CAS: 2767-47-7; Dibromo(Dimethyl)Stannane

该化合物是一种有机锡化合物,主要用作有机合成和工业应用中的催化剂或中间体,其主要优点包括:在诸如静态结合等交叉反应中具有高度的回反应性,及其在聚合工艺中的效用.该化合物具有良好的热稳定性,适合高温应用.其二溴化物结构增强了某些催化变异的选择性,有助于高效反应途径.二甲基二溴化物还被用于生产锡基材料和涂层,对分子结构的精确控制至关重要.由于对水分的敏感性和潜在毒性,需要妥善处理.

结构式图片

欧盟法规

ECHA物质C&L通报

上下游产品

tetrabromosilane trimethylstannane 1-bromo-1,2,2-trifluoroethene dimethylstannane(2-(4,4-dimethyl-2-oxazolinyl)-5-methylphenyl)dimethyltin bromide dimethylstannane Dimethylzinn-bis-diphenylphosphin

合成工艺路线路线简述

    📜二甲基二氯化锡置于sodium Bromide Or Potassium Bromide体系中,用 丙酮 用作溶剂,化学反应生成二甲基溴化锡
    参考文献:一些具有氮和氧供体配体的二卤代二有机锡二卤化物和双假卤化物配合物的合成和119Mmössbauer光谱
    标题:一些具有氮和氧供体配体的二卤代二有机锡二卤化物和双假卤化物配合物的合成和119Mmössbauer光谱
    摘要:合成和119米的类型r的114个络合物的sn穆斯堡尔谱2 Snx 2,L 2(rme等,正pr,正丁基,正-十月中,Ph,Bz; X氟,氯,溴,I,Ncs,L 2 2单齿或二齿1 O-或n-供配体(S)),其中74个是新的,则报告.大部分复合物是同构的,具有八面体反式-R 2 Snx 4几何约锡,而二苯基复合物5(rph值; X氯,L 2 amp,Nphen; Xncs,L 2  Bipy,Phen,Tmphen)采用顺式-R 2 Snx 4八面体结构.
    Doi:10.1016/s0022-328X(00)85834-9

    专利信息


    专利号:US-2024368099-A1
    优先权日:2022-01-18
    标 题:Methods for the synthesis of di(hydroxymethyl)tetrahydrofuran and its application in polyesters and polyurethanes
    发明人:SPIEGELBERG BRIAN; BRANDT ADRIAN; BECK HORST; KUX ALEXANDER; TIN SERGEY; DE VRIES JOHANNES GERARDUS
    权利人:HENKEL AG & CO KGAA
    摘要:The present invention relates to the synthesis of di(hydroxymethyl)tetrahydrofuran (DHMTHF) and the preparation of trans-enriched mixtures of DHMTHF. The invention further refers to polyester polyols which are obtained by reaction of cis/trans DHMTHF mixtures with a dicarboxylic acid. The invention further relates to polyurethanes and compositions containing a polyester polyol comprising DHMTHF, in particular to such polyurethane-containing (adhesive) compositions.

    专利号:US-10294336-B2
    优先权日:2014-11-27
    标题 :Synthesis of polymer polyols in unsaturated polyols, polymer polyols and their use
    发明人:KOENIG CHRISTIAN; EMGE ANDREAS; OTERO MARTINEZ IRAN
    权利人:BASF SE
    摘要:The present invention relates to the synthesis of polymer polyols in unsaturated polyols as liquid phase, polymer polyols and their use.

    专利号:US-2024383928-A1
    优先权日:2021-07-30
    标 题:Production of diorganotin dihalides
    发明人:VINCENT ROBERT; ZIMMERMANN JARROD C
    权利人:MERCK PATENT GMBH
    摘要:The disclosed and claimed subject matter relates to the safe and efficient synthesis of diorganotin dihalide compounds of the formula R2SnX2 that as-synthesized are free of tetraalkyltin (R4Sn), trialkyltin halide (R3SnX) and monoalkyltin trihalide (RSnX3) species and of methods for their synthesis and use.

    专利号:US-6624116-B1
    优先权日:1998-09-03
    标 题 :On-line synthesis and regeneration of a catalyst used in autothermal oxidation
    发明人:BHARADWAJ SAMEER S; MAJ JOSEPH J; SIDDALL JONATHAN H
    权利人:DOW GLOBAL TECHNOLOGIES INC
    摘要:An on-line method of synthesizing or regenerating catalysts for autothermal oxidation processes, specifically, the oxidation of paraffinic hydrocarbons, for example, ethane, propane, and naphtha, to olefins, for example, ethylene and propylene. The catalyst comprises a Group 8B metal, for example, a platinum group metal and, optionally, a promoter, such as tin, antimony, or copper, on a support, preferably a monolith support. On-line synthesis or regeneration involves co-feeding a volatile Group 8B metal compound and/or a volatile promoter compound with the paraffinic hydrocarbon and oxygen into the oxidation reactor under ignition or autothermal conditions.

    专利号:US-2018009956-A1
    优先权日:2014-11-27
    标题 :Synthesis of polymer polyols in unsaturated polyols, polymer polyols and their use

    专利号:US-8329923-B2
    优先权日:2010-06-17
    标 题:4, 4′ disubstituted 4H-cyclopentadithiophene and new methods for synthesizing the same
    发明人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH
    权利人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH; IMEC; UNIV HASSELT
    摘要:The present preferred embodiments relate to a method for the synthesis of a compound having the following general formula: n nthe method comprising the step of reacting, in presence of a diprotic acid having a negative pKa, a compound having the general formula:n n nwherein R 1 and R 2 are organic groups and wherein X and Y are independently selected from the group consisting of hydrogen, chloro, bromo, iodo, boronic acid, boronate esters, borane, pseudohalogen and organotin. It further relates to compounds so obtained and to compounds resulting from the ring closure of compound (II).

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Metallacycle Transfer From Zirconium To Main Group Elements: A Versatile Synthesis Of Heterocycles
    作者:Paul J. Fagan,William A. Nugent,Joseph C. Calabrese |发布日期:1994.3
    摘要:The Reaction Of Zirconium Metallacycles Is Used To Produce A Variety Of Main Group Heterocycles Including Borole Diels-Alder Dimers, Galloles, Indacyclopentadienes, Siloles, Germoles, Stannoles, Phospholes, Arsoles, Stiboles, Bismoles, Thiophenes, Selenophenes, Dihydrothiophenes, Dihydroselenophenes, Tetrahydrothiophenes, Tetrahydroselenophenes, Stannacyclopentanes, Phospholenes, And Isothiazoles.

    合成参考文献


    摘要:Ramirez y Medina, I.-M.; Kipke, W.; Makow, J.; Staubitz, A., Science of Synthesis Knowledge Updates, (2020) 2, 43.
    摘要:Marschner, C., Science of Synthesis Knowledge Updates, (2022) 3, 136.
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