CAS: 587-85-9; Diphenylmercury

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欧盟法规

《欧盟PIC法规》ECHA物质ECHA物质OtherC&L通报REACH预注册

上下游产品

diazomethane diethyl ether phenylmercury(II) chloride bromobenzenephenylmercury(II) chloride Diphenylmethane benzophenone biphenyl

合成工艺路线路线简述

    📜Phenylmercury Hydride 以 氘代吡啶,氘代甲苯 作为反应溶剂,化学反应生成 二苯基汞
    参考文献:Characterization Of Alkyl-And Aryl-Mercuric Hydrides By NMR Spectroscopy
    标题:Characterization Of Alkyl-And Aryl-Mercuric Hydrides By NMR Spectroscopy
    摘要:Low-Temperature NMR Measurements (H-1,C-13,Hg-199) Confirm That Organomercuric Hydrides (Rhgh; R = Alkyl,Cycloalkyl,Phenyl) Are Characterisable Species In Solution.
    DOI:10.1039/c39940000345

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    专利信息


    专利号:US-7615169-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-7927516-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-4105705-A
    优先权日:1976-04-30
    标 题:Symmetrical biaryl synthesis via rhodium catalyzed dimerization of aryl mercuric salts
    发明人:LAROCK RICHARD CRAIG
    权利人:UNIV IOWA STATE RES FOUND INC
    摘要:Vinyl- and arylmercuric halide salts undergo reaction with rhodium (I) and (III) catalysts, preferably in the presence of lithium chloride to provide essentially quantitative yields of the corresponding 1,3 dienes and biaryls respectively. Importantly, the reaction is stereospecific and is especially valuable for synthesis of symmetrical functionally substituted dienes, biaryls and polyenes.

    专利号:US-6867202-B1
    优先权日:1997-06-25
    标 题 :Treatment of insulin resistance
    发明人:CARPINO PHILIP ALBERT; CHIU CHARLES KWOK-FUNG; PAN LYDIA CODETTA; LEFKER BRUCE ALLEN; TREADWAY JUDITH LEE; ZAWISTOSKI MICHAEL PAUL
    权利人:PFIZER
    摘要:This invention is directed to methods of treating insulin resistance in a mammal which comprise administering an effective amount of a compound of formula I, n n nwhere the variables are defined in the specification, or the stereoisomeric mixtures, diastereomerically enriched, diastereomerically pure, enantiomerically enriched or enantiomerically pure isomers, or the pharmaceutically acceptable salts and prodrugs thereof to said mammal. The compounds of formula I are growth hormone secretagogues and as such are useful for increasing the level of endogenous growth hormone. In another aspect this invention provides certain intermediates which are useful in the synthesis of the foregoing compounds and certain processes useful for the synthesis of said intermediates and th compounds of formula I. This invention is further directed to methods comprising administering to a human or other animal a combination of a functional somatostatin antagonist such as an alpha-2 adrenergic agonist and a compound of formula I.

    专利号:US-2007264834-A1
    优先权日:2004-09-20
    标题:Method for Synthesis of Colloidal Nanoparticles

    专利号:US-2006061017-A1
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles

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    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Miranda C, Yáñez J, Contreras D, Zaror C, Mansilla HD. Phenylmercury degradation by heterogeneous photocatalysis assisted by UV-A light. J Environ Sci Health A Tox Hazard Subst Environ Eng. 2013;48(13):1642-8. doi: 10.1080/10934529.2013.815453. doi: 10.1039/c1dt11324k. Epub 2011 Oct 21. doi: 10.1039/b903056e. Epub 2009 May 7. Epub 2005 Jan 31.
    11: Pandey AS, MacRae TH. Toxicity of organic mercury compounds to the developing brine shrimp, Artemia. Ecotoxicol Environ Saf. 1991 Feb;21(1):68-79.

    合成参考文献


    摘要:National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review., 5(30), 1953
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