CAS: 84131-04-4; 2-(2-(2-(Benzyloxy)Ethoxy)Ethoxy)Ethyl 4-Methylbenzenesulfonate

该化合物是一种化学化合物,其复杂结构包括乙醇脊柱和多醚联系,具有复合结构特征,该化合物具有磺酸盐组的特点,有助于其在水中的溶解性并增强其反应性.该苯氧组的存在表明它具有芳香特性,能够影响其物理特性,如稳定性和沸点.这种乙醇衍生物经常用于各种用途,包括溶剂,制药和化学合成.该类混合物还表明其在表面活性剂或有机合成的中间体中的潜在用途.

英文名称2-(2-(2-(Benzyloxy)Ethoxy)Ethoxy)Ethyl 4-Methylbenzenesulfonate
中文名称4-甲基苯磺酸2-(2-(2-(苄氧基)乙氧基)乙氧基)乙酯
IUPAC名称2-(2-(2-(benzyloxy)ethoxy)ethoxy)ethyl 4-methylbenzenesulfonate
其它别名2-(2-(2-(苄氧基)乙氧基)乙氧基)乙基 4-甲基苯磺酸负离子
CAS编号84131-04-4
MFCD编号:MFCD31555345
分子式:C20H26O6S分子量:394.48
产品CID: 1829760
产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

相似结构搜索
InChIKey: SULYUXLJHONROP-UHFFFAOYSA-N
InChI=1S/C20H26O6S/c1-18-7-9-20(10-8-18)27(21,22)26-16-15-24-12-11-23-13-14-25-17-19-5-3-2-4-6-19/h2-10H,11-17H2,1H3
计算化学: 氢键受体数6.0氢键供体数*可旋转键数13.0

MSDS等安全信息

GHS符号GHS07
警示词Warning
危险描述H302-H315-H319-H335
防范说明P261-P280-P302+P352

上下游产品

triethylene glycol monobenzyl ether p-toluenesulfonyl chloride benzyl chloride 2,2'-[1,2-ethanediylbis(oxy)]bisethanol(11S,12S)-1,22-dibenzyloxy-11,12-O-isopropylidene-3,6,9,14,17,20-hexaoxad°Cosane (2-{2-[2-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluoro-°Ctyloxy)-ethoxy]-ethoxy}-ethoxymethyl)-benzene ethoxy>ethoxy>--3-carboxylic acid methyl ester2,2'-Bis2-2-2-(phenylmethoxy)ethoxyethoxyethoxy-1,1'-binaphthalene-3-carboxylic acid methyl ester ethoxy>methyl>-15-crown-52-2-2-(2-Benzyloxyethoxy)ethoxyethoxymethyl-15-crown-5

合成工艺路线路线简述

55489-58-2 = 84131-04-4
反应条件:1.1 Reagents: Pyridine Solvents: Dichloromethane; 12 H,0 °C -> 23 °C
标题:Membrane-Mimetic Dendrimersomes Engulf Living Bacteria Via Endocytosis
作者:Kostina,Nina Yu.; Rahimi,Khosrow; Xiao,Qi; Haraszti,Tamas; Dedisch,Sarah; Et Al
参考文献:Nano Letters 日期:2019 卷标:19(8) 页码:5732-5738]

55489-58-2 = 84131-04-4
反应条件:1.1 Reagents: Potassium Hydroxide Solvents: Tetrahydrofuran,Water; 15 Min,Rt1.2 Overnight,Rt
标题:Design,Synthesis,And Characterization Of Brequinar Conjugates As Probes To Study Dhodh Inhibition
作者:Madak,Joseph T.; Cuthbertson,Christine R.; Chen,Wenmin; Showalter,Hollis D.; Neamati,Nouri
参考文献:Chemistry - A European Journal 日期:2017 卷标:23(56) 页码:13875-13878]

55489-58-2 = 84131-04-4
反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Tetrahydrofuran,Water
标题:Self-Assembly Of Janus Dendrimers Into Uniform Dendrimersomes And Other Complex Architectures
作者:Percec,Virgil; Wilson,Daniela A.; Leowanawat,Pawaret; Wilson,Christopher J.; Hughes,Andrew D.; Et Al
参考文献:Science (Washington 日期:2010 卷标:328(5981) 页码:1009-1014]

55489-58-2 = 84131-04-4
反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Tetrahydrofuran,Water; 30 Min,Cooled; Overnight,Rt
标题:Two-Step Folding Of Donor-Acceptor Foldamers
作者:Ramkumar,S. G.; Ramakrishnan,S.
参考文献:Macromolecules (Washington 日期:2010 卷标:43(5) 页码:2307-2312]

55489-58-2 = 84131-04-4
反应条件:1.1 Reagents: Silver Oxide (Ag2O) Catalysts: Potassium Iodide Solvents: Dichloromethane
标题:Silver(I) Oxide-Mediated Facile And Practical Sulfonylation Of Alcohols
作者:Bouzide,Abderrahim; Leberre,Nicolas; Sauve,Gilles
参考文献:Tetrahedron Letters 日期:2001 卷标:42(50) 页码:8781-8783]

55489-58-2 = 84131-04-4
反应条件:1.1 Solvents: Pyridine; 30 Min,0 °C1.2 Solvents: Pyridine; 0 °C; 5 - 17 H,Rt1.3 Reagents: Hydrochloric Acid Solvents: Water; Neutralized
标题:Multigram Synthesis Of Well-Defined Extended Bifunctional Polyethylene Glycol (Peg) Chains
作者:Loiseau,Francois A.; Hii,King Kuok; Hill,Alison M.
参考文献:Journal Of Organic Chemistry 日期:2004 卷标:69(3) 页码:639-647]

55489-58-2 = 84131-04-4
反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Tetrahydrofuran,Water; 3 H,0 - 5 °C
标题:One-Component Multifunctional Sequence-Defined Ionizable Amphiphilic Janus Dendrimer Delivery Systems For Mrna
作者:Zhang,Dapeng; Atochina-Vasserman,Elena N.; Maurya,Devendra S.; Huang,Ning; Xiao,Qi; Et Al
参考文献:Journal Of The American Chemical Society 日期:2021 卷标:143(31) 页码:12315-12327]

55489-58-2 = 84131-04-4
反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Tetrahydrofuran,Water; 0 °C
标题:Novel Ethoxylated Inositol Derivatives - Hybrid Carbohydrate/oligoethylene Oxide Surfactants
作者:Catanoiu,Gabriela; Blunk,Dirk; Stubenrauch,Cosima
参考文献:Journal Of Colloid And Interface Science 日期:2012 卷标:371(1) 页码:82-88

📜三乙二醇置于四丁基溴化铵,Sodium Hydride,三乙胺体系中,用四氢呋喃,二氯甲烷作为反应溶剂,化学反应 0.5H,反应生成三乙二醇单苄醚对甲苯磺酸酯
参考文献:用于同时成像,跟踪和靶向光动力治疗的综合硫酮衍生苝二亚胺及其生物共轭
标题:用于同时成像,跟踪和靶向光动力治疗的综合硫酮衍生苝二亚胺及其生物共轭
摘要:在本研究中,发色团 3,4,9,10-苝四羧酸二亚胺 (Pdi) 在酰亚胺 N 位点用苯基取代基锚定,然后进行硫化,得到一系列硫酮产物1S-Pdi-D,2S-Cis-Pdi-D,2S-反式-Pdi-D,3S-Pdi-D和4S-Pdi-D分别具有n = 1,2,3 和 4 硫酮.光物理性质取决于锚定硫酮的数量,其中观测到的显着较低吸收分配给 S 0-> S 2(ππ*) 跃迁并且随着硫酮数量的增加而红移;最低激发态归因于禁止跃迁的 S 1 (N π*) 构型.所有n S-Pdi在溶液中都是不发射的,但显示出 > 800 Gm 的出色双光子吸收截面.在飞秒瞬态吸收研究的支持下,S 1 (N π*)-> T 1 (ππ*) 系统间穿越 (Isc) 率 > 10 12 S-1,导致 ∼100% 三重态种群.最低的 T 1 (ππ*) 能量计算为1S-Pdi-D > 2S-Cis-Pdi-D
DOI:10.1021/jacs.2C07967