CAS: 113728-71-5; A-Octithiophene

该化合物是一种属于硫苯类的有机化合物,它由五人组成,含有硫磺原子的芳香环组成.具体地说,α-辛蒂欧芬由八种硫苯元素组成的线性链条组成,使它成为多环芳香化合物,其特征是其共生系统,有助于其电子特性,使其对有机电子和材料科学感兴趣.结构中多硫磷原子的存在增强了其稳定性,并能够影响其溶解性和导电性.阿尔法-辛蒂欧芬通常表现出高度的阳性,有利于有机半导体的应用.其合成通常涉及聚合反应,可用于开发有机光电装置,外效应晶体晶体和其他电子应用.此外,其光性在传感器和发光装置的设计中可能得到利用.对于许多硫苯衍生物而言,它对于处理甲型-辛基苯及其潜在毒性和潜在毒性而言,对于处理甲型-辛基苯具有至关重要.

英文名称A-Octithiophene
中文名称α-八噻吩
IUPAC名称2,2':5',2'':5'',2''':5''',2'''':5'''',2''''':5''''',2'''''':5'''''',2'''''''-octithiophene
其它别名°Ctathiophene; °Ctithiophene; a-°Ctathienyl; a-°Ctithiophene
CAS编号113728-71-5
MFCD编号:MFCD09038539
分子式:C32H18S8分子量:659.03
产品CID: 168886
产品分类医药中间体 → 噻吩类化合物

相似结构搜索
InChIKey: GCMCTPRNKVKGCY-UHFFFAOYSA-N
InChI=1S/C32H18S8/c1-3-19(33-17-1)21-5-7-23(35-21)25-9-11-27(37-25)29-13-15-31(39-29)32-16-14-30(40-32)28-12-10-26(38-28)24-8-6-22(36-24)20-4-2-18-34-20/h1-18H
计算化学: 氢键受体数8.0氢键供体数*可旋转键数7.0

MSDS等安全信息

上下游产品

CAS号5632-29-1 α-四联噻吩 | CAS号492-97-7 2,2'-双噻吩 | CAS号188290-36-0 Thiophene(SIV) | CAS号3480-11-3 5-溴-2,2'-双噻吩

合成工艺路线路线简述

492-97-7 = 113728-71-5 + 5632-29-1 + 88493-55-4
反应条件:1.1 Reagents: Acetic Acid,2,2,2-Trifluoro-,Mercury(2+) Salt (2:1) Solvents: Benzene1.2 Reagents: Triethylamine Catalysts: Palladium Chloride1.3 Reagents: Acetic Acid,2,2,2-Trifluoro-,Mercury(2+) Salt (2:1)1.4 Reagents: Triethylamine Catalysts: Palladium Chloride
标题:A Novel Approach To A One-Pot Synthesis Of Unsubstituted Oligo(α-Thiophenes)
作者:Buzhansky,Ludmila; Et Al
参考文献:Journal Of Organic Chemistry 日期:2002 卷标:67(21) 页码:7523-7525]

= 113728-71-5 + 5632-29-1 + 88493-55-4
反应条件:1.1 Reagents: Acetic Acid,2,2,2-Trifluoro-,Mercury(2+) Salt (2:1) Solvents: Benzene1.2 Reagents: Triethylamine Catalysts: Palladium Chloride1.3 Reagents: Acetic Acid,2,2,2-Trifluoro-,Mercury(2+) Salt (2:1)1.4 Reagents: Triethylamine Catalysts: Palladium Chloride1.5 Reagents: Acetic Acid,2,2,2-Trifluoro-,Mercury(2+) Salt (2:1)1.6 Reagents: Triethylamine Catalysts: Palladium Chloride
标题:A Novel Approach To A One-Pot Synthesis Of Unsubstituted Oligo(α-Thiophenes)
作者:Buzhansky,Ludmila; Et Al
参考文献:Journal Of Organic Chemistry 日期:2002 卷标:67(21) 页码:7523-7525

📜2,2'-联二噻吩置于mercury(II) Trifluoroacetate体系中,用苯用作溶剂,化学反应 1.0H,反应生成α-八噻吩
参考文献:A Novel Approach To A One-Pot Synthesis Of Unsubstituted Oligo(α-Thiophenes)
标题:A Novel Approach To A One-Pot Synthesis Of Unsubstituted Oligo(α-Thiophenes)
摘要:Oligo(Alpha-Thiophenes) Alpha-4T And Alpha-8T Were Prepared By The Following One-Pot Sequential Conversions: Thiophene (T)--> Alpha-2T--> Alpha-4T--> Alpha-St. Pdcl2-Induced Coupling Of A Mono-Alpha-Mercuration Derivative Of Each Of The N-Mers T,Alpha-2T,And Alpha-4T Was Applied In These Conversions.
Doi:10.1021/jo025838E