乙烯双(三苯基磷)铂置于三苯基膦体系中,用 Neat (No Solvent) 用作溶剂,化学反应生成四(三苯基膦)铂 参考文献:Synthesis Of A Platinum(0) Ethylene Complex By The Hydrazine Method 标题:Synthesis Of A Platinum(0) Ethylene Complex By The Hydrazine Method 摘要: Doi:10.1007/bf00955386
专利信息
专利号:US-7605218-B2 优先权日:2004-02-03 标题:Synthesis of elastomeric carborane-siloxanes by hydrosilation reactions 发明人:KELLER TEDDY M; KOLEL-VEETIL MANOJ K 权利人:US NAVY 摘要:A carborane-siloxane compound is provided having the repeat unit n nQ contains any of —SiR 2 —, —SiR 2 —O—, —C≡C—C≡C—, carboranyl, and U′. Each R and R′ is alkyl, aryl, alkylaryl, haloalkyl, haloaryl, or mixtures thereof. Each U′ is derivable from hydrosilation of an alkenyl or alkynyl group. Each T is alkyl, aryl, alkylaryl, haloalkyl, haloaryl mixtures thereof, —(O—SiR′ 2 ) x H, or the repeat unit. Each x and x′ is a positive integer. The compounds may be made be reacting a carborane-siloxane precursor having unsaturated end groups with a siloxane crosslinker in the presence of a hydrosilation catalyst.
专利号:US-6302940-B2 优先权日:1999-07-26 标 题 :Chemical synthesis of monodisperse and magnetic alloy nanocrystal containing thin films 发明人:MURRAY CHRISTOPHER BRUCE; SUN SHOUHENG; WELLER DIETER K 权利人:IBM 摘要:A method and structure for forming magnetic alloy nanoparticles includes forming a metal salt solution with a reducing agent and stabilizing ligands, introducing an organometallic compound into the metal salt solution to form a mixture, heating the mixture to a temperature between 260° and 300° C., and adding a flocculent to cause the magnetic alloy nanoparticles to precipitate out of the mixture without permanent agglomeration. The deposition of the alkane dispersion of FePt alloy particles, followed by the annealing results in the formation of a shiny FePt nanocrystalline thin film with coercivity ranging from 500 Oe to 6500 Oe.
专利号:EP-1892237-A1 优先权日:2004-01-28 标 题 :Vinylchloroformate-free synthesis of vinyl and allyl(thio)carbamates 发明人:SEELYE DAVID E; KUNZLER JAY F; SALAMONE JOSEPH C 权利人:BAUSCH & LOMB 摘要:The invention generally relates to methods of forming allyl(thio)carbamates and more particularly to a method of synthesizing allyl(thio)carbamates that does not necessitate the use of phosgene and organomercury intermediates.
专利号:US-7402689-B2 优先权日:2004-01-28 标 题 :Vinylchloroformate-free synthesis of vinyl and allyl(thio) carbamates 发明人:SEELYE DAVID E; KUNZLER JAY F; SALAMONE JOSEPH C 权利人:BAUSCH & LOMB 摘要:The invention generally relates to methods of forming vinyl(thio)carbamates and more particularly to a vinylchloroformate-free method of synthesizing (N-vinyloxycarbonyl)-3-aminopropyltris(trimethylsiloxysilane).
专利号:US-7202375-B2 优先权日:2003-05-30 标 题:Bissilylamino group-bearing chlorosilane compound and preparation method, and method of preparing bissilylamino group-bearing organooxysilane compound 发明人:TONOMURA YOICHI; KUBOTA TOHRU 权利人:SHINETSU CHEMICAL CO 摘要:Bissilylamino group-bearing chlorosilane compounds of formula (1):n n[(CH 3 ) 3 Si] 2 NCH 2 CH 2 CH 2 Si(CH 3 ) n Cl 3−n   (1)n nwherein n is 0 or 1 are novel. They are useful as silane coupling agents and surface treating agents. They can be readily converted, through reaction with alcohols, to bissilyl group-bearing alkoxysilane compounds which are useful as intermediates for the synthesis of aminopropyl-modified silicone oil. The invention also provides an industrially advantageous method capable of preparing the bissilylamino group-bearing chlorosilane compounds.
专利号:US-2025011272-A1 优先权日:2021-09-23 标 题:Long-chain compound that acts on acly, preparation method therefor and use thereof 发明人:NAN FAJUN; LI JINGYA; CHEN YI; Song Gaolei; XIE ZHIFU; FANG YANFEN; ZHANG MEI; SUN XINYU; CAO LEI; MA HUI; YANG YUROU 权利人:SHANGHAIINSTITUTE OF MATERIA MEDICA CHINESE ACAD OF SCIENCES 摘要:A long-chain compound, a preparation method therefor and the use thereof are disclosed. The structure of said compound is represented by formula (I). The definition of each substituent in the formula is as set out in the description and claims. The compound can directly inhibit ACLY, inhibit lipid synthesis in primary hepatocytes, inhibit lipid de novo synthesis and histone acetylation in various cancer cells such as H358, and inhibit cancer cell proliferation. The compound may be used to prepare drugs that treat metabolic diseases such as hyperlipidemia and atherosclerosis or various cancers such as lung cancer, pancreatic cancer, breast cancer, ovarian cancer, liver cancer, intestinal cancer, brain cancer, and acute myeloid leukemia.