以 Neat (No Solvent) 用作溶剂,化学反应生成七氧化二铼 参考文献:The Bridging Bidentate Perchlorato Group In Reo3(Clo4),Reo3(Clo4)Cl2O6 And Sb2Cl6(O)(Oh)(Clo4),A Vibrational Analysis 标题:The Bridging Bidentate Perchlorato Group In Reo3(Clo4),Reo3(Clo4)Cl2O6 And Sb2Cl6(O)(Oh)(Clo4),A Vibrational Analysis 摘要:Raman And Infrared Analysis Of The New Compounds: Reo3(Clo4),An Ivory-White Solid,And (Clo2)(X)Reo3(Clo(4))(1+x),(X Less Than Or Equal To 1),An Orange-Red Chloryl Salt,Showed That Bridging Bidentate [clo4] And Terminal Reo3 Groups Are Present In Both Complexes. Vibrational Data On [clo4] In Reo3(Clo4) Were Compared To Those Obtained Experimentally And By Dft Calculation On A Bridging Bidentate [clo4] In Sb2Cl6(O)(Oh)(Clo4). (C) 2002 Elsevier Science B.V. All Rights Reserved. Doi:10.1016/s1386-1425(02)00073-2
参考标题:Behaviour Of Dimeric Methylrhenium(Vi) Oxides In The Presence Of Hydrogen Peroxide And Its Consequences For Oxidation Catalysis 作者:Alexandra M. J. Rost,Andrea Scherbaum,Wolfgang A. Herrmann,Fritz E. Kühn 摘要:Enium(Vi)], Slow Conversion To The Monomeric Mono- And Bis-Peroxo Congenes Of Mto Occurs. Furthermore, Part Of The Re(Vi) Starting Complex Is Transformed Into Inactive Perrhenate. While Bis[dimethyl(μ-Oxo)Oxorhenium(Vi)] Might Be Applied (Also In A Mixture With Mto) As An Oxidation Catalyst Precursor, (μ-Oxo)Bis[trimethyloxorhenium(Vi)] Can Be Applied As A Useful Precursor For The Synthesis Of Tri
合成参考文献
摘要:Kühn, F. E.; Romäo, C. C.; Herrmann, W. A., Science of Synthesis, (2003) 2, 142. 摘要:Kühn, F. E.; Romäo, C. C.; Herrmann, W. A., Science of Synthesis, (2003) 2, 128. 摘要:Kühn, F. E.; Romäo, C. C.; Herrmann, W. A., Science of Synthesis, (2003) 2, 119. 摘要:Murahashi, S.-I., Science of Synthesis, (2004) 19, 383. 摘要:Heydt, H., Science of Synthesis, (2004) 27, 917.