CAS: 106-30-9; Ethyl Heptanoate

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111-70-6 106-32-1 106-33-2

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CAS号64-17-5 乙醇 | CAS号111-26-2 正己胺 | CAS号201230-82-2 carbon monoxide | CAS号25118-23-4 6-庚烯酸乙酯 | CAS号2351-88-4 ethyl hept-2-enoate | CAS号623-73-4 重氮乙酸乙酯 | CAS号109-66-0 正戊烷 | CAS号15676-66-1 tributylindigane | CAS号140-88-5 丙烯酸乙酯 | CAS号111-14-8 庚酸 | CAS号10385-08-7 Heptanamide,N,N... | CAS号373-49-9 棕榈油酸 | CAS号462-18-0 7-十三酮 | CAS号18229-17-9 8-hydroxytetrad... | CAS号2363-86-2 2-oxo°Ctanal | CAS号111-71-7 正庚醛 | CAS号111-70-6 正庚醇 | CAS号64-17-5 乙醇 | CAS号111-14-8 庚酸 | CAS号10030-73-6 反式-棕榈油酸

庚酸置于咪唑体系中,用 N,N-二甲基甲酰胺 用作溶剂,化学反应生成庚酸乙酯
参考文献:Reaction Of Tert-Butyldimethylsilyl Esters With Oxalyl Chloride-Dimethylformamide: Preparation Of Carboxylic Acid Chlorides Under Neutral Conditions
标题:Reaction Of Tert-Butyldimethylsilyl Esters With Oxalyl Chloride-Dimethylformamide: Preparation Of Carboxylic Acid Chlorides Under Neutral Conditions
摘要:
Doi:10.1021/jo00414A041

专利信息

专利号:US-4841045-A
优先权日:1985-03-12
标 题 :Synthesis of vinblastine and vincristine type compounds
发明人：KUEHNE MARTIN
权利人:UNIV VERMONT
摘要:A new process for the stereospecific synthesis of alkaloids of the vinblastine and vincristine type including the synthesis of vinblastine and vincristine as well novel alkaloids which are active as anti-tumor agents.

专利号:US-4897477-A
优先权日:1985-03-12
标题:Synthesis of vinblastine and vincristine type compounds
发明人：KUEHNE MARTIN
权利人:UNIV VERMONT
摘要:A new process for the stereospecific synthesis of alkaloids of the vinblastine and vincristine type including the synthesis of vinblastine and vincristine as well novel alkaloids which are active as anti-tumor agents.

专利号:US-4794176-A
优先权日:1981-06-26
标 题 :Synthesis of tumor antigenic determinant
发明人：LEMIEUX RAYMOND U; RATCLIFFE ROBERT M; BAKER DONALD A
权利人:CHEMBIOMED
摘要:Processes are provided for the synthesis of the human T-antigenic determinant 2-acetamido-2-deoxy-3-O-(β-D-galactopyranosyl)-α-D-galactopyranoside containing an α-O-glycosidically linked bridging arm O--(CH 2 ) n COR. The determinant is coupled to carrier molecules to form artifical T-antigens, and to insoluble supports to form T-immunoadsorbents. The artificial T-antigen is shown to elicit a delayed type hypersensitivity reaction as a diagnostic for the presence of cancer in humans.

专利号:US-4767845-A
优先权日:1980-07-10
标题 :Synthesis of tumor antigenic determinant
发明人：LEMIEUX RAYMOND U; RATCLIFFE ROBERT M; BAKER DONALD A
权利人:CHEMBIOMED LTD
摘要:Processes are provided for the synthesis of the human T-antigenic determinant 2-acetamido-2-deoxy-3-O-(β-D-galactopyranosyl)-α-D-galactopyranoside containing an α-O-glycosidically linked bridging arm O--(CH 2 ) n COR. The determinant is coupled to carrier molecules to form artificial T-antigens, and to insoluble supports to form T-immunoadsorbents. The artifical T-antigen is shown to elicit a delayed type hypersensitivity reaction as a diagnostic for the presence of cancer in humans.

专利号:US-4818816-A
优先权日:1981-04-28
标 题:Process for the organic synthesis of oligosaccharides and derivatives thereof
发明人：PETITOU MAURICE; JACQUINET JEAN-CLAUDE; SINAY PIERRE; CHOAY JEAN; LORMEAU JEAN-CLAUDE; NASSR MAHMOUD
权利人:CHOAY SA
摘要:The invention relates to a process for the organic synthesis of oligosaccharides constituting or comprising fragments of acid mucopolysaccharides comprising the reaction of two compounds constituted or terminated by units of glucosamine structure and of uronic acid structure respectively, said units being specifically substituted. This process particularly enables valuable anticoagulant drugs to be obtained.

专利号:US-4806655-A
优先权日:1986-07-03
标题:Process for the stereospecific synthesis of indole derivatives
发明人：WAGNON JEAN; PLOUZANE CLAUDE; TONNERRE BERNARD; NISATO DINO
权利人:SANOFI SA
摘要:The present invention relates to a process for the stereo-specific synthesis of indole derivatives of formula: ##STR1## which consists in using 3-tosyloxy-1,2-O-isopropylidenepropane-1,2-diol (II) in an optically pure form in order to introduce the asymetric carbon C* of compound (I). Compound (II) is condensed with a suitable primary amine in order to prepare an oxazolidinone and condensation with a suitable phenol, and the oxazolidinone ring is then opened to form an indole compound (I).