📜[cu(2,2'-Biimidazole)2(H2O)](Sif6)*h2O 以 Neat (No Solvent,Solid Phase) 用作溶剂,化学反应生成氟硅酸铜
参考文献:Synthesis,Characterization And Crystal Structures Of Supramolecular Complexes Of Copper(II)(2,2'-Biimidazole) Induced By Inorganic Counter Anions
标题:Synthesis,Characterization And Crystal Structures Of Supramolecular Complexes Of Copper(II)(2,2'-Biimidazole) Induced By Inorganic Counter Anions
摘要:Four New Complexes [cu(H(2)Biim)(2)(H(2)O)](No(3))(2) (1),[cu(H(2)Biim)(2)](Clo(4))(2)Center Dot 2Dmso (2),[cu(H(2)Biim)(2)] [i(0.36)Center Dot(No(3))(0.64)](2) (3) And {[cu(H(2)Biim)(2)(H(2)O)](Sif(6))}Center Dot H(2)O (4) (H(2)Biim = 2,2'-Biimdazole,Dmso = Dimethyl Sulfoxide) Have Been Synthesized And Characterized By X-Ray Diffraction. The Different Inorganic Anions No(3)(-),Clo(4)(-),[i(0.36)Center Dot(No(3))(0.64)](-) And Sif(6)(2-) In These Complexes Lead To Different 3D Structures. Among Them,Complex 3 Has An Interesting 3D Porous Structure With Two [i(0.36)Center Dot(No(3))(0.64)](-) Ions As Guests In The Cavity. Compound 4 Was Obtained By The Reaction Of Cu(Bf(4))(2) With H(2)Biim In Water In Glass Bottle. The Robust Hydrogen Bond Of Typev R(2)(1)(7) Played A Key Role In The Formation Of Sif(6)(2-) In Complex 4. (C) 2009 Elsevier Ltd. All Rights Reserved.
Doi:10.1016/j.Poly.2009.05.052