CAS: 919789-80-3; 4-(1,2,2-Triphenylvinyl)Aniline

该化合物是一种功能性有机化合物,其特征为与三联苯乙烯协会相联系的中央阴性组,具有独特的电子和消毒特性,在材料科学和光电子应用中具有价值;同系系统增强了荧光和充电运输特性,有利于开发有机光排放二极管(OLEDs)和其他光学装置;其矿物质组可以进一步功能化,为特定研究或工业需要作出量身定做的修改;该化合物的稳定性和明确界定的合成路径有助于其在实验和生产环境中的可靠性;对于先进的研究来说,它是一个适合高级研究的中间体,是设计高性能有机材料的关键中间体.

英文名称4-(1,2,2-Triphenylvinyl)Aniline
中文名称1-(4-氨基苯)-1,2,2-三苯乙烯
IUPAC名称4-(1,2,2-triphenylvinyl)aniline
CAS编号919789-80-3
MFCD编号:MFCD31697689
分子式:C26H21N分子量:347.45
产品CID: 1958090
产品分类有机原料 → 烃类化合物及其衍生物 → 芳香烃

相似结构搜索
InChIKey: WCNQRPKNQRXHQJ-UHFFFAOYSA-N
InChI=1S/C26H21N/c27-24-18-16-23(17-19-24)26(22-14-8-3-9-15-22)25(20-10-4-1-5-11-20)21-12-6-2-7-13-21/h1-19H,27H2
计算化学: 氢键受体数1.0氢键供体数1.0可旋转键数4.0

物理性质

熔点202.1-203.4 °C
沸点472.6±24.0 °C(预测)
密度1.128±0.06 g/cm3(预测)
pKa:4.16±0.10(预测)
PSA:26.02
LogP:6.8574
外观形态类白色至淡黄色固体
储存条件2-8°C, 避光
产品应用该化合物用作有机释放光二极管,液晶装置,超分子组件,药物运载系统和传感器.

MSDS等安全信息

GHS符号GHS07
警示词Warning
危险描述H302-H315-H319-H335
防范说明P261-P280-P301+P312-P302+P352-P305+P351+P338

上下游产品

1,1,2,2-四苯乙烯 1,1,2,2-Tetraphenylethylene 632-51-9
1-(4-硝基苯基)-1,2,2-三苯乙烯 (2-(4-Nitrophenyl)Ethene-1,1,2-Triyl)Tribenzene 166264-70-6
1-(4-溴苯基)-1,2,2-三苯乙烯 1-(4-Bromophenyl)Triphenylethene 34699-28-0
三苯溴乙烯 Triphenylvinyl Bromide 1607-57-4

合成工艺路线路线简述

166264-70-6 = 919789-80-3
反应条件:1.1 Reagents: Hydrazine Hydrate (1:1) Catalysts: Palladium Solvents: Ethanol; 4 H,Reflux
标题:Tetraphenylethylene Conjugated P-Hydroxyphenacyl: Fluorescent Organic Nanoparticles For The Release Of Hydrogen Sulfide Under Visible Light With Real-Time Cellular Imaging
作者:Parthiban,C.; M.,Pavithra; Reddy,L. Vinod Kumar; Sen,Dwaipayan; Samuel S.,Melvin; Et Al
参考文献:Organic & Biomolecular Chemistry 日期:2018 卷标:16(42) 页码:7903-7909]

166264-70-6 = 919789-80-3
反应条件:1.1 Reagents: Hydrazine Hydrate (1:1) Catalysts: Palladium Solvents: Ethanol; 4 H,Reflux
标题:A New Tict And Aie-Active Tetraphenylethene-Based Schiff Base With Reversible Piezofluorochromism
作者:Han,Fangfang; Zhang,Ran; Zhang,Zhaoming; Su,Jianguo; Ni,Zhonghai
参考文献:Rsc Advances 日期:2016 卷标:6(72) 页码:68178-68184]

166264-70-6 = 919789-80-3
反应条件:1.1 Reagents: Hydrazine Hydrate (1:1) Catalysts: Palladium Solvents: Ethanol; 5 H,Reflux
标题:Preparation Of Fluorescent Probe For Detection Of Water
参考文献:China]

119-61-9 + 1137-41-3 = 919789-80-3
反应条件:1.1 Reagents: Zinc,Titanium Tetrachloride Solvents: Tetrahydrofuran; 10 °C; 10 °C -> Rt; 0.5 H,Rt; 2.5 H,Reflux; Reflux -> 0 °C1.2 Reagents: Pyridine; 10 Min,-5 - 0 °C1.3 Solvents: Tetrahydrofuran; Rt1.4 Reagents: Potassium Carbonate Solvents: Water; -5 - 0 °C
标题:Boranil Dyes Bearing Tetraphenylethene: Synthesis,Aie/aiee Effect Properties,Ph Sensitive Properties And Application In Live Cell Imaging
作者:Chen,Shengxin; Qiu,Rongmao; Yu,Qiuhan; Zhang,Xueyan; Wei,Ming; Et Al
参考文献:Tetrahedron Letters 日期:2018 卷标:59(27) 页码:2671-2678]

166264-70-6 = 919789-80-3
反应条件:1.1 Catalysts: Palladium Solvents: Ethanol; 15 Min,Rt1.2 Reagents: Hydrazine Hydrate (1:1); 4 H,Reflux
标题:Preparation Of Phenylsulfonamide Derivative As Fluorescent Reagent For Selective Detection Of Cysteine
参考文献:China]

166264-70-6 = 919789-80-3
反应条件:1.1 Reagents: Hydrazine Hydrate (1:1) Catalysts: Palladium Solvents: Ethanol; Rt; 3 H,Reflux
标题:How Is The Aie Mechanism Profoundly Changed In An Esipt Family: The Novel Introduction Of A Tetraphenylethene Group Onto (Z)-3-(Quinolin-2-Ylmethylene)-3,4-Dihydroquinoxalin-2(1H)-One
作者:Wu,Ding-Er; Yao,Qi-Chao; Xia,Min
参考文献:Physical Chemistry Chemical Physics 日期:2015 卷标:17(5) 页码:3287-3294]

119-61-9 + 1137-41-3 = 919789-80-3
反应条件:1.1 Catalysts: Zinc,Titanium Tetrachloride Solvents: Tetrahydrofuran; 2.5 H,Rt1.2 Catalysts: Pyridine; 10 Min,0 °C1.3 Solvents: Tetrahydrofuran; 0 °C; 0 °C -> Reflux; Overnight,Reflux
标题:Synthetic Method Of Ureido-Pyrimidinone Substituted Tetraphenylethylene
参考文献:China]

119-61-9 + 1137-41-3 = 919789-80-3
反应条件:1.1 Reagents: Zinc,Titanium Tetrachloride Solvents: Tetrahydrofuran,Pyridine
标题:The First Aggregation-Induced Emission Fluorophore As A Solution Processed Host Material In Hybrid White Organic Light-Emitting Diodes
作者:Lee,Yi-Ting; Chang,Yung-Ting; Chen,Chao-Tsen; Chen,Chin-Ti
参考文献:Journal Of Materials Chemistry C: Materials For Optical And Electronic Devices 日期:2016 卷标:4(29) 页码:7020-7025]

80460-73-7 + 1607-57-4 = 919789-80-3
反应条件:1.1 Reagents: Potassium Bicarbonate Catalysts: Tetrabutylammonium Bromide,Tetrakis(Triphenylphosphine)Palladium Solvents: Tetrahydrofuran,Water; 24 H,90 °C
标题:Facile Fabrication Of End-Functional Plla With Aiegens Via Ugi Reaction
作者:Zeng,Guangjian; Qiu,Lu; Li,Xinyu; Wen,Tao
参考文献:Polymer 日期:2022 卷标:239]

166264-70-6 = 919789-80-3
反应条件:1.1 Reagents: Hydrazine Hydrate (1:1) Catalysts: Palladium Solvents: Ethanol; 8 H,85 °C
标题:Tailor-Made Pdnl2N Metal-Organic Cages Through Covalent Post-Synthetic Modification
作者:Luo,Dong; Yuan,Zi-Jun; Ping,Lin-Jie; Zhu,Xiao-Wei; Zheng,Ji; Et Al
参考文献:Angewandte Chemie 日期:2023 卷标:62(14)]

166264-70-6 = 919789-80-3
反应条件:1.1 Reagents: Hydrazine Hydrate (1:1) Catalysts: Palladium Solvents: Ethanol; 4 H,Reflux
标题:Visible-Light -Triggered Fluorescent Organic Nanoparticles For Chemo-Photodynamic Therapy With Real-Time Cellular Imaging
作者:Parthiban,C.; M.,Pavithra; L.,Vinod Kumar Reddy; Sen,Dwaipayan; S.,Melvin Samuel; Et Al
参考文献:Acs Applied Nano Materials 日期:2018 卷标:1(11) 页码:6281-6288]

80460-73-7 + 1607-57-4 = 919789-80-3
反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: Tetrahydrofuran,Water; 24 H,80 °C; 80 °C -> Rt
标题:Preparation Of Diamine Compounds With Aggregation-Induced Luminescent Group As Photoelectric Material
参考文献:China]

166264-70-6 = 919789-80-3
反应条件:1.1 Catalysts: Palladium Solvents: Ethanol; 15 Min,Rt1.2 Reagents: Hydrazine Hydrate (1:1); 4 H,Reflux
标题:Enantioselective Recognition For Many Different Kinds Of Chiral Guests By One Chiral Receptor Based On Tetraphenylethylene Cyclohexylbisurea
作者:Xiong,Jia-Bin; Xie,Wen-Zhao; Sun,Jian-Ping; Wang,Jin-Hua; Zhu,Zhi-Hua; Et Al
参考文献:Journal Of Organic Chemistry 日期:2016 卷标:81(9) 页码:3720-3726]

89415-43-0 + 1607-57-4 = 919789-80-3
反应条件:1.1 Reagents: Potassium Carbonate Solvents: Tetrahydrofuran,Water; 30 Min,Rt1.2 Catalysts: Tetrakis(Triphenylphosphine)Palladium; Rt -> 80 °C; 24 H,80 °C
标题:Fluorescence-Enhanced Organogelators With Mesomorphic And Piezofluorochromic Properties Based On Tetraphenylethylene And Gallic Acid Derivatives
作者:Luo,Miao; Zhou,Xie; Chi,Zhenguo; Liu,Siwei; Zhang,Yi; Et Al
参考文献:Dyes And Pigments 日期:2014 卷标:101 页码:74-84]

89415-43-0 + 1607-57-4 = 919789-80-3
反应条件:1.1 Reagents: Potassium Carbonate Solvents: Tetrahydrofuran,Water; 30 Min,Rt1.2 Catalysts: Tetrakis(Triphenylphosphine)Palladium; 24 H,80 °C
标题:Synthesis And Properties Of Gelators Derived From Tetraphenylethylene And Gallic Acid With Aggregation-Induced Emission
作者:Luo,Miao; Zhou,Xie; Chi,Zhenguo; Ma,Chunping; Zhang,Yi; Et Al
参考文献:Journal Of Molecular And Engineering Materials 日期:2013 卷标:1(3)]

89415-43-0 + 1607-57-4 = 919789-80-3
反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Tetrabutylammonium Bromide,Tetrakis(Triphenylphosphine)Palladium Solvents: Toluene,Water; 16 H,Reflux
标题:A New Tetraphenylethylene Based Aie Probe For Light-Up And Discriminatory Detection Of Cys Over Hcy And Gsh
作者:Jiang,Guoyu; Liu,Xiang; Chen,Qingqing; Zeng,Guanjie; Wu,Yongquan; Et Al
参考文献:Sensors And Actuators 日期:2017 卷标:252 页码:712-716]

119-61-9 + 1137-41-3 = 919789-80-3
反应条件:1.1 Reagents: Zinc,Titanium Tetrachloride Solvents: Tetrahydrofuran; Rt -> -5 °C; 10 °C; 10 °C -> Rt; 0.5 H,Rt; 2.5 H,Reflux; Reflux -> -5 °C1.2 Reagents: Piperidine; 10 Min,-5 - 0 °C1.3 Solvents: Tetrahydrofuran; -5 - 0 °C; -5 °C -> Reflux; 20 - 30 H,Reflux1.4 Reagents: Potassium Carbonate Solvents: Water
标题:A Facile Synthesis Of Tetraarylethenes Via Cross Mcmurry Coupling Between Diaryl Ketones
作者:Duan,Xin-Fang; Zeng,Jing; Lu,Jia-Wei; Zhang,Zhan-Bin
参考文献:Synthesis 日期:2007 卷标:(5) 页码:713-718]

1607-57-4 + 214360-73-3 = 919789-80-3
反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Tetrabutylammonium Bromide,Tetrakis(Triphenylphosphine)Palladium Solvents: Toluene,Water; 24 H,90 °C
标题:In Situ Visualization Of Reversible Diels-Alder Reactions With Self-Reporting Aggregation-Induced Emission Luminogens
作者:Hu,Danning; Mao,Liucheng; Wang,Mengshi; Huang,Hongye; Hu,Renjian; Et Al
参考文献:Acs Applied Materials & Interfaces 日期:2022 卷标:14(2) 页码:3485-3495]

37220-17-0 + 919789-80-3 = 919789-80-3
反应条件:1.1 Solvents: Tetrahydrofuran,Water; 12 H,Rt
标题:Aggregation-Induced Emission Of Active Nanoparticles Based On Konjac Glucomannan: Fabrication,Properties,And Applications
作者:Guan,Lianxiong; Zeng,Zhi; Zhao,Rui; Hu,Sheng; Liu,Wei; Et Al
参考文献:Polymer 日期:2022 卷标:252]

119-61-9 + 1137-41-3 = 919789-80-3
反应条件:1.1 Reagents: Zinc,Titanium Tetrachloride Solvents: Tetrahydrofuran; Rt; 2.5 H,Reflux; 0 °C -> 5 °C; 10 Min,Rt1.2 Reagents: Pyridine Solvents: Tetrahydrofuran; Rt; 24 H,Reflux
标题:Fluorophore-Labeling Tetraphenylethene Dyes Ranging From Visible To Near-Infrared Region: Aie Behavior,Performance In Solid State,And Bioimaging In Living Cells
作者:Chen,Weijie; Zhang,Chen; Han,Xie; Liu,Sheng Hua; Tan,Ying; Et Al
参考文献:Journal Of Organic Chemistry 日期:2019 卷标:84(22) 页码:14498-14507

📜1,1,2,2-四苯乙烯置于copper(II) Nitrate Trihydrate,Palladium 10% On Activated Carbon,乙酸酐,一水合肼体系中,用乙醇,乙酸乙酯作为反应溶剂,化学反应 12.0H,反应生成 1-(4-氨基苯)-1,2,2-三苯乙烯
参考文献:具有可逆的压电荧光致变色的新的基于tict和aie活性的基于四苯乙烯的席夫碱†
标题:具有可逆的压电荧光致变色的新的基于tict和aie活性的基于四苯乙烯的席夫碱†
摘要:基于4-四苯基乙烯基胺和5-硝基水杨醛合成了一种新的基于四苯基乙烯的席夫碱n-5-硝基水杨基-4-四苯基乙烯基胺(nstpe),并通过1 H NMR,13 C NMR,Ms和单晶对结构进行了全面表征x射线衍射分析.光学性质的研究表明,当在nstpe的四氢呋喃溶液中加水时,发射物表现出有趣的"开-关-开"转换特性,呈u形趋势,显示出扭曲的分子内电荷转移(tict)和聚集诱导的发射(aie)的特征.此外,该化合物表现出可逆的压电氟致变色性质.
DOI:10.1039/c6Ra14729A