CAS: 98243-57-3; (3S,4As,5R,6As,6Bs,8Ar,9R,9As,12S,15As,15Br,16As,16Br)-9,12,16B-Trimethyltetracosahydrobenzo[4,5]Indeno[1,2-H]Pyrido[1,2-B]Isoquinoline-3,5-Diol

英文名称(3S,4As,5R,6As,6Bs,8Ar,9R,9As,12S,15As,15Br,16As,16Br)-9,12,16B-Trimethyltetracosahydrobenzo[4,5]Indeno[1,2-H]Pyrido[1,2-B]Isoquinoline-3,5-Diol
中文名称湖贝甲素
IUPAC名称(3S,4aS,5R,6aS,6bS,8aR,9R,9aS,12S,15aS,15bR,16aS,16bR)-9,12,16b-trimethyltetracosahydrobenzo[4,5]indeno[1,2-h]pyrido[1,2-b]isoquinoline-3,5-diol
其它别名Hupehenine; Cevane-3,6-Diol(3β,5α,6β,17β); Hupehenine, , From Fritillary; (3Beta,5Alpha,6Beta,17Beta)-Cevane-3,6-Diol; Hujiasu; Hupehenine, 10 Mm In Dmso
CAS编号98243-57-3
MFCD编号:MFCD07781416
分子式:C27H45NO2
分子量:415.66
产品CID: 2025248
产品分类生物化工 → 提取物

相似结构搜索
InChIKey: NEMWYOKGHGSVSC-MSSYMPDSSA-N
NEMWYOKGHGSVSC-PRTTVAHLNA-N…
计算化学: 氢键受体数3.0氢键供体数2.0可旋转键数0.0

MSDS等安全信息

警示词warning
危险描述H303 May be harmful if swallowed+H313 Skin contact may be harmful+H333 Inhalation may be harmful to the body
防范说明P264+P280+P305+P351+P338+P337+P313
安全声明24/25

上下游产品

CAS号96997-98-7 Delavinone

合成工艺路线路线简述

Delavinone置于sodium Tetrahydroborate体系中,化学反应生成新贝母碱
参考文献:Isolation And Structure Elucidation Of New Alkaloids From Fritillaria Delavayi Franch.
标题:Isolation And Structure Elucidation Of New Alkaloids From Fritillaria Delavayi Franch.
摘要:Two New D/e Cis-5α-Cevanine Alkaloids,Delavine (1) And Delavinone (2),Which Lack A Hydroxyl Group At C-20,Have Been Isolated Together With Imperialine From Fritillaria Delavayi Franch (Liliaceae). The X-Ray Crystallographic Analysis Of 2 Also Has Been Accomplished.
DOI:10.1248/cpb.33.2614

海关参考信息

2905122000-异丙醇
2905399002-1,4-丁二醇
2905141000-异丁醇
2905142000-仲丁醇
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合成参考文献

参考文献:10.1002/chin.200302187|10.1002/chin.200333201
摘要:Rahman‐Atta‐Ur R, Akhtar MN, Choudhary MI, Tsuda Y, Sener B, Khalid A, Parvez M. New Steroidal Alkaloids from Fritillaria imperialis and Their Cholinesterase Inhibiting Activities. ChemInform. 2003 Jan 14;34(2). doi: 10.1002/chin.200302187.
参考文献:10.1248/cpb.33.2614
摘要:Kaneko K, Katsuhara T, Mitsuhashi H, Chen Y, Hsu H, Shiro M. Isolation and structure elucidation of new alkaloids from Fritillaria delavayi Franch. Chem. Pharm. Bull. 1985;33(6):2614–7. doi: 10.1248/cpb.33.2614.
参考文献:10.1246/cl.1992.163
摘要:Ori K, Mimaki Y, Sashida Y, Nikaido T, Ohmoto T, Masuko A. Persicanidine A, a Novel Cerveratrum Alkaloid from the Bulbs of Fritillaria persica. 1992 Jan 01;21(1):163–6. doi: 10.1246/cl.1992.163.
参考文献:10.1016/0031-9422(92)83735-h
摘要:Ori K, Mimaki Y, Sashida Y, Nikaido T, Ohmoto T. Cerveratrum alkaloids from bulbs of Fritillaria persica. Phytochemistry. 1992 Oct;31(10):3605–7. doi: 10.1016/0031-9422(92)83735-h.