专利号:US-11767388-B1 优先权日:2019-09-18 标 题 :Silicon-functionalized rubber 发明人:ENSIGN SETH CODY; VIELHABER MARGARET FLOOK; JOHNGRASS JENA LYNN; MA LIQING 权利人:GOODYEAR TIRE & RUBBER 摘要:The compatibility between silica fillers and synthetic rubbers which are synthesized utilizing lanthanide-based catalyst systems, such as neodymium catalyst systems can be improved by terminating the polymerization with a vinyl silane terminating agent. In doing so the vinyl silane is allowed to react with the polymer chain ends of the neodymium rubber to functionalize the chain ends of the polymer chains with silicon containing groups. This results in the rubber having better characteristics for utilization in tire rubber formulations, such a tire tread formulations, that exhibit improved wear characteristics and lower rolling resistance. The process for the synthesis of such functionalized polydiene rubber comprises (1) polymerizing a diene monomer in the presence of a lanthanide-based catalyst system, and (2) terminating the polymerization with a vinyl silane terminator. The functionalized polydiene rubber composition made by this method is comprised of a polydiene rubber which is functionalized at its chain ends with a silicon containing group.
专利号:US-7776250-B2 优先权日:2004-09-15 标 题:Imprinted polymer support 发明人:LOW HONG YEE; PARAPPUVEETIL SARANGADHARAN SURESH; KONG YEN PENG; DARMONO KARAN 权利人:AGENCY SCIENCE TECH & RES 摘要:There is disclosed an imprinted polymer support for solid phase organic synthesis (SPOS). The polymer support being obtainable from a method that comprises providing a substrate and a mold, the mold having a defined surface pattern. A composition is placed between the defined surface pattern of the mold and the substrate. The composition comprises a polymerisation medium with at least one functional monomer and a free radical initiator. The composition is polymerised to form an array of polymer imprints adhered to the substrate.
专利号:US-6384172-B1 优先权日:2001-01-02 标题:Hyperbranched polycarbosilanes, polycarbosiloxanes, polycarbosilazenes and copolymers thereof 发明人:DVORNIC PETAR R; HU JIN; MEIER DALE J; NOWAK ROBERT M 权利人:MICHIGAN MOLECULAR INST 摘要:Hyperbranched polycarbosilanes, polycarbosiloxanes, polycarbosilazenes and copolymers thereof are prepared by reacting a difunctional or polyfunctional monomer having functional groups of one type (A) without any other functional groups capable of reacting significantly during polymerization, and a difunctional or polyfunctional monomer having functional groups of another type (B) without any other functional groups capable of reacting significantly during polymerization, wherein each A-functional group is reacted with a B-functional group, and wherein at least one of the monomers has a functionality of at least three. The process enables hyperbranched polycarbosilanes, polycarbosiloxanes, polycarbosilazenes and copolymers thereof to be prepared at a lower cost than with conventional synthesis processes, and provides greater flexibility in the preparation of a larger variety of different types of hyperbranched polycarbosilanes, polycarbosiloxanes, polycarbosilazenes and copolymers thereof.
专利号:CN-112661782-A 优先权日:2020-12-15 标 题:Low Free Chlorine One-Step Synthesis Process of Alkenyl Silane and Alkenyl Siloxane
参考文献:10.1007/s00289-010-0319-5 摘要:Schuller A, Delaite C, Farge H. Effect of a formulation named “Giral” on mechanical properties of a composite based on silica and unsaturated polyester resin. Polymer Bulletin. 2010 Jun 19;66(1):77–94. doi: 10.1007/s00289-010-0319-5. 参考文献:10.1007/978-3-7091-0421-7_8 摘要:Stana-Kleinschek K, Ehmann HMA, Spirk S, Doliška A, Fasl H, Fras-Zemljič L, Kargl R, Mohan T, Breitwieser D, Ribitsch V. Cellulose and Other Polysaccharides Surface Properties and Their Characterisation. 2012. In: The European Polysaccharide Network of Excellence (EPNOE). : Springer Vienna; 2012.