CAS: 653589-95-8; Methyl 2-(4,4,5,5-Tetramethyl-1,3,2-Dioxaborolan-2-yl)Benzoate

上下游产品

CAS号93-58-3 苯甲酸甲酯 | CAS号73183-34-3 双戊酰二硼 | CAS号17763-70-1 Benzoic acid, 2... | CAS号610-94-6 2-溴苯甲酸甲酯 | CAS号25015-63-8 频那醇硼烷 | CAS号610-97-9 邻碘苯甲酸甲酯 | CAS号610-96-8 邻氯苯甲酸甲酯 | CAS号76-09-5 频哪醇 | CAS号374538-03-1 2-(甲氧基羰基)苯硼酸 | CAS号25991-27-9 2-氧代-2H-吡喃-3-甲酸甲酯 | CAS号1801-42-9 2.3-二苯基-1-二氢茚酮 | CAS号119-36-8 水杨酸甲酯

📜苯甲酸置于(1,5-Cyclooctadiene)(Methoxy)Iridium(I) Dimer,硫酸,5,5'-二(三氟甲基)-2,2'-联吡啶体系中,用 四氢呋喃,二氯甲烷 作为反应溶剂,化学反应 17.5H,反应生成 2-甲氧羰基苯硼酸频哪醇酯
参考文献:5-三氟甲基化联吡啶配体实现的铱催化芳族酰胺的邻位选择性硼酸化
标题:5-三氟甲基化联吡啶配体实现的铱催化芳族酰胺的邻位选择性硼酸化
摘要:仅仅在联吡啶配体的 5 位引入 Cf 3基团就促进了铱催化的苯甲酰胺和衍生物的硼酸化反应中区域选择性的显着变化,从间位/对位取代到邻位取代.计算和实验数据表明,这种效应与底物的羰基和配体的cf 3-Bipy 环之间不寻常的外球色散相互作用有关.
DOI:10.1002/anie.202214510

专利信息

专利号:US-10005796-B2
优先权日:2014-05-01
标 题 :Substituted angular bistetracenes and substituted angular bisoligoacenes and electronic devices made with same
发明人：BRISENO ALEJANDRO L; ZHANG LEI
权利人:UNIV MASSACHUSETTS
摘要:We report the synthesis and characterization of novel bistetracenes, an unconventional, linearly extended conjugated core with eight fused rings. Also described are bisoligoacenes. In general, the properties and stability of large polycyclic aromatic hydrocarbons (PAHs) strongly depend on the mode of ring annellation and the topology of their it-electron systems, which are usually associated with the resonance stabilization energy in large PAHs.