CAS: 104-62-1; Phenethyl Formate

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103-45-7 3530-36-7 3558-60-9

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CAS号64-18-6 甲酸 | CAS号60-12-8 苯乙醇 | CAS号109-94-4 甲酸乙酯 | CAS号75-87-6 三氯乙醛 | CAS号14629-58-4 [2-(Trimethylsi... | CAS号1927-61-3 tetrahydro-2-(2... | CAS号622-24-2 β-氯代苯乙烷 | CAS号101-41-7 苯乙酸甲酯 | CAS号142-62-1 正己酸 | CAS号3197-61-3 N-甲酰基咪唑 | CAS号60-12-8 苯乙醇 | CAS号80858-47-5 [2-(环己氧基)乙基]苯

📜苯基乙二醇置于palladium(II) Acetylacetonate,N,N-二异丙基乙胺,Alpha,Alpha'双(二叔丁基膦)邻二甲苯体系中,用 氯仿,乙腈 用作溶剂,化学反应 36.0H,反应生成甲酸-2-苯乙酯
参考文献:乙二醇衍生物的串联酸/钯催化还原还原重排.
标题:乙二醇衍生物的串联酸/钯催化还原还原重排.
摘要:在本文中,我们描述了酸/ Pd串联催化的乙二醇衍生物向末端甲酸酯的转化.机理研究表明,在[1,2]-H迁移和氧基离去基团的裂解下,底物发生重排成醛.离开的基团被捕获为其甲酸酯,醛被还原并随后酯化为甲酸酯.磺酸可催化醛的重排,而还原步骤则需要独特的催化剂体系,该体系包含pd(II)-或pd(0)-前体,其负载量低至0.75 Mol%和a,A'-Bis(二叔丁基膦基)-邻二甲苯作为配体.还原步骤利用甲酸作为易于处理的转移还原剂.
Doi:10.1002/chem.202000251

专利信息

专利号:US-5338851-A
优先权日:1993-03-31
标 题:Synthesis of cis-decahydroisoquinoline-3-carboxylic acids
发明人：HUFF BRET E; KHAU VIEN V; MARTINELLI MICHAEL J; PETERSON BARRY C
权利人:LILLY CO ELI
摘要:This invention provides a process for the synthesis of cis-decahydroisoquinoline-3-carboxylic acids and provides intermediates in the synthesis thereof.

专利号:US-10787458-B2
优先权日:2014-09-25
标 题:Chiral synthesis of N-acyl-(3-substituted)-(8-substituted)-5,6-dihydro-[1,2,4]triazolo[4,3-A]pyrazines
发明人：HOVEYDA HAMID; DUTHEUIL GUILLAUME
权利人:OGEDA SA
摘要:Disclosed is a novel chiral synthesis of N-acyl-(3-substituted)-(8-substituted)-5,6-dihydro-[1,2,4]triazolo[4,3-a]pyrazines of Formula (I): n nor a solvate thereof. The novel chiral synthesis avoids the use of protection/deprotection steps.

专利号:US-2013338369-A1
优先权日:2011-03-07
标 题 :Process for the Synthesis of Aminobiphenylene
发明人：HEINRICH MARKUS; PRATSCH GERALD
权利人:HEINRICH MARKUS; PRATSCH GERALD; BASF SE
摘要:The present invention relates to a process for the synthesis of 2-aminobiphenylene and derivatives thereof by reacting a benzene diazonium salt with an aniline compound under basic reaction conditions.

专利号:WO-9804535-A1
优先权日:1996-07-26
标 题 :A practical synthesis of benzoxazinones useful as hiv reverse transcriptase inhibitors
发明人：PIERCE MICHAEL ERNEST; RADESCA LILIAN ALICIA
权利人:DU PONT MERCK PHARMA
摘要:The present invention describes novel methods for the synthesis of benzoxazinone compounds which are useful as human immunodeficiency virus (HIV) reverse transcriptase inhibitors. The benzoxazinone of formula (VI-a) is particularly effective in the treatment of HIV.

专利号:US-6348616-B1
优先权日:1996-07-26
标题 :Practical synthesis of benzoxazinones useful as HIV reverse transcriptase inhibitors
发明人：PIERCE MICHAEL ERNEST; RADESCA LILIAN ALICIA
摘要:The present invention describes novel methods for the synthesis of benzoxazinone compounds which are useful as human immunodeficiency virus (HIV) reverse transcriptase inhibitors. The benzoxazinone of the formula:is particularly effective in the treatment of HIV.

专利号:US-6770763-B2
优先权日:2002-06-11
标题 :Asymmetric synthesis of amino-pyrrolidinones
发明人：MAGNUS NICHOLAS A; CONFALONE PASQUALE N; SAVAGE SCOTT A; YATES MATTHEW; WALTERMIRE ROBERT E; MELONI DAVID J; CAMPAGNA SILVIO
权利人:BRISTOL MYERS SQUIBB CO
摘要:A novel process for the asymmetric synthesis of an amino-pyrrolidinone of the type shown below from appropriate pyrrolidinones is described.These compounds are useful as intermediates for MMP and TACE inhibitors.