CAS: 1687-36-1; 1,3,5,7-Tetramethyladamantane

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    上下游产品

    propellane4,4,4propellane 1-Adamantyl bromide tetramethylsilane 1-chloroadamantane

    合成工艺路线路线简述

      📜金刚烷置于aluminum (III) Chloride,Aluminum Tri-Bromide,溴体系中,用 二氯甲烷 用作溶剂,化学反应 15.0H,反应生成1,3,5,7-四甲基金刚烷
      参考文献:金刚烷衍生物与四甲基硅烷的完全一步桥头甲基化
      标题:金刚烷衍生物与四甲基硅烷的完全一步桥头甲基化
      摘要:研究了 Alcl 3和四甲基硅烷的组合用于金刚烷衍生物的桥头甲基化.重排的影响用各种例子说明,合成效用通过反应的放大来证明.机理研究表明,形成了由四甲基硅烷和 Alcl 3形成的反应甲基化复合物.
      Doi:10.1002/ejoc.202101004

      专利信息


      专利号:US-7408085-B2
      优先权日:2006-11-28
      标 题:Rapid cost effective method for the synthesis of TPD-type arylamines
      发明人：BENDER TIMOTHY P; COGGAN JENNIFER A; MCGUIRE GREGORY; MURPHY LEANNE DAWN; TOTH ALAN EDWARD JOHN
      权利人:XEROX CORP
      摘要:A process for forming a tetra(aryl)-biphenyldiamine compound, including reacting a dibromobiphenyl compound and a diarylamine compound in the presence of a palladium ligated catalyst and a base.

      专利号:US-7402700-B2
      优先权日:2006-11-28
      标题 :Rapid, cost effective method for synthesis of diarylamine compounds
      发明人：BENDER TIMOTHY P; COGGAN JENNIFER A
      权利人:XEROX CORP
      摘要:A process for forming a diarylamine compound, including reacting an aniline and an arylbromide in the presence of a palladium ligated catalyst and a base.

      专利号:US-7345203-B1
      优先权日:2006-11-28
      标题:Cost effective method for synthesis of triarylamine compounds from an aniline and an arylchloride
      发明人：BENDER TIMOTHY P; COGGAN JENNIFER A
      权利人:XEROX CORP
      摘要:A process for forming a triarylamine compound, including reacting an aniline and an arylchloride in the presence of a ligated palladium catalyst and a base.

      专利号:US-7482492-B2
      优先权日:2007-04-12
      标 题 :Cost effective method for synthesis of triarylamine compounds
      发明人：COGGAN JENNIFER A; HU NAN-XING
      权利人:XEROX CORP
      摘要:A process for forming a triarylamine compound includes reacting a halogenated aryl alcohol with an alcohol protecting agent and a first base to form a halogenated protected aryl alcohol compound, and reacting the halogenated protected aryl alcohol compound with an amine in the presence of a suitable catalyst and a second base.

      专利号:US-2008125607-A1
      优先权日:2006-11-28
      标 题 :Rapid, cost effective method for synthesis of diarylamine compounds

      专利号:US-2008125608-A1
      优先权日:2006-11-28
      标 题 :Rapid cost effective method for the synthesis of tpd-type arylamines

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      主要参考文献

      参考标题:Propellanes-Ix
      作者:J. Altman,E. Cohen,T. Maymon,J.B. Petersen,N. Reshef,D. Ginsburg |发布日期:1969.1
      摘要:(Intramolecular) Dieckmann Condensations And A Propellane Tetraone By A Diels-Alder Reaction. The Synthesis Of Mixed Oxa-Thia And Polyoxa And Polythiat[3.3.3]Propellanes Is Described. Bis-Irontricarbonyl Derivatives Of Tetraenic Propallanes Have Been Prepared.

      合成参考文献


      参考文献:10.1007/978-3-642-71737-6_4
      摘要:Petrov AA. Cycloalkanes (Naphthenes). 1987. In: Petroleum Hydrocarbons.
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