CAS: 111-63-7; Vinyl Stearate (Stabilized With Mehq)

该化合物是一种有机化合物,被归类为乙烯酯,具体地说,是乙烯醇和石酸酯酯酯,一种无色的黄黄色液体,具有独特的气味.乙烯蒸酸盐的化学配方为C18H34O2,其分子重量约为282.46克/摩尔.该化合物以其在水中的低溶解性而著称,但在乙醇和乙醇等有机溶剂中可溶解.乙烯蒸酸盐主要用于生产聚合物和共聚物,在包括涂层,粘合剂和塑料在内的各种应用中作为单体.它具有良好的热稳定性,可通过自由的激进机制进行聚合.此外,乙烯蒸酸盐可以作为表面活性剂和乳化剂,增强它所加入的配方的特性.安全考虑包括在经过通风的地区处理它,并使用适当的个人防护设备,因为接触时可能会造成皮肤和眼刺激.

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相似化合物

5809-91-6 111-81-9 25601-41-6

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CAS号57-11-4 硬脂酸 | CAS号74-86-2 乙炔 | CAS号108-05-4 乙酸乙烯酯 | CAS号74-98-6 丙烷 | CAS号75-07-0 乙醛 | CAS号112-76-5 十八碳酰氯 | CAS号27098-24-4 1-硬脂酰-2-亚油酰基-sn... | CAS号816-94-4 二硬脂酰磷脂酰胆碱 | CAS号17364-19-1 ()-(7-hydroxy-4... | CAS号57-11-4 硬脂酸 | CAS号10287-60-2 2-aminoethyl st... | CAS号111-57-9 硬脂酰胺MEA | CAS号34487-26-8 1-硬脂酰基-2-亚油酰基-sn-甘油 | CAS号19420-57-6 1-硬脂酰-SN-甘油-3-磷酰胆碱 | CAS号18194-24-6 二肉豆蔻酰磷脂酰胆碱(DMPC)

合成工艺路线路线简述

    📜硬脂酸,乙炔置于马来酸酐,三丁基膦,Bis(η5-Cyclooctadienyl)Ruthenium体系中,用 甲苯 用作溶剂,化学反应 4.0H,以77%的收率获得硬脂酸酯乙烯基
    参考文献:Ruthenium-Catalyzed Selective Addition Of Carboxylic Acids To Alkynes. A Novel Synthesis Of Enol Esters
    标题:Ruthenium-Catalyzed Selective Addition Of Carboxylic Acids To Alkynes. A Novel Synthesis Of Enol Esters
    摘要:
    Doi:10.1021/jo00387A024

    海关参考信息

    专利信息


    专利号:WO-0134589-A1
    优先权日:1999-11-05
    标 题 :Semi-synthesis of baccatin iii from 9-dihydro-13-acetylbaccatin iii
    发明人:ZAMIR LOLITA
    权利人:ZAMIR LOLITA
    摘要:The present invention relates to a semi-synthetic process to convert a naturally occurring taxane into a suitable starting material for the synthesis of paclitaxel and related compounds. Specifically, the present invention relates to a process for the conversion of 9-dihydro-13-acetylbaccatin III into baccatin III which can then be used as starting material for the synthesis of taxane derivatives such as paclitaxel, docetaxel, cephalomannine and other taxanes structurally related to baccatin III.

    专利号:US-8053522-B2
    优先权日:2006-02-28
    标题 :Synthesis of polyester-graft-poly(meth)acrylate copolymers
    发明人:LOEHDEN GERD; BALK SVEN; BRAND THORSTEN; BRENNER GABRIELE; ARNOLD THOMAS; BAUMANN CORNELIA
    权利人:EVONIK ROEHM GMBH
    摘要:The present invention relates to a novel synthesis of (meth)acrylate-grafted polyesters and their action as compatibilizers.

    专利号:US-7189849-B2
    优先权日:1997-02-10
    标 题:Synthesis of acyclic nucleoside derivatives
    发明人:LEANNA M ROBERT; RASMUSSEN MICHAEL; HANNICK STEVEN M; TIEN JIEN-HEH J; LUKIN KIRILL A; TIAN ZHENPING; CHANG SOU-JEN; CURTY CYNTHIA B; NARAYANAN BIKSHANDARKOIL A; BELLETTINI JOHN; SHELAT BHADRA; SPITZ TIFFANY
    权利人:MEDIVIR AB
    摘要:Novel processes towards the synthesis of the antiviral valomaciclovir stearate in which an esterified guanine acetal is reduced to the corresponding alcohol, reacted with an activated amino acid and N-deprotected. The esterified guanine acetal is prepared from a 9-guanine derivative bearing an acyclic hydroxymethylbutylacetal. The processes are amendable to one-pot reactions.

    专利号:WO-9723519-A1
    优先权日:1995-12-21
    标题:Synthesis of aqueous, anionic, amino acrylate polymers
    发明人:DAS SURYYA K; KILIC SONER
    权利人:PPG INDUSTRIES INC
    摘要:Disclosed is a method of making aqueous, anionic amino polymers in water from olefinically unsaturated monomers including amine-containing monomers, but substantially without the inclusion of acid-group containing monomers. The polymerization of the amino polymer is carried out in the presence of a carboxy functional azo initiator dissolved in water by neutralization of acid groups present on the initiator. The polymer is useful in single-package or two-package coating compositions having pH above 7.0 that may be cured with polyisocyanates or polyepoxides.

    专利号:US-5541273-A
    优先权日:1993-11-12
    标 题 :Method for preparing poly(vinyl trifluoroacetate) and poly(vinyl trifluoroacetate/vinyl ester) in the absence of chlorofluorocarbon solvent
    发明人:EIAN GILBERT L
    权利人:MINNESOTA MINING & MFG
    摘要:A method for the production of poly(vinyl trifluoroacetate) and copolymers thereof with vinyl esters is described. Poly(vinyl trifluoroacetate) (PVTFA) is obtained in essentially quantitative yield under mild conditions by using non-chlorofluorocarbon solvents comprising siloxanes or perfluorinated fluid. Hexamethyl disiloxane is a particularly useful example of such solvents. Synthesis of syndiotactic PVTFA on a commercial scale without the use of environmentally-harmful solvents is made possible by the invention, which provides a convenient commercial route to syndiotactic polyvinyl alcohol.

    专利号:US-11859029-B2
    优先权日:2018-07-25
    标 题 :Methods of synthesis of homopolymers and non-homopolymers comprising repeating units derived from monomers comprising lactam and acryloyl moieties in an aqueous medium
    发明人:DEANE OLIVER JOHNATHAN; MUSA OSAMA M; ARMES STEVEN PETER; FERNYHOUGH ALAN; GIBSON REBECCA ROISIN
    权利人:ISP INVESTMENTS LLC
    摘要:The invention provides a method for preparation of homopolymers and non-homopolymers comprising polymerizing in an aqueous medium a monomer comprising at least one acryloyl moiety and at least one functionalized or unfunctionalized lactam moiety, and optionally at least one hydrophilic or hydrophobic comonomer, in the presence of at least one chain transfer agent and at least one non-radiation initiator. Exemplary diblock polymers prepared by the method have the structure:where subscripts x, y, and z and variables R, R8, R9 and R10 are described herein.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Eunae Cho, Et Al. Regioselective Self-Acylating Cyclodextrins In Organic Solvent. Sci Rep. 2016 Mar 29:6:23740.

    合成参考文献


    参考文献:10.1007/s11095-006-9072-8
    摘要:Hastedt JE, Wright JL. Percolative Transport and Cluster Diffusion Near and Below the Percolation Threshold of a Porous Polymeric Matrix. Pharmaceutical Research. 2006 Aug 24;23(10):2427–40. doi: 10.1007/s11095-006-9072-8.
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