专利号:US-10593928-B2 优先权日:2014-08-20 标 题 :Single-step synthesis of nanostructured thin films by a chemical vapor and aerosol deposition process 发明人:CHADHA TANDEEP SINGH; BISWAS PRATIM; AN WOO-JIN 权利人:UNIV WASHINGTON 摘要:The present disclosure is generally directed to a single-step synthesis of nanostructured thin films by a chemical vapor and aerosol deposition (CVAD) process. The present disclosure is also directed to methods for controlling the morphology of the nanostructured thin films. The films can be used, for example, in lithium ion and/or sodium ion battery electrodes, solar cells and gas sensors.
专利号:WO-2006008175-A1 优先权日:2004-07-23 标 题 :Rapid flame synthesis of doped zno nanorods with controlled aspect ration 发明人:HEIGHT MURRAY J; MAEDLER LUTZ; PRATSINIS SOTIRIS 权利人:ETH ZUERICH; HEIGHT MURRAY J; MAEDLER LUTZ; PRATSINIS SOTIRIS 摘要:Described is a flame spray pyrolysis (FSP) method for the production of nanorods wherein at least one dopant metal precursor is added to a precursor solution of the predominant metal in amounts of at most 15 atom-% referred to the predominant metal, said dopant having an higher valency than the predominant metal, and wherein the crystal lattice of the pure metal oxide formed by FSP is in a hexagonal closed package. In preferred embodiments, the coordination number of the dopant atoms is higher than the coordination number of the predominant metal atoms and the dopant atoms and/or ions and the predominant metal atoms/ions have sizes varying by less than 20 atom-%.
专利号:US-2012168686-A1 优先权日:2009-09-03 标 题:Continuous Synthesis of Carbon-Coated Lithium-Iron-Phosphate 发明人:METZ HANS JOACHIM; WASER OLIVER; BUECHEL ROBERT; PRATSINIS SOTIRIS E 权利人:METZ HANS JOACHIM; WASER OLIVER; BUECHEL ROBERT; PRATSINIS SOTIRIS E; CLARIANT FINANCE BVI LTD 摘要:The invention relates to a continuous process for preparing carbon-coated lithium-iron-phosphate particles, wherein the carbon-coated lithium-iron-phosphate particles have a mean (d 50 ) particle size of 10 to 150 nm, and wherein the carbon-coating is an acetylene-black coating, comprising performing in a reactor a flame-spray pyrolysis step (i) in a particle formation zone of the reactor, and a carbon-coating step (ii) in a carbon-coating zone of the reactor, wherein inn (i) a combustible organic solution containing a mixture of lithium or a lithium compound; iron or an iron compound; and phosphorus or a phosphorous compound in an organic solvent, is fed through at least one nozzle where said organic solution is dispersed, ignited and combusted, to give a flame spray thereby forming an aerosol of lithium iron phosphate particles; (ii) acetylene gas is injected into said aerosol thereby forming an acetylene-black coating on the lithium iron phosphate particles; (iii) the coated particles are cooled by an inert quench gas and collected on a filter.
专利号:CN-110982054-B 优先权日:2019-12-28 标题 :A composite catalyst for catalyzing synthesis of polycarbonate and method for catalyzing synthesis of polycarbonate
专利号:CN-110982054-A 优先权日:2019-12-28 标 题 :A composite catalyst for catalyzing synthesis of polycarbonate and method for catalyzing synthesis of polycarbonate
专利号:US-6013838-A 优先权日:1998-01-27 标题:Chemical intermediates bearing a trifluoromethyl group 发明人:VAN DER PUY MICHAEL 权利人:ALLIED SIGNAL INC 摘要:Novel trifluoromethylated intermediates are provided which are useful in synthesizing trifluoromethylated organic compounds. Specifically, compounds of the formula CF 3 CR are provided, wherein R is (Cl)â•?CHCH 2 SO 2 Ph, (Cl)â•?CHCH 2 CH 2 C(â•?O)CH 3 , (Cl)â•?CHCH 2 CH(COCH 3 ) 2 , (Cl)â•?CHCH 2 NR'R' or Hâ•?CHCHâ•?NR'; R' and R' are the same or different and are selected from the group consisting of hydrogen, unsubstituted or substituted C 1 to C 6 straight chain or branched alkyl, unsubstituted or substituted C 3 to C 7 cycloalkyl, unsubstituted or substituted C 2 to C 12 alkenyl, a benzyl group unsubstituted or substituted with R'', or a phenyl group unsubstituted or substituted with R''; or R' and R' taken together form a five- or six-membered ring; and R'' is an unsubstituted or substituted C 1 to C 6 straight chain or branched alkyl, an unsubstituted or substituted C 1 to C 6 alkoxy, an unsubstituted or substituted C 1 to C 6 thioakyl, a cyano, a halogen, or a C 1 to C 2 dialkylamino group; with the proviso that when the alkyl, cycloalkyl or alkenyl of R' or R' or the alkyl, alkoxy or thioalkyl of R'' is substituted, it may be substituted with any group compatible with amine functionality. The novel compounds are versatile intermediates for the synthesis of a wide variety of trifluoromethylated organic compounds, which have found great utility as pharmaceuticals, agricultural chemicals, and materials such as liquid crystals.
[参考文献]: Murukanahally Kempaiah Devaraju, Et Al. Synthesis, Characterization And Observation Of Antisite Defects In Linipo4 Nanomaterials. Sci Rep. 2015 Jun 19:5:11041.
合成参考文献
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