9 78603-91-5物理性质
MSDS等安全信息
欧盟法规
ECHA物质C&L通报上下游产品
methyl (L)-leucinate hydr°Chloride L-Leucine ethyl ester L-leucyl chloride L-leucine 3,3'-Bis-{[(E)-(S)-1-(hydroxy-diphenyl-methyl)-3-methyl-butylimino]-methyl}-[1,1']binaphthalenyl-2,2'-diol (S)-4-Isobutyl-5,5-diphenyl-oxazolidin-2-one合成工艺路线路线简述
- 合成目标产物 (S)-(-)-2-Amino-4-Methyl-1,1-Diphenyl-1-Pentanol 主要起始原料 Bromobenzene And Methyl L-Leucinate Hydrochloride
- (文献来源)合成步骤主要原料 Bromobenzene 和 Methyl L-Leucinate Hydrochloride
📜Methyl (S)-N-(Ethoxycarbonyl)Leucinate置于magnesium,Potassium Hydroxide体系中,用 四氢呋喃,甲醇 作为反应溶剂,化学反应 31.0H,反应生成 (S)-(-)-2-氨基-4-甲基-1,1-二苯基-1-戊醇
参考文献:基于三齿氨基烷氧基nno-配体的铝配合物:合成,结构和性能
标题:基于三齿氨基烷氧基nno-配体的铝配合物:合成,结构和性能
摘要:一系列新颖的nno型配体12A-17A,Lh 2,R 1 N(ch 2 Ch 2 N Hts)chr 2 Cr 3 R 4 O H(r 1 = Bn,R 3 = R 4 = H; R 2 = H(12A),R 2 =(S)-Ph(13A),R 2 =(S)-Bn(14A),R 2 =(S)-I-Bu(15A)); R 1 = R 2=(R)-Me,R 3 = H,R 4=(S)-Ph(16A);得到r 1 = Bn,R 2=(S)-I-Bu,R 3 = R 4 = Ph(17A)).配体lh 2具有各种取代度,空间体积和手性.的治疗11A(r 1 =我,R 2 = R 3 = R 4 = H),12A-17A,和18A 用alme 3(r 1 = Me,R 2 = H,R 3 = R 4= Ph)得到配合物11B-18B,[lalme] N(n
DOI:10.1016/j.Jorganchem.2018.08.021
海关参考信息
- 2902600000-乙苯
2905121000-正丙醇
2905130000-正丁醇
2906210000-苄醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:WO-9501357-A1
优先权日:1993-07-02
标题 :Optically active 1-(4-nitrophenyl)-4-methyl-7,8-methylenedioxy-3,4-dihydro-5h-2,3-benzodiazepine and process for preparing same
发明人：LING ISTVAN; HAMORI TAMAS; BOTKA PETER; SOLYOM SANDOR; SIMAY ANTAL; MORAVCSIK IMRE
权利人:GYOGYSZERKUTATO INTEZET; LING ISTVAN; HAMORI TAMAS; BOTKA PETER; SOLYOM SANDOR; SIMAY ANTAL; MORAVCSIK IMRE
摘要:The invention relates to the (+)- and (-)-enantiomers of the compounds of formula (I) as well as a process for the preparation of these enantiomers. This process comprises reducing 1-(4-nitrophenyl)-4-methyl-7,8-methylenedioxy-5H^_-2,3-benzodiazepine of formula (II) by using an adduct formed from an (R)- or (S)-, respectively, 2-amino-1,1-diphenyl-alkan-1-ol derivative of general formula (III), wherein R1 and R2, which are different, stand for a straight or branched chain C1-4 alkyl group or an unsubstituted phenyl or benzyl group, with one molar equivalent of borane or a borane complex. The enantiomers of the compound of formula (I) are valuable intermediates in the synthesis of therapeutically active compounds.
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📌 第三方产品分析报告
主要参考文献
参考标题:Direct Asymmetric N-Specific Reaction Of Nitrosobenzene With Aldehydes Catalyzed By A Chiral Primary Amine-Based Organocatalyst作者:Long Qin,Lei Li,Lei Yi,Chao-Shan Da,Yi-Feng Zhou |发布日期:2011.8
摘要:Interesting And Important To Perform A Nitrogen Or Oxygen Selective Reaction With Interesting Substrates. These Atom Specific Reactions Are Crucial To Specifically Synthesis Of Specific Compounds. An Enantioselective N‐specific Reaction Of Nitrosobenzene With Unmodified Aldehydes Was Successfully Achieved Catalyzed First By A Variety Of Primary Amine‐based Organocatalysts With Higher Yield And Enantioselectivity
合成参考文献
参考DOI号:10.1021/op200283q
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