CAS: 1120-34-9; (Z)-Methyl Docos-13-Enoate

该化合物是一种不饱和的脂肪酸甲基酯,其特点是其长的碳链和位于甲基端第13个碳点的双环结合,该化合物属于脂肪酸酯家族,通常来自天然来源,如植物油.该化合物无色可粉黄,具有温和的气味,在有机溶剂中可溶解,但由于其疏水性,其溶解性在水中有限.该二环结的存在有助于其流动性,影响其与饱和脂肪酸相比的熔点和沸点.甲基Cis-13-docosenoate对各种应用都感兴趣,包括作为潜在的生物燃料,化妆品和食品工业中的吸食剂或乳化剂.其化学结构允许各种反应,使其在有机合成和工业过程中成为多功能的化合物.应参考安全数据,以便处理和接触准则,以及任何化学物质.

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相似化合物

112-86-7 1120-25-8 2390-09-2

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CAS号67-56-1 甲醇 | CAS号143-07-7 月桂酸 | CAS号112-86-7 芥酸 | CAS号1679-53-4 10-羟基癸酸 | CAS号143-28-2 油醇 | CAS号112-62-9 油酸甲酯 | CAS号693-58-3 1-溴壬烷 | CAS号50530-12-6 10-溴代癸酸 | CAS号18107-18-1 (三甲硅烷)重氮甲烷 | CAS号71736-18-0 10-iododecanoic acid | CAS号111924-39-1 22-bromod°Cos-9-ene | CAS号506-37-6 神经酸 | CAS号872-05-9 正癸烯 | CAS号54716-25-5 methyl tetradec... | CAS号124-19-6 正壬醛 | CAS号111-66-0 1-辛烯 | CAS号29972-79-0 月桂酸甲酯 | CAS号629-98-1 顺-13-二十二烯醇 | CAS号58594-45-9 (Z)-13-十八碳烯醛

合成工艺路线路线简述

  • 合成目标产物 Erucic Acid Methyl Ester 主要起始原料 Methyl Oleate
  • (文献来源)合成步骤主要原料 Methyl Oleate
油酸甲酯置于lithium Aluminium Tetrahydride,四溴化碳,三苯基膦体系中,用 乙醚,二氯甲烷 用作溶剂,化学反应 19.0H,反应生成芥酸甲酯
参考文献:Kling,Marcel R.; Easton,Christopher J.; Poulos,Alf,Journal Of The Chemical Society. Perkin Transactions I,1993,# 10,P. 1183-1190
标题:Kling,Marcel R.; Easton,Christopher J.; Poulos,Alf,Journal Of The Chemical Society. Perkin Transactions I,1993,# 10,P. 1183-1190

海关参考信息

专利信息


专利号:US-2024110196-A1
优先权日:2022-08-29
标题 :Use of multigene stacking method in synthesis of nervonic acid in brassica napus
发明人:LIU FANG; WANG PANDI; WU GANG; XIONG XIAOJUAN
权利人:OIL CROPS RES INSTITUTE CAAS
摘要:The present disclosure relates to use of a multigene stacking method in synthesis of nervonic acid in Brassica napus. The present disclosure provides a multigene co-expression plant vector, including an initial backbone of pBWA(V)BII and multiple exogenous gene expression cassettes. The present disclosure further provides two plant vectors applicable to genetic transformation, including a three-gene co-expression plant vector and a five-gene co-expression plant vector. In the present disclosure, after the three-gene co-expression plant vector and the five-gene co-expression plant vector are separately transferred into the Brassica napus, the nervonic acid (NA) with a high content is synthesized in the Brassica napus through multigene co-expression. An NA ratio can be significantly increased combined with a higher seed oil content and a greater field seed yield. The plant vector realizes efficient synthesis of NA in oil crops, obtains NA-rich seed oil, and increases an added value of edible oil.

专利号:US-2014194584-A1
优先权日:2013-01-07
标题 :Process for the synthesis of w-Unsaturated nitrile-acid/ester in which two types of cross metathesis are alternated consecutively swing process
发明人:DUBOIS JEAN-LUC; COUTURIER JEAN-LUC
权利人:ARKEMA FRANCE
摘要:The invention relates to a process for the synthesis of a monounsaturated nitrile-ester (acid) by cross metathesis starting from an unsaturated compound I comprising at least one trivalent nitrile, acid or ester functional group, characterized in that it comprises a stage in which two types of cross metathesis are alternated consecutively:n a first type of cross metathesis cm1 with an acrylic compound II chosen from acrylonitrile, acrylic acid or an acrylic ester, one of the compounds I or II comprising a nitrile functional group and the other of these compounds II or I comprising an acid or ester functional group, and a second type of cross metathesis cm2 with a light C 2 to C 4 alkene compound III, preferably with ethylene. nn The invention also relates to a process for the synthesis of an α,ω-amino ester (acid) obtained by a process comprising a stage in which the two types of cross metathesis defined above are alternated consecutively, followed by a hydrogenation stage.

专利号:WO-2024112938-A1
优先权日:2022-11-22
标题:New method for the ozonolytic synthesis of high melting dicarboxylic acids and oxo-acids
发明人:FOLEY PATRICK; YANG YONGHUA
权利人:P2 SCIENCE INC
摘要:The present disclosure pertains to improved methods of preparing high melting dicarboxylic acids or oxo-acids (e.g., carboxylic acid/aldehydes) by ozonolysis of their esters. For example, the present disclosure provides methods for preparing brassylic acid by way of the ozonolysis of erucic acid ester, the method comprising the steps of converting the erucic acid to an ester, performing ozonolysis on the ester, and converting the resulting brassylate ester product to brassylic acid.

专利号:US-6852759-B2
优先权日:2002-03-28
标 题:Process for the synthesis of trans-alkenoic acids, use thereof
发明人:GUPTA VISHWA NATH; BHARDWAJ VIKRAM; SINGH BHUPINDER; CHANDAN BAL KRISHAN; SURI KRISHAN AVTAR; SATTI NARESH KUMAR; SURI OM PARKASH; HANDA SUKHDEV SWAMI
权利人:COUNCIL SCIENT IND RES
摘要:The present invention relates to a process for the preparation of trans-alkenoic acids of general formula CH 3 —(CH 2 )n—CHâ•?(CH 2 )mCO 2 H where n=4 to 9 m=8 to 16. More particularly, the present invention relates to a process for the preparation of trans-tetracos-15-enoic acid, which is a bioactive constituent possessing dose-related hepatoprotective activity. The present invention also relates to the use thereof for hepatoprotection.

专利号:US-2023095259-A1
优先权日:2020-06-01
标 题:Synthesis of pheromone derivatives via z-selective olefin metathesis

专利号:US-2015065682-A1
优先权日:2013-08-30
标 题 :Aliphatic polyesters and copolyesters derived from natural oils and their related physical properties
发明人:NARINE SURESH; BOUZIDI LAZIZ; LI SHAOJUN; JOSE JESMY; POURFALLAH GHAZALEH
权利人:ELEVANCE RENEWABLE SCIENCES
摘要:The synthesis of certain medium and long chain ω-hydroxy esters and certain ω-hydroxy fatty acids is disclosed. Such ω-hydroxy esters and ω-hydroxy fatty acids are derived from natural oils, and their corresponding polymers were obtained by melt polycondensation. Additionally, the present effort investigates the effects of structural and molecular parameters on the thermal and mechanical properties of ω-hydroxy ester based polymers. Additionally, the present effort investigates the co-polymerization of ω-hydroxy ester based polymers.
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主要参考文献

[参考文献]: Oier Aizpurua-Olaizola, Et Al. Optimization Of Supercritical Fluid Consecutive Extractions Of Fatty Acids And Polyphenols From Vitis Vinifera Grape Wastes. J Food Sci. 2015 Jan;80(1):E101-7.

合成参考文献


摘要:Couve-Bonnaire, S.; Castanheiro, T.; Bouillon, J.-P., Science of Synthesis: Modern Strategies in Organofluorine Chemistry, (2025) 2.
参考文献:10.1007/s00216-017-0222-0
摘要:Pojjanapornpun S, Aryusuk K, Lilitchan S, Krisnangkura K. Gibbs energy additivity approaches to QSRR in generating gas chromatographic retention time for identification of fatty acid methyl ester. Analytical and Bioanalytical Chemistry. 2017 Feb 06;409(11):2777–89. doi: 10.1007/s00216-017-0222-0.
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