CAS: 17049-49-9; N-Octylmagnesium Bromide

该化合物是一种有机金属化合物,其特点是有镁和溴化八溴二苯醚组,该化合物通常具有与镁和有机溴有关的特性,包括由于溴原子的存在而具有的潜在反应性,这些物质可以参与核生殖替代反应; 辛基化合物组助长分子的疏水特性,影响分子在有机溶剂中的溶解性,同时有可能限制其在水中的溶解性; 作为有机金属化合物,它也可能显示独特的催化特性,或作为各种化学合成的前体; 安全考虑很重要,因为有机金属化合物可能是反应性的,如果处理不当,可能会造成危害.

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CAS号111-83-1 1-溴代正辛烷 | CAS号2314-78-5 N-乙基琥珀酰亚胺 | CAS号7664-93-9 硫酸 | CAS号39836-21-0 顺-9-二十一碳烯 | CAS号6064-38-6 7-十五酮 | CAS号3590-84-9 四辛基锡 | CAS号329976-79-6 辛基三氟硼酸钾 | CAS号3510-72-3 甲基三正辛基硅烷 | CAS号14086-46-5 di°Ctyl(phenyl)... | CAS号146690-00-8 4-壬酰基吡啶 | CAS号143363-50-2 tri°Ctyl(phenyl... | CAS号14861-60-0 1-(噻吩-3-基)乙醇 | CAS号1227495-94-4 2-(thiophen-3-y...

合成工艺路线路线简述

    📜1-溴辛烷置于溴,Magnesium体系中,用 四氢呋喃 用作溶剂,化学反应 3.0H,反应生成正辛基镁溴盐
    参考文献:使用带有受体单元的苯并三噻吩衍生物作为非富勒烯受体的有机薄膜太阳能电池
    标题:使用带有受体单元的苯并三噻吩衍生物作为非富勒烯受体的有机薄膜太阳能电池
    摘要:已经合成了两种带有受体单元的苯并三噻吩衍生物,并估计了一些物理性质.使用两种苯并三噻吩衍生物作为非富勒烯受体的有机薄膜太阳能电池显示出功率转换效率.此外,发现这些材料对于作为添加剂的三元共混有机太阳能电池是有效的.
    Doi:10.1002/ejoc.202100178

    海关参考信息

    专利信息


    专利号:US-5880295-A
    优先权日:1994-02-16
    标 题 :Process for the preparation of diamine intermediates useful in the synthesis of HIV protease inhibitors
    发明人:KALTENBACH III ROBERT FRANK
    权利人:DU PONT PHARM CO
    摘要:The present invention provides a process for the preparation of compounds of formula (V) below, and analogs thereof, which are useful as intermediates for the synthesis of HIV protease inhibitors, including cyclic ureas. ##STR1##

    专利号:US-5847149-A
    优先权日:1994-01-27
    标 题 :Thiadiazole derivatives, process for their preparation, and their use as precursors for the production of liquid crystals
    发明人:FUSS ROBERT WALTER; MANERO JAVIER; SCHLOSSER HUBERT; WINGEN RAINER
    权利人:HOECHST AG
    摘要:Thiadiazole derivatives of the formula (I) n n X-B-A.sup.1 -(M.sup.1 -A.sup.2 -).sub.m (M.sup.2 -A.sup.3).sub.n -R.sup.1(I n n ) n in which the symbols and indices have the following meanings: n X is Cl, Br or I; n B is 1,3,4-thiadiazole-2,5-diyl; n A 1 , A 2 and A 3 are identical or different and are substituted or unsubstituted 1,4-phenylene, pyrazine-2,5-diyl, pyridazine-3,6-diyl, pyridine-2,5-diyl, pyrimidine-2,5-diyl, trans-1,4-cyclohexylene, 1,3,4-thiadiazole-2,5-diyl, 1,3-dioxane-2,5-diyl, 1,3-dithiane-2,5-diyl, 1,3-thiazole-2,4-diyl, 1,3-thiazole-2,5-diyl, thiophene-2,4-diyl, thiophene-2,5-diyl, piperazine-1,4-diyl, piperazine-2,5-diyl, naphthalene-2,6-diyl, bicyclo 2.2.2!octane-1,4-diyl, or 1,3-dioxaborinane-2,5-diyl; n M 1 and M 2 are identical or different and are --CO--O--, --O--CO--, --O--CO--O--, --O--CS--O--, --CH 2 --O--, --O--CH 2 --, --CHâ•?CH--, --C.tbd.C-- or a single bond; n R 1 is --O-benzyl, H, an alkyl group having 1 to 12 carbon atoms or an alkoxy group having 1 to 12 carbon atoms; n m and n are 0 or 1. n The novel compounds allow the synthesis of a wide range of 1,3,4-thiadiazole derivatives, as employed, for example, as components of liquid-crystal mixtures, in a significantly reduced number of synthesis stes.

    专利号:WO-2023237381-A1
    优先权日:2022-06-09
    标题:Process for the synthesis of polyethylenes or copolymers of ethylene and 1,3-diene having a terminal ketone function
    发明人:BOISSON CHRISTOPHE; D'AGOSTO FRANCK; DESGRANGES ARIANE; NGO ROBERT; JEAN-BAPTISTE-DIT-DOMINIQUE FRANÇOIS
    权利人:MICHELIN & CIE; CENTRE NAT RECH SCIENT; ECOLE SUPERIEURE DE CHIMIE PHYSIQUE ELECTRONIQUE LYON; UNIV CLAUDE BERNARD LYON
    摘要:The invention relates to a method for preparing a polyethylene having a terminal ketone function or a copolymer of ethylene and a 1,3-diene and optionally a vinyl aromatic compound which contains more than 50 mol% of ethylene and has a terminal ketone function; said method comprises a polymerization reaction of the monomers in the presence of a borohydrido-neodymocene complex and an organo-magnesium compound, followed by a coupling reaction with a compound having a nitrile function, and then a hydrolysis reaction.

    专利号:US-7368616-B2
    优先权日:2002-10-30
    标题 :Method for the production of monomers useful in the manufacture of semiconductive polymers
    发明人:WALLACE PAUL; TOWNS CARL; POUNDS THOMAS
    权利人:MERCK PATENT GMBH
    摘要:The instant invention relates to a new method for the synthesis of monomers and their use inter alia in the manufacture of semiconductive polymers. Monomers, in particular, asymmetric monomers, such as asymmetric fluorene compounds, are valuable material in the manufacture of semiconductive polymers. The know methods for producing asymmetric monomers, such as asymmetric fluorene compounds, are expensive due to the formation of by-products. n The method according to the present invention avoids the formation of such by-products and is described in more detail in claims 1 to 14.

    专利号:US-8535689-B2
    优先权日:2007-10-01
    标题 :Identification of bacterial autoinducer and use in treating bacterial pathogenicity
    发明人:BASSLER BONNIE; SEMMELHACK MARTIN; HIGGINS DOUGLAS A; BOLITHO MEGAN EILEEN; KRAML KRISTINA M; NG WAI-LEUNG
    权利人:BASSLER BONNIE; SEMMELHACK MARTIN; HIGGINS DOUGLAS A; BOLITHO MEGAN EILEEN; KRAML KRISTINA M; NG WAI-LEUNG; UNIV PRINCETON
    摘要:A bacterial autoinducer, CAI-1, was purified and its structure identified. Methods for synthesis of the autoinducer and its analogues were elucidated. Methods of using the autoinducer or its analogues for treating bacterial pathogenicity and bio film formation are described. Methods for prevention and treatment of cholera are described. Synthetic (S)-3-hydroxytridecan-4-one functions as well as natural CAI-1 in repressing production of the virulence factor toxin co-regulated pilus (TCP). Strategies are described to manipulate bacterial quorum sensing in the clinical arena.

    专利号:US-4367343-A
    优先权日:1981-12-31
    标 题:Synthesis of tetraalkylsilanes
    发明人:TAMBORSKI CHRIST; SNYDER JR CARL E
    权利人:US AIR FORCE
    摘要:A mixture of tetraalkylsilanes is prepared by reacting a mixture of at least two organometallic compounds with a silicon tetrahalide or an alkyl silicon trihalide. The mixture of silanes is useful as a hydraulic fluid.

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    合成参考文献


    摘要:Alonso, D. A.; Nájera, C., Science of Synthesis, (2010) 45, 243.
    摘要:Alonso, D. A.; Nájera, C., Science of Synthesis, (2010) 47, 463.
    摘要:Alonso, D. A.; Nájera, C., Science of Synthesis, (2010) 47, 451.
    摘要:Kantchev, E. A. B.; Organ, M. G., Science of Synthesis, (2009) 48, 77.
    摘要:Kantchev, E. A. B.; Organ, M. G., Science of Synthesis, (2009) 48, 38.
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