CAS: 558-37-2; 3,3-Dimethyl-1-Butene

该化合物是一种有机化合物,被归类为烷,其特点是存在碳-碳双联体.分子分子式为C6H12,表明该分子式由6个碳原子和12个氢原子组成.该化合物具有一个分支结构,其中两个甲基组附于丁烯链的第三个碳,这有利于其独特的反应和物理特性. 3,3,3-二甲基-1-丁在室温中是一种无色液体,其沸点相对较低,典型为藻类,它具有挥发性.该化合物在水中溶解,但有机溶解剂中溶解.该化合物主要用于有机合成,并且作为包括聚合物在内的各种化学品生产的中间体.由于存在双联体,它可以发生典型的烷反应,如氢化,聚合物化和电荷添加.在处理该化合物时,应当采取安全防范措施,因为它可能是易燃的,如果吸入或吸入,则可能构成健康风险.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号917-92-0 3,3-二甲基-1-丁炔 | CAS号464-07-3 3,3-二甲基-2-丁醇 | CAS号54509-73-8 ethene | CAS号754-05-2 三甲基硅乙烯 | CAS号115-11-7 2-甲基丙烯 | CAS号563-79-1 2,3-二甲基-2-丁烯 | CAS号6366-35-4 1-chloro-2,2-di... | CAS号19493-09-5 methylidene tri... | CAS号97797-99-4 1-Butene, 4-bro... | CAS号918-83-2 2,2-dimethylbut... | CAS号5469-26-1 1-溴频哪酮 | CAS号14272-73-2 5,5-dimethylhex... | CAS号93-55-0 苯丙酮 | CAS号75-83-2 2,2-二甲基丁烷 | CAS号4265-25-2 2-甲基苯并呋喃 | CAS号34557-54-5 methane | CAS号463-82-1 新戊烷 | CAS号464-06-2 2,2,3-三甲基丁烷 | CAS号590-35-2 2,2-二甲基戊烷 | CAS号115-11-7 2-甲基丙烯

合成工艺路线路线简述

    O-Pinacolyl S-Methyl Xanthate 反应生成 3,3-二甲基-1-丁烯
    参考文献:Fomin; Sochanski,Chemische Berichte,1913,Vol. 46,P. 247
    标题:Fomin; Sochanski,Chemische Berichte,1913,Vol. 46,P. 247

    海关参考信息

    专利信息


    专利号:US-12139504-B2
    优先权日:2022-08-09
    标 题:Vanadium alkylidene complex, synthesis and use thereof
    发明人:BUKHRYAKOV KONSTANTIN; BELOV DMITRY
    权利人:BUKHRYAKOV KONSTANTIN; BELOV DMITRY; THE FLORIDA INTERNATIONAL UNIV BOARD OF TRUSTEES
    摘要:The subject invention provides catalytical compounds/complexes, compositions comprising such compound/complex, synthesis of the compounds/complexes, and methods of using such compounds/complexes as catalysts in, for example, RCM reactions. Specifically, the subject invention provides the synthesis of the first catalytically active V oxo alkylidene, VO(CHSiMe 3 )(PEt 3 ) 2 Cl, which exhibits superior performance compared to other analogs.

    专利号:US-9255117-B2
    优先权日:2006-07-13
    标题 :Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis
    发明人:SCHRODI YANN
    权利人:MATERIA INC
    摘要:This invention relates generally to olefin metathesis, and more particularly relates to the synthesis of terminal alkenes from internal alkenes using a cross-metathesis reaction catalyzed by a selected olefin metathesis catalyst. In one embodiment of the invention, for example, a method is provided for synthesizing a terminal olefin, the method comprising contacting an olefinic substrate comprised of at least one internal olefin with ethylene, in the presence of a metathesis catalyst, wherein the catalyst is present in an amount that is less than about 1000 ppm relative to the olefinic substrate, and wherein the metathesis catalyst has the structure of formula (II) n nwherein the various substituents are as defined herein. The invention has utility, for example, in the fields of catalysis, organic synthesis, and industrial chemistry.

    专利号:US-2023183177-A1
    优先权日:2020-04-24
    标题:Enantioselective chemo-enzymatic synthesis of optically active amino amide compounds
    发明人:GRILL BIRGIT; WINKLER MARGIT; SCHWAB HELMUT; STROHMEIER GERNOT; DONSBACH KAI; WALDVOGEL SIEGFRIED R; ARNDT SEBASTIAN; WEIS DOMINIK
    权利人:PHARMAZELL GMBH
    摘要:The present invention relates to a novel biocatalytic process for the stereoselective preparation of alpha amino amide compounds catalyzed by NHase enzymes. A further aspect of the invention relates to novel NHase enzymes as well as further improved NHase enzyme mutants, nucleic acid molecules encoding these enzymes, recombinant microorganisms suitable for preparing such enzymes and mutants. Another aspect of the invention relates to a chemo-biocatalytic process for the preparation of lactam compounds comprising the new catalytic process for the preparation of alpha amino amide compounds catalyzed by NHase enzymes, as well as the chemical oxidation of the alpha amino amide by applying certain chemical oxidation catalysts suitable for converting the alpha amino amide under retention of its stereochemical configuration to the respective lactam. The novel chemo-biocatalytic process is particularly suited for the synthesis of valuable pharmaceutical compounds, like in particular (S)-Levetiracetam.

    专利号:US-2019228842-A1
    优先权日:2017-11-17
    标 题 :Recipe for the synthesis of metastable structures using topologically assembled precursors
    发明人:JENA PURUSOTTAM; FANG HONG
    权利人:UNIV VIRGINIA COMMONWEALTH
    摘要:Methods of planning and executing the synthesis of metastable materials are provided. Topologically assembled precursors having potential energy surfaces in which the volumes of potential wells of certain local minima are increased are created in silico. The precursor molecules are used to synthesize, e.g. two-dimensional metastable carbon materials such as penta-graphene comprised entirely of pentagons, O-graphene comprised of five- and eight-membered rings, and R-graphene comprised of four-, six- and eight-membered rings.

    专利号:US-9382189-B2
    优先权日:2013-02-08
    标题:Synthesis of a branched unsaturated compound by means of cross metathesis
    发明人:DUBOIS JEAN-LUC; COUTURIER JEAN-LUC
    权利人:ARKEMA FRANCE
    摘要:The invention relates to a method for the synthesis of a branched unsaturated fatty compound, said method comprising the metathesis, in the presence of a metathesis catalyst, of a linear unsaturated fatty compound and a branched olefin. The branched unsaturated fatty compound is used in particular for the production of at least one of the following products: dielectric fluids, specialty surfactants, emulsifiers, frictions agents, antistatic additives, antifogging additives, mould release agents, pigment dispersants, high-performance lubricants, waxes and wax emulsifiers, polymer conversion additives, PVC stabilizing agents, inks, resins, paints, varnishes, solvents, lipsticks, creams for the skin, deodorants, particularly stick deodorants, hair dyes, shampoos and other liquid soaps, shaving foam, laundry detergents, cleaning agents, fabric softeners, and mixtures of same.

    专利号:US-11306041-B2
    优先权日:2017-03-30
    标 题:Catalytic synthesis of super linear alkenyl arenes using rhodium catalysts
    发明人:SCHINSKI WILLIAM; GOLDMAN ALAN; GUNNOE THOMAS B; WEBSTER-GARDINER MICHAEL S; SCHWARTZ NICHOLE
    权利人:UNIV VIRGINIA PATENT FOUNDATION
    摘要:Catalytic methods for synthesis of super linear alkenyl arenes and alkyl arenes are provided. The methods are capable of synthesizing super linear alkyl and alkenyl arenes from simple arene and olefin starting materials and with high selectivity for linear coupling. Methods are also provided for making a 2,6-dimethylnapthalene (DMN) or 2,6-methylethylnapthalene (MEN).
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    合成参考文献


    摘要:Cherkinsky, M.; Levinger, S., Science of Synthesis, (2010) 47, 494.
    摘要:Kostikov, R. R.; Khlebnikov, A. F.; Sokolov, V. V., Science of Synthesis, (2010) 47, 816.
    摘要:Michalak, M.; Gulajski, L.; Grela, K., Science of Synthesis, (2010) 47, 340.
    摘要:Li, H.; Mazet, C., Science of Synthesis Knowledge Updates, (2015) 2, 53.
    摘要:Batrice, R. J.; Karmel, I.-S. R.; Eisen, M. S., Science of Synthesis Knowledge Updates, (2012) 4, 121.
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