CAS: 53463-68-6; 10-Bromodecanol

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CAS号112-47-0 1,10-癸二醇 | CAS号252316-67-9 1-bromo-10-(met... | CAS号85920-81-6 10-Bromodecanal | CAS号51309-10-5 10-氯-1-癸醇 | CAS号13019-22-2 9-十烯-1-醇 | CAS号50530-12-6 10-溴代癸酸 | CAS号1124-78-3 Cyclodeca-1,5-diene | CAS号5519-23-3 4-癸氧基苯甲酸 | CAS号50816-18-7 乙酸-9-癸烯基酯 | CAS号140713-97-9 4-[10-(2-methyl... | CAS号3669-80-5 11-羟基十一烷酸 | CAS号189945-43-5 tert-butyl-(10-... | CAS号112-30-1 正癸醇 | CAS号186788-38-5 1-(10-羟癸基)咪唑 | CAS号73033-09-7 十九碳烯酸(顺-10) | CAS号62442-62-0 11-二十碳烯醇 | CAS号58186-27-9 艾地苯醌

1,10-癸二醇置于氢溴酸体系中,用 水,甲苯 作为反应溶剂,化学反应 36.0H,以74.5%的收率获得产物10-溴-1-癸醇
参考文献:两亲性含偶氮苯的线性树枝状嵌段共聚物的合理设计,合成,表征和溶液行为
标题:两亲性含偶氮苯的线性树枝状嵌段共聚物的合理设计,合成,表征和溶液行为
摘要:本文基于具有线性聚(乙二醇)(peg)分子量约为2000的线性前体线性-树状嵌段共聚物(ldbc)和g0至g3代的树状聚酰胺型(aama)链段的合成含偶氮苯的两亲ldbcs Mpeg-Dendr [pamam-(azo)n](n 通过在树枝状链段的周边胺基团与带有辛氧基尾巴和柔性癸基亚甲基间隔基的反应性偶氮苯丙烯酸酯液晶元之间的完全迈克尔加成反应,已成功地以中等收率45-60%制备了2,3,4,8,16).纯化的共聚物已通过NMR,Ft-Ir,Maldi-Tof Ms和gpc进行了表征和确认,显示出窄的分子量分布,范围为1.09-1.20.从二恶烷/水.此外,还研究了thf溶液中的反式-顺式-反式光化学跃迁,对于g3共聚物而言,实测的反式-顺式光异构化速率常数0.0240 S-1是前体偶氮苯化合物的0.0127 S-1的两倍,这显示出一种有希望的光敏共聚物材料.
DOI:10.1016/j.Polymer.2011.11.047

专利信息

专利号:US-4912253-A
优先权日:1988-06-06
标题 :Method for the preparation of an unsaturated alcohol or ester thereof
发明人：FUKUMOTO TAKEHIKO; YAMAMOTO AKIRA
权利人:SHINETSU CHEMICAL CO
摘要:An efficient method is proposed for the synthesis of an unsaturated alcohol of the general formula R--CHâ•?CH(CH 2 ) n+1 OH, in which R is a hydrogen atom or a monovalent hydrocarbon group having 1 to 10 carbon atoms and the subscript n is an integer in the range from 3 to 10, in which an acetate of the formula R--CHâ•?CHCH 2 OCOCH 3 is subjected to a coupling reaction with a Grignard reagent of the formula X 1 Mg(CH 2 ) n OMgX 2 , in which X 1 and X 2 are each a halogen atom, and then the reaction product is hydrolyzed. When the reaction product of the coupling reaction is reacted with acetic anhydride instead of hydrolysis, the corresponding acetate can readily be obtained. These unsaturated alcohols and acetates form a class of important biologically active compounds or intermediates thereof including sex pheromone compounds of insects.

专利号:US-10202620-B2
优先权日:2014-05-16
标 题:Synthesis of olefinic alcohols via enzymatic terminal hydroxylation
发明人：COELHO PEDRO; CHEN MIKE M Y; MEINHOLD PETER; CHO CATHERINE MEE-HIE; BUI VU; HEEL THOMAS
权利人:PROVIVI INC
摘要:In certain aspects, the present invention provides methods for producing terminally hydroxylated alkenes and alkynes by contacting an unsaturated or saturated hydrocarbon substrate with a hydroxylase enzyme. Exemplary terminal hydroxylases useful for carrying out the methods of the invention exhibit strong selectivity towards one terminal carbon of a hydrocarbon substrate and include, but are not limited to, non-heme diiron alkane monooxygenases, cytochromes P450 (e.g., cytochromes P450 of the CYP52 and CYP153 family), as well as long chain alkane hydroxylases. In some embodiments, the terminally hydroxylated alkene or alkyne is further converted to a terminal alkenal. In certain embodiments, terminally hydroxylated alkenes and alkynes are useful as insect pheromones which modify insect behavior. In other embodiments, terminally hydroxylated alkenes and alkynes are useful intermediates for producing pheromones via acetylation or oxidation of the alcohol moiety.

专利号:US-4198533-A
优先权日:1979-02-26
标题:(11Z,13Z)-11,13-Hexadecadien-1-ol and derivatives
发明人：CARNEY ROBERT L; HENRICK CLIVE A
权利人:ZOECON CORP
摘要:Synthesis of an attractant (11Z,13Z)-11,13-hexadecadienal for the navel orangeworm Amyelois transitella, and intermediates therefor.

专利号:US-2016108436-A1
优先权日:2014-05-16
标题:Synthesis of olefinic alcohols via enzymatic terminal hydroxylation

专利号:CN-117756720-A
优先权日:2023-12-18
标 题 :Polymerizable quaternary ammonium salt antibacterial agent and its preparation and application in the synthesis of antibacterial polyester

专利号:CN-117756720-B
优先权日:2023-12-18
标 题:Polymerizable quaternary ammonium salt antibacterial agent and its preparation and application in the synthesis of antibacterial polyester