专利号:US-2019211134-A1 优先权日:2016-08-19 标 题 :Thiourethane polymers, method of synthesis thereof and use in fused filament fabrication printing 发明人:ELLSON GREGORY T; LUND BENJAMIN R; VOIT WALTER 权利人:BOARD OF REGENTS THE UNIV OF TEXAS; ADAPTIVE 3D TECH 摘要:A thermoplastic thiourethane polymer comprising a sequential chain of a first type of monomer covalently bonded to a second type of monomer via thiourethane linkages. The first type of monomer includes two or more thiol functional groups and the type of monomer includes two or more isocyanate functional groups. The first and second types of monomers are polymerized together in an anhydrous aprotic solvent-dissolved anionic step-growth polymerization reaction that is catalyzed by a non-nucleophillic base having a pKa greater than 7.
专利号:US-2024158826-A1 优先权日:2022-11-16 标 题 :Preparation method of synthetase for continuous monitoring of blood glucose 发明人:ZHANG SHAODA; QIU ZHIPENG; ZHENG XINGYU 权利人:ZHANG SHAODA; QIU ZHIPENG; ZHENG XINGYU 摘要:The present invention discloses a preparation method of a synthetase for continuous monitoring of blood glucose. The method includes the preparation steps of step S1: hydroxylation of a glass bead; step S2: silanization of the glass bead; step S3: bonding of the glass bead to glucose; step S4: synthesis of a polymer particle on the surface of the glass bead to form a glucose synthetase; and step S5: separation of the highly specific glucose synthetase. According to the preparation method of a synthetase for continuous monitoring of blood glucose provided by the present invention, the glass bead is bonded to the glucose by activating the surface of the glass bead, and then bonded to a polymer to form the glucose synthetase. The artificial synthetase prepared by the method has low sensitivity to temperature and pH value, and can be directly used in a blood glucose electrochemical sensor.
专利号:US-10899072-B2 优先权日:2016-03-15 标题:Thiourethane polymers, method of synthesis thereof and use in additive manufacturing technologies 发明人:ELLSON GREGORY T; LUND BENJAMIN R; VOIT WALTER 权利人:UNIV TEXAS; ADAPTIVE 3D TECH; BOARD OF RESENTS THE UNIV OF TEXAS SYSTEM 摘要:A semi-crystalline thiourethane polymer. The semi-crystalline thiourethane polymer comprises a sequential chain of a first type of monomer covalently bonded to a second type of monomer via thiourethane linkages. Each of the first type of monomer includes two or more thiol functional groups and each of the second type of monomer includes two or more isocyanate functional groups. The first and second types of monomers are polymerized together in an anionic step-growth polymerization reaction that is catalyzed by a non-nucleophillic base having a pKa greater than 7, produced by photo-initiated decomposition of a photolatent base. A method of synthesizing, and polymer jetting and stereolithography methods of manufacturing a polymer part, are also disclosed.
专利号:US-9505880-B2 优先权日:2013-06-04 标题 :Synthesis of polyfunctional polyol acrylates 发明人:MCCARTHY KEVIN ROBERT; NIU WEIJUN; SCHISSEL DAVID NEAL; WALLACE ARTHUR LAWRENCE 权利人:CORNING INC 摘要:A method of synthesizing urethane-free polyfunctional acrylate compounds. The method includes reaction of a polyol with acrylic acid in the presence of an inhibitor. A catalyst may also be present. The catalyst may be an acid and the inhibitor may be a substituted phenol compound. Excess acid may be removed by adding a salt and excess water may be removed by adding a drying agent. The reaction converts alcohol groups of the polyol to acrylate groups to provide a radiation-curable polyfunctional acrylate compound. The reaction is applicable to polyols generally and provides a scalable high yield process for forming urethane-free polyfunctional acrylates over a wide range of molecular weights. Coatings made from the acrylate products exhibit modulus and tensile strength characteristics favorable for primary fiber coatings.
专利号:US-2021238374-A1 优先权日:2020-02-04 标 题 :Templated synthesis of nanovoided polymers 发明人:YE SHENG; LANDIG RENATE EVA KLEMENTINE; DIEST KENNETH ALEXANDER; OUDERKIRK ANDREW JOHN; BOWMAN CHARLES ROBERT; BOWMAN ROBERT G; HENDRICKSON WILLIAM ARTHUR; RUEB CHRISTOPHER J; PURVIS II LAFE JOSEPH; SUN WENMO; LI RYAN; YAROSHCHUK OLEG; RAO TINGLING; BOROMAND ARMAN; ZHAO CHURNING; Khaleghimeybodi Morteza 权利人:FACEBOOK TECH LLC 摘要:A method of forming a voided polymer includes forming a polymerizable composition containing a polymer precursor and a solid templating agent, forming a coating of the polymerizable composition, processing the coating to form a cured polymer material having a solid phase in a plurality of defined regions, and removing at least a portion of the solid phase from the cured polymer material to form a voided polymer layer.
专利号:US-3886201-A 优先权日:1971-11-17 标 题:Perfluoroalkyl esters of mercapto- and thio-carboxylic acids 发明人:FALK ROBERT ALLAN; KLEINER EDUARD KARL 权利人:CIBA GEIGY CORP 摘要:Novel perfluoroalkyl group containing mercaptans and sulfides are disclosed having soil repellent properties if applied to substrates such as textiles, paper and leather and being useful as intermediates for the synthesis of soil repellent polymers. The adducts are obtained by the base or free radical catalyzed addition of hydrogen sulfide or mono- or polymercaptans to perfluoroalkyl group containing esters of fumaric, maleic, citraconic, mesaconic, itaconic, methylene malonic or aconitic acid.
参考文献:10.1021/la060625w 摘要:Perl A, Péter M, Ravoo BJ, Reinhoudt DN, Huskens J. Heavyweight dendritic inks for positive microcontact printing. Langmuir. 2006 Aug 29;22(18):7568–73. doi: 10.1021/la060625w. 参考文献:10.1002/jbm.b.31539 摘要:Blakely B, Hoon Lee B, Riley C, McLemore R, Pathak CP, Vernon BL. Formulation and characterization of radio-opaque conjugated in situ gelling materials. J Biomed Mater Res B Appl Biomater. 2010 Apr;93(1):9–17. doi: 10.1002/jbm.b.31539.