专利号:US-2024368099-A1 优先权日:2022-01-18 标 题:Methods for the synthesis of di(hydroxymethyl)tetrahydrofuran and its application in polyesters and polyurethanes 发明人:SPIEGELBERG BRIAN; BRANDT ADRIAN; BECK HORST; KUX ALEXANDER; TIN SERGEY; DE VRIES JOHANNES GERARDUS 权利人:HENKEL AG & CO KGAA 摘要:The present invention relates to the synthesis of di(hydroxymethyl)tetrahydrofuran (DHMTHF) and the preparation of trans-enriched mixtures of DHMTHF. The invention further refers to polyester polyols which are obtained by reaction of cis/trans DHMTHF mixtures with a dicarboxylic acid. The invention further relates to polyurethanes and compositions containing a polyester polyol comprising DHMTHF, in particular to such polyurethane-containing (adhesive) compositions.
专利号:US-10294336-B2 优先权日:2014-11-27 标题 :Synthesis of polymer polyols in unsaturated polyols, polymer polyols and their use 发明人:KOENIG CHRISTIAN; EMGE ANDREAS; OTERO MARTINEZ IRAN 权利人:BASF SE 摘要:The present invention relates to the synthesis of polymer polyols in unsaturated polyols as liquid phase, polymer polyols and their use.
专利号:US-2024383928-A1 优先权日:2021-07-30 标 题:Production of diorganotin dihalides 发明人:VINCENT ROBERT; ZIMMERMANN JARROD C 权利人:MERCK PATENT GMBH 摘要:The disclosed and claimed subject matter relates to the safe and efficient synthesis of diorganotin dihalide compounds of the formula R2SnX2 that as-synthesized are free of tetraalkyltin (R4Sn), trialkyltin halide (R3SnX) and monoalkyltin trihalide (RSnX3) species and of methods for their synthesis and use.
专利号:US-6624116-B1 优先权日:1998-09-03 标 题 :On-line synthesis and regeneration of a catalyst used in autothermal oxidation 发明人:BHARADWAJ SAMEER S; MAJ JOSEPH J; SIDDALL JONATHAN H 权利人:DOW GLOBAL TECHNOLOGIES INC 摘要:An on-line method of synthesizing or regenerating catalysts for autothermal oxidation processes, specifically, the oxidation of paraffinic hydrocarbons, for example, ethane, propane, and naphtha, to olefins, for example, ethylene and propylene. The catalyst comprises a Group 8B metal, for example, a platinum group metal and, optionally, a promoter, such as tin, antimony, or copper, on a support, preferably a monolith support. On-line synthesis or regeneration involves co-feeding a volatile Group 8B metal compound and/or a volatile promoter compound with the paraffinic hydrocarbon and oxygen into the oxidation reactor under ignition or autothermal conditions.
专利号:US-2018009956-A1 优先权日:2014-11-27 标题 :Synthesis of polymer polyols in unsaturated polyols, polymer polyols and their use
专利号:US-8329923-B2 优先权日:2010-06-17 标 题:4, 4′ disubstituted 4H-cyclopentadithiophene and new methods for synthesizing the same 发明人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH 权利人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH; IMEC; UNIV HASSELT 摘要:The present preferred embodiments relate to a method for the synthesis of a compound having the following general formula: n nthe method comprising the step of reacting, in presence of a diprotic acid having a negative pKa, a compound having the general formula:n n nwherein R 1 and R 2 are organic groups and wherein X and Y are independently selected from the group consisting of hydrogen, chloro, bromo, iodo, boronic acid, boronate esters, borane, pseudohalogen and organotin. It further relates to compounds so obtained and to compounds resulting from the ring closure of compound (II).
参考标题:Metallacycle Transfer From Zirconium To Main Group Elements: A Versatile Synthesis Of Heterocycles 作者:Paul J. Fagan,William A. Nugent,Joseph C. Calabrese |发布日期:1994.3 摘要:The Reaction Of Zirconium Metallacycles Is Used To Produce A Variety Of Main Group Heterocycles Including Borole Diels-Alder Dimers, Galloles, Indacyclopentadienes, Siloles, Germoles, Stannoles, Phospholes, Arsoles, Stiboles, Bismoles, Thiophenes, Selenophenes, Dihydrothiophenes, Dihydroselenophenes, Tetrahydrothiophenes, Tetrahydroselenophenes, Stannacyclopentanes, Phospholenes, And Isothiazoles.
合成参考文献
摘要:Ramirez y Medina, I.-M.; Kipke, W.; Makow, J.; Staubitz, A., Science of Synthesis Knowledge Updates, (2020) 2, 43. 摘要:Marschner, C., Science of Synthesis Knowledge Updates, (2022) 3, 136.