CAS: 1027757-13-6; 2-(2-(Benzyloxy)Phenyl)-4,4,5,5-Tetramethyl-1,3,2-Dioxaborolane
该化合物是一种有机有机体化合物,其特征是含有一种碳酸性功能组和一种乙醇酸酯.该化合物一般显示白色和白色外的固体外观,在二氯甲烷和乙乙酸乙酸等有机溶剂中可溶解,但水中溶解性较低.乙酸组允许与二醇发生可逆的共价结合,使其在各种应用中有用,包括有机合成和药用化学.其结构特征是代之以苯氧基组的苯基环,可增强其再活性和稳定性.
- 英文名称2-(2-(Benzyloxy)Phenyl)-4,4,5,5-Tetramethyl-1,3,2-Dioxaborolane
- 中文名称2-苄氧基苯硼酸频那醇酯
- IUPAC名称2-(2-(benzyloxy)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
- 其它别名2-(2-苄氧基苯基)-4,4,5,5-四甲基-1,3,2-二氧杂环戊硼烷; 2-Benzyloxyphenylboronic Acid Pinacol Ester
- CAS编号1027757-13-6
- MFCD编号:MFCD03001334
- EINECS号:172-443-9
- 分子式:C19H23BO3分子量:310.2
- 产品CID: 60702
- 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物
相似化合物
190661-29-1 2246645-45-2 935846-39-2物理性质
MSDS等安全信息
欧盟法规
C&L通报上下游产品
o-(benzyloxy)aniline bis(pinacol)diborane (4-(benzyloxy)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)(phenyl)iodonium tosylate 7-(2-(benzyloxy)phenyl)-5-methyl-2-((4-(methylsulphonyl)piperazin-1-yl)methyl)thieno[3,2-c]pyridin-4(5H)-one合成工艺路线路线简述
📜2-苄氧基苯胺置于bis(1,5-Cyclooctadiene)Nickel (0),甲酸,Potassium Tert-Butylate,Sodium Cyanoborohydride,1,3-二环己基氯化咪唑体系中,用 甲醇,乙二醇乙醚,甲苯 用作溶剂,化学反应 40.0H,反应生成2-苄氧基苯硼酸频那醇酯
参考文献:Nickel-Catalyzed Borylation Of Aryl-And Benzyltrimethylammonium Salts Via C-n Bond Cleavage
标题:Nickel-Catalyzed Borylation Of Aryl-And Benzyltrimethylammonium Salts Via C-n Bond Cleavage
摘要:By Developing A Mild Ni-Catalyzed System,A Method For Direct Borylation Of Sp(2) And Sp(3) C-N Bonds Has Been Established. The Key To This Hightly Efficient C-N Bond Borylative Cleavage Depends On The Appropriate Choice Of The Nickel Catalyst Ni(Cod)(2),Icy Center Dot Hcl As A Ligand,And The Use Of 2-Ethoxyethanol As The Cosolvent. This Transformation Shows Good Functional Group Compatibility And Can Serve As Powerful Synthetic Tool For Gram-Scale Synthesis And Late-Stage C-N Borylation Of Complex Compounds.
Doi:10.1021/acs.Joc.5B02557
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
参考DOI号:10.1021/acs.j°C.5b02557
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尽可能描述清楚需求与问题信息
