CAS: 18115-70-3; Lithium Acetylacetonate

该化合物是一个由锂和乙酰蕾素组成的协调复合体,一般是白色到浅黄色晶体固态,以极地有机溶剂溶性著称,在各种化学应用中有用;锂乙酰蕾素在有机合成中作为锂来源,经常用作有机金属化学反应的催化剂或试剂;其协调特性允许它形成各种金属离子的复合体,加强其在催化和材料科学中的效用;此外,该复合体具有热稳定性,在高温应用中具有优势;该复合体在电池技术领域,特别是锂离子电池领域也很感兴趣,因为它在提高电化学性能方面的潜在作用;在处理该物质时,应注意安全防范,因为如果浸入或吸入,可能会对健康造成危害.

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相似化合物

815-57-6 15435-71-9 345909-31-1

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上下游产品

N,N,N,N,-tetramethylethylenediamine methyllithium manganese(III) acetylacetonate lithium aluminium tetrahydride6-(1-acetyl-2-oxoprop-1-yl)-5-phenyl-1-ethyl-1,6-dihydropyrazine-2,3-dicarbonitrile 6-(1-acetyl-2-oxoprop-1-yl)-5-(4-fluorophenyl)-1-ethyl-1,6-dihydropyrazine-2,3-dicarbonitrile

合成工艺路线路线简述

    📜Cobalt Acetylacetonate置于苯乙烯,Lithium Aluminium Tetrahydride,氢气体系中,用 四氢呋喃 用作溶剂,30.0 °C,202.66 Kpa 条件下,反应生成乙酰基丙酮锂
    参考文献:氢化铝锂和三(叔丁氧基)铝氢化锂作用下钴加氢催化剂的形成及其性能
    标题:氢化铝锂和三(叔丁氧基)铝氢化锂作用下钴加氢催化剂的形成及其性能
    摘要:Co(acac)2(3)与lialh4或lialh(t-Buo)3的相互作用使用NMR,Uv,Ir,Esr光谱,电子显微镜和体积分析法进行了研究.提出了氢化用钴催化剂形成的基本步骤.是在氢化过程的活性纳米颗粒的形成显示在试剂5<=红/钴<=12.纳米颗粒通过过量的lialh的稳定的比率发生4或的lialh(吨-Buo)3,以及如它们在还原态的钴作用下催化分解的产物.Lialh 4的比例 为了获得具有催化活性的颗粒,需要通过质子给体化合物对其进行活化.
    Doi:10.1134/s1070363212080026

    海关参考信息

    专利信息


    专利号:US-10593928-B2
    优先权日:2014-08-20
    标 题 :Single-step synthesis of nanostructured thin films by a chemical vapor and aerosol deposition process
    发明人:CHADHA TANDEEP SINGH; BISWAS PRATIM; AN WOO-JIN
    权利人:UNIV WASHINGTON
    摘要:The present disclosure is generally directed to a single-step synthesis of nanostructured thin films by a chemical vapor and aerosol deposition (CVAD) process. The present disclosure is also directed to methods for controlling the morphology of the nanostructured thin films. The films can be used, for example, in lithium ion and/or sodium ion battery electrodes, solar cells and gas sensors.

    专利号:WO-2006008175-A1
    优先权日:2004-07-23
    标 题 :Rapid flame synthesis of doped zno nanorods with controlled aspect ration
    发明人:HEIGHT MURRAY J; MAEDLER LUTZ; PRATSINIS SOTIRIS
    权利人:ETH ZUERICH; HEIGHT MURRAY J; MAEDLER LUTZ; PRATSINIS SOTIRIS
    摘要:Described is a flame spray pyrolysis (FSP) method for the production of nanorods wherein at least one dopant metal precursor is added to a precursor solution of the predominant metal in amounts of at most 15 atom-% referred to the predominant metal, said dopant having an higher valency than the predominant metal, and wherein the crystal lattice of the pure metal oxide formed by FSP is in a hexagonal closed package. In preferred embodiments, the coordination number of the dopant atoms is higher than the coordination number of the predominant metal atoms and the dopant atoms and/or ions and the predominant metal atoms/ions have sizes varying by less than 20 atom-%.

    专利号:US-2012168686-A1
    优先权日:2009-09-03
    标 题:Continuous Synthesis of Carbon-Coated Lithium-Iron-Phosphate
    发明人:METZ HANS JOACHIM; WASER OLIVER; BUECHEL ROBERT; PRATSINIS SOTIRIS E
    权利人:METZ HANS JOACHIM; WASER OLIVER; BUECHEL ROBERT; PRATSINIS SOTIRIS E; CLARIANT FINANCE BVI LTD
    摘要:The invention relates to a continuous process for preparing carbon-coated lithium-iron-phosphate particles, wherein the carbon-coated lithium-iron-phosphate particles have a mean (d 50 ) particle size of 10 to 150 nm, and wherein the carbon-coating is an acetylene-black coating, comprising performing in a reactor a flame-spray pyrolysis step (i) in a particle formation zone of the reactor, and a carbon-coating step (ii) in a carbon-coating zone of the reactor, wherein inn (i) a combustible organic solution containing a mixture of lithium or a lithium compound; iron or an iron compound; and phosphorus or a phosphorous compound in an organic solvent, is fed through at least one nozzle where said organic solution is dispersed, ignited and combusted, to give a flame spray thereby forming an aerosol of lithium iron phosphate particles; (ii) acetylene gas is injected into said aerosol thereby forming an acetylene-black coating on the lithium iron phosphate particles; (iii) the coated particles are cooled by an inert quench gas and collected on a filter.

    专利号:CN-110982054-B
    优先权日:2019-12-28
    标题 :A composite catalyst for catalyzing synthesis of polycarbonate and method for catalyzing synthesis of polycarbonate

    专利号:CN-110982054-A
    优先权日:2019-12-28
    标 题 :A composite catalyst for catalyzing synthesis of polycarbonate and method for catalyzing synthesis of polycarbonate

    专利号:US-6013838-A
    优先权日:1998-01-27
    标题:Chemical intermediates bearing a trifluoromethyl group
    发明人:VAN DER PUY MICHAEL
    权利人:ALLIED SIGNAL INC
    摘要:Novel trifluoromethylated intermediates are provided which are useful in synthesizing trifluoromethylated organic compounds. Specifically, compounds of the formula CF 3 CR are provided, wherein R is (Cl)â•?CHCH 2 SO 2 Ph, (Cl)â•?CHCH 2 CH 2 C(â•?O)CH 3 , (Cl)â•?CHCH 2 CH(COCH 3 ) 2 , (Cl)â•?CHCH 2 NR'R' or Hâ•?CHCHâ•?NR'; R' and R' are the same or different and are selected from the group consisting of hydrogen, unsubstituted or substituted C 1 to C 6 straight chain or branched alkyl, unsubstituted or substituted C 3 to C 7 cycloalkyl, unsubstituted or substituted C 2 to C 12 alkenyl, a benzyl group unsubstituted or substituted with R'', or a phenyl group unsubstituted or substituted with R''; or R' and R' taken together form a five- or six-membered ring; and R'' is an unsubstituted or substituted C 1 to C 6 straight chain or branched alkyl, an unsubstituted or substituted C 1 to C 6 alkoxy, an unsubstituted or substituted C 1 to C 6 thioakyl, a cyano, a halogen, or a C 1 to C 2 dialkylamino group; with the proviso that when the alkyl, cycloalkyl or alkenyl of R' or R' or the alkyl, alkoxy or thioalkyl of R'' is substituted, it may be substituted with any group compatible with amine functionality. The novel compounds are versatile intermediates for the synthesis of a wide variety of trifluoromethylated organic compounds, which have found great utility as pharmaceuticals, agricultural chemicals, and materials such as liquid crystals.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Murukanahally Kempaiah Devaraju, Et Al. Synthesis, Characterization And Observation Of Antisite Defects In Linipo4 Nanomaterials. Sci Rep. 2015 Jun 19:5:11041.

    合成参考文献


    摘要:Alonso, D. A.; Nájera, C., Science of Synthesis, (2010) 47, 473.
    摘要:Kauffman, M. C.; Walsh, P. J., Science of Synthesis: Stereoselective Synthesis, (2011) 2, 458.
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