CAS: 76-19-7; Octafluoropropane

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CAS号422-04-8 pentafluoroprop... | CAS号71-43-2 苯 | CAS号116-15-4 六氟丙烯 | CAS号463-49-0 丙二烯 | CAS号116-14-3 四氟乙烯 | CAS号75-10-5 二氟甲烷 | CAS号34557-54-5 methane | CAS号75-46-7 三氟甲烷 | CAS号754-34-7 全氟丙基碘 | CAS号422-85-5 七氟丙基溴 | CAS号75-63-8 三氟溴甲烷 | CAS号354-55-2 溴五氟乙烷 | CAS号116-15-4 六氟丙烯 | CAS号76-16-4 六氟乙烷 | CAS号382-21-8 全氟异丁烯 | CAS号354-33-6 五氟乙烷 | CAS号75-10-5 二氟甲烷 | CAS号75-46-7 三氟甲烷 | CAS号56112-35-7 2,3,3,3-tetrafl...

苯置于铜,Fluorine体系中,化学反应生成 八氟丙烷
参考文献:Fukuhara; Bigelow,Journal Of The American Chemical Society,1941,Vol. 63,P. 2793
标题:Fukuhara; Bigelow,Journal Of The American Chemical Society,1941,Vol. 63,P. 2793

专利信息

专利号:US-2004038331-A1
优先权日:2002-08-23
标题:Solid phase synthesis of biomolecule conjugates
发明人：REDDY M PARAMESWARA; FAROOQUI FIRDOUS; BRILLHART KURT L
摘要:Processes for the solid state phase formation synthesis of biomolecule conjugates, particularly protein-oligonucleotide conjugates are shown. One of the protein or oligonucleotide is reversibly bound to a solid substrate phase. At least one portion of each of the protein and the oligonucleotide molecules is activated with complementary activation groups. The activated protein and the activated oligonucleotide are then reacted, in a buffered solution resulting in the formation of the desired conjugate which remains reversibly bound to the substrate. The nature of the buffered solution is then modified causing the conjugate to be released from the substrate solid phase.

专利号:US-2010173100-A1
优先权日:2006-01-16
标题 :Method for the synthesis of product molecules
发明人：WEISS HORST; GERBER GUSTAV; NUERNBERGER PATRICK HENNING; WOLPERT DANIEL STEPHAN
权利人:BASF AG
摘要:The invention relates to a method for the synthesis of product molecules, wherein ultrashort laser pulses shaped with the aid of a pulse shaper are generated and a gas which contains educt molecules is fed onto a surface, on which the educt molecules are at least partially adsorbed, the shaped ultrashort laser pulses being directed onto the surface in order to control a reaction process for synthesis of the product molecules from educts adsorbed on the surface.

专利号:WO-9010069-A1
优先权日:1989-02-28
标题:RECOMBINANT PLASMID DNA pAA 1213-23 AND pAC 262-33 CODING FOR SYNTHESIS OF HUMAN INTERLEUKIN-2, METHOD OF THEIR CONSTRUCTION AND STRAIN OF BACTERIA ESCHERICHIA COLI RRI/pAC 262-33 AS PRODUCER OF HUMAN INTERLEUKIN-2
发明人：AVOT ANDRIS YANOVICH; VARIVOTSKAYA NADEZHDA VIKTOROV; VOITENOK NIKOLAI NIKOLAEVICH; GREN ELMAR YANOVICH; MARTINOVICH ALEXANDR EVGENIEVI; ROMANCHIKOVA NADEZHDA VIKTOROV; SEVCH NINA VYACHESLAVOVNA; TSIMANIS ALEXANDR JURIEVICH; APSALON ULDIS RUDOLFOVICH; BUNDULIS JURIS PETROVICH; LUNEV VITALY EVGENIEVICH; ONOPRIENKO LJUDMILA VIKTOROVNA; SKRIVELIS VITALY ANDRISOVICH
权利人:INST ORGANICHESKOGO SINTEZA AK
摘要:A recombinant plasmid DNA pAA 1213-23 coding for synthesis of human interleukin-2 has a size of 5,150 b.p. and consists of the following elements: an EcoRI-SalI fragment, of a size of 3,710 b.p. of vector plasmid pBR 322; a Cfr 13 fragment of a size of 880 b.p. containing a promoter of tryptophan operon, a polylinker section of recognition of restrictase EcoRI, SmaI, BamHI, initiating ATG and first GCC codons of mature interleukin-2; a Cfr 13-SalI fragment of a size of 570 b.p. of cloned cDNA. A recombinant plasmid DNA pAC 262-33 on the basis of said DNA pAA 1213-23 has a size of 5,135 b.p. and consists of the following elements: an EcoRI-SalI fragment of a size of 3,710 b.p. of vector plasmid pBR 322; a Cfr 13 fragment of a size of 867 b.p.; a Cfr 13-SalI fragment of a size of 570 b.p. of cloned cDNA. A method of construction of recombinant plasmid DNA pAC 262-33 comprises the preliminary construction of plasmid DNA pAA 1213-23 with subsequent construction, on its basis, of plasmid pAC 262-33 with a changed distance between the Shine-Dalgarno sequence and the initiating ATG codon. A strain Escherichia coli RRI/pAC 262-33 as producer of interleukin-2 deposited on 10.07.87 under No VKPM B-3823 at the USSR-Union Collection of Industrial Microorganisms of the USSR Research Institute for Genetics and Industrial Microorganisms Breeding.

专利号:US-9731284-B1
优先权日:2014-03-24
标 题:Process for oxidation of amines in the synthesis of energetic materials
发明人：SANCHEZ PEGGY A; GRISWOLD KIMBERLY; GORUN SERGIU M; PATEL HEMANTBHAI H
权利人:US ARMY; SETON HALL UNIV
摘要:A process for use of composite catalysts for oxidation of amines during synthesis of energetic compounds. This method overcomes the safety concerns associated with dangerous reaction conditions for these energetic materials. The process requires exposing phthalocyanine conjugated to an inorganic substrate to the precursor reactant and activating the composite material to light and oxygen to covert amine groups into oxidized nitrogen species.

专利号:EP-2676962-A1
优先权日:2012-06-21
标 题 :Derivatives of 1-aminoalkylphosphonate diaryl esters, method of 1-aminoalkylphosphonate diaryl ester derivatives preparation and their application
发明人：SIENCZYK MARCIN; GRZYWA RENATA; PIETRUSEWICZ EWA; OLEKSYSZYN JOZEF; WINIARSKI LUKASZ; BURSTER TIMO; BOEHM OTTO
权利人:UNIV ULM; WROCLAW UNIVERSITY OF TECHNOLOGY
摘要:The subject of the invention relates to 1-aminoalkylphosphonate diaryl esters of formula I, in which Bt represents biotin, W is a hydrocarbon linker chain of 5 to 10 carbon atoms, Y is the amino acid residues in an amount of 0 to 4, R is a substituent corresponding to the side chain of valine, alanine, leucine, phenylalanine, 4-guanidinephenylglycine, or 2-aminobutyric acid (Abu), X is the hydrogen or a compound selected from the group consisting of mercaptomethyl (S-methyl), methoxy (O-methyl), or carboxymethyl, and their use as inhibitors of serine proteases, and the low molecular weight molecular probes to detect the catalytically active forms of the enzymes. n A process for preparing 1-aminoalkylphosphonate diaryl esters of formula I, in which Bt represents biotin, W is a hydrocarbon linker chain of 5 to 10 carbon atoms, Y is the amino acid residues in an amount of 0 to 4, R is a substituent corresponding to the side chain of valine, alanine, leucine, phenylalanine, 4-guanidinephenylglycine, or 2-aminobutyric acid (Abu), X is the hydrogen or a compound selected from the group consisting of mercaptomethyl (S-methyl), methoxy (O-methyl), or carboxymethyl relies on application of triaryl phosphite, obtained from the phenol substituted at para position phosphorus (III) chloride in refluxing acetonitrile and is subjected to amidoalkylation reaction with benzyl carbamate and an aldehyde such as acetaldehyde, propionic aldehyde, iso -butyric aldehyde, phenylacetic aldehyde, p-nitrobenzoic aldehyde and isovaleric aldehyde, followed by the synthesis of hydrobromide salts of 1-aminoalkylphosphonate diaryl esters, in which the benzyloxycarbonyl (Cbz) protective group is removed, and in the next step is reacted with an amino acid containing protected α-amino group in the presence of a coupling reagent. The resulting phosphonic dipeptide containing tert-butoxycarbonyl (t-Boc) protective group is subjected to deprotection of α-amino group and obtained dipeptidyl 1-aminoalkylphosphonate diaryl ester is coupled with another amino acid with protected α-amino group, biotin or a derivative thereof in a manner analogous to that described above.

专利号:US-2011172437-A1
优先权日:2008-04-01
标题:Perfluorophthalocyanine Molecules and Methods of Synthesis
发明人：GORUN SERGIU M; GERDES ROBERT; GERDES OLGA; LAPOK LUKASZ
权利人:NEW JERSEY TECH INST
摘要:Advantageous methods for synthesis of fluorinated phthalocyanines are provided. Typical implementation involves a reaction mixture that includes perfluoro compound that is reacted for a reaction period sufficient to yield a fluorinated phthalocyanine of formula F 64 PcM, wherein “Pcâ€? is any phthalocyanine macrocycle and “Mâ€? is hydrogen. Novel fluorinated phthalocyanine molecules/compounds are also provided herein, including specifically compounds that include fluorinated phthalocyanines wherein “Mâ€? is Cu or Vâ•?O. The fluorinated phthalocyanines have wide ranging applications, e.g., corrosion-related applications, coating-related applications, catalysis, and the production of optical and electronic materials.