CAS: 1707-03-5; Diphenylphosphinic Acid

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137219-82-0 72804-96-7 4559-70-0

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CAS号4559-70-0 二苯基磷氧 | CAS号1079-66-9 氯代二苯基膦 | CAS号591-50-4 碘苯 | CAS号829-85-6 二苯基膦 | CAS号1499-21-4 二苯基次膦酰氯 | CAS号125722-48-7 triphenylsilyld... | CAS号108-86-1 溴苯 | CAS号25530-11-4 diphenylphosphi... | CAS号109817-40-5 (2-bromophenyl)... | CAS号4559-70-0 二苯基磷氧 | CAS号1101-41-3 四苯基二膦 | CAS号829-85-6 二苯基膦 | CAS号41593-58-2 硼烷二苯基膦络合物 | CAS号18593-20-9 PHOSPHINIC ACID... | CAS号21713-53-1 1-diphenylphosp... | CAS号10259-20-8 Phosphinic acid... | CAS号5994-87-6 二苯基磷酰胺 | CAS号13689-20-8 环己基双苯膦氧化物

2,4-二硝基苯基二苯基膦酸酯置于水体系中,用 1,4-二氧六环 用作溶剂,化学反应生成二苯基磷酸
参考文献:Cevasco,Giorgio; Thea,Sergio,Journal Of The Chemical Society. Perkin Transactions Ii,1994,# 5,P. 1103-1106
标题:Cevasco,Giorgio; Thea,Sergio,Journal Of The Chemical Society. Perkin Transactions Ii,1994,# 5,P. 1103-1106

专利信息

专利号:US-10040898-B2
优先权日:2016-08-31
标 题:Method for one-step synthesis of functional polyesters by organic catalysis
发明人：GUO KAI; LIU YIHUAN; ZHU NING; HU XIN; FANG ZHENG; FENG WEIYANG; HUANG WEIJUN
权利人:NANJING UNIVERSITY OF TECHNOLOGY
摘要:It relates to the field of synthetic macromolecular chemistry, and discloses a method for one-step synthesis of thiol-functionalized polyester polyols by organic catalysis. This method uses lactone monomer as reaction raw material, thiol-alcohol as initiator, and diphenyl phosphate as organic catalyst to catalyze and synthesize the thiol-functionalized polyester polyols. The present invention provides a method which is simple, inexpensive, easily controllable and environmentally friendly to prepare thiol-functionalized polyester polyols with the easily available and controllable catalyst. The method can selectively catalyze the ring opening polymerization of lactone to prepare thiol-functionalized polyester polyols using the organic catalyst.

专利号:US-6184168-B1
优先权日:1997-09-22
标题:Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst
发明人：LYNCH THOMAS J
权利人:BRIDGESTONE CORP
摘要:The invention provides a catalyst composition, comprising: (a) an organolithium compound; and, (b) an organic acid salt of lanthanide series element; wherein: (1) only components (a) and (b) are required to promote the synthesis of 1,4-trans-polybutadiene; (2) the ratio of component (a) to component (b) is selected to maximize formation of the trans structure of said 1,4-trans-polybutadiene; and, (3) components (a) and (b) are selected for enabling further diblock synthesis. The invention further contemplates a process for using the catalyst to synthesize 1,4-trans-polybutadiene and other polymers and copolymers having trans configuration in the conjugated diene monomer contributed units.

专利号:WO-2007003236-A1
优先权日:2005-06-30
标 题:Process for synthesis of complex 2-deoxy-2-iodo pyranosides of high purity, particularly suitable for manufacturing pharmaceutically pure annamycin
发明人：SZEJA WIESLAW; GRYNKIEWICZ GRZEGORZ; FOKT IZABELA
权利人:ZACLAD BADAWCZO PROD SYNTEX; SZEJA WIESLAW; GRYNKIEWICZ GRZEGORZ; FOKT IZABELA
摘要:The method according to the invention comprises using as glycosyl donors high purity 2- deoxy-2-iodo derivatives of sugars of a defined configuration of C-2 carbon with O-alkyl, S- alkyl, O-aryl, S-aryl, O-heteroaryl, S-heteroaryl, O-acyl, O-silyl, O-N-imido, O-P- (phosphino, phosphono, thiophosphono, selenophosphono) groups at the anomeric position, and subjecting them to a condensation reaction with a compound containing a hydroxyl group or a protected hydroxyl group in the presence of electrophilic reagents, followed by deprotection and isolation of a pharmaceutically pure product. The objective of the present invention is to provide a method for preparing complex glycosides by coupling cyclic multifunctional compounds containing hydroxyl functional groups (glycosyl acceptors, including aglycones of natural origin which are known as constituents of active pharmaceutical ingredients) with diastereoisomerically pure 2-deoxy-2-halopyranosyl derivatives containing anomeric substituent capable of exchange under glycosidating conditions, for example by virtue of activation with electrophilic agents. This method substantially simplifies the synthesis of Annamycin. The present invention relies on a regio- and stereoselective reaction of cohalogenating 1,2- unsaturated sugars in the presence of hydroxyl group containing compounds, such as: water, alcohols, phenols, carboxylic acids, silanols, phosphinic acids, phosphoric acids, thiophosphoric acids, selenophosphoric acids, followed by separation of the product with proper C-2 carbon configuration required for the synthesis. As the separation of stereoisomers is carried out at the stage of obtaining a relatively inexpensive intermediate in the form of glycosyl donor, the method of the invention substantially reduces the cost of Annamycin manufacture. Other advantages of the synthesis process of the invention consist in the reduction of the number of stages of the antibiotic manufacture process and in yield increase of the final product.

专利号:US-10100060-B2
优先权日:2016-06-16
标题:Asymmetric synthesis of funapide
发明人：BEN-DAVID RONEN; CHEN JIAN; CHRISTIE MICHAEL A; DIMITRI MINA GADELRAB; GERSHON GRACIELA NOEMI; HE LINLI; LANDMESSER NELSON G; LEVY DANIEL V; MIZRAHI OREL YOSEF; MUDIPALLI PARTHA S; REESE HARLAN F; SCLAFANI JOSEPH A; WANG YI
权利人:XENON PHARMACEUTICALS INC
摘要:This invention is directed to asymmetric synthesis of funapide, which is useful for the treatment and/or prevention of sodium channel-mediated diseases or conditions, such as pain.

专利号:US-4092316-A
优先权日:1975-02-03
标题:Synthesis of C-alkyl-triethylenediamines
发明人：NIEH EDWARD C Y
权利人:TEXACO DEVELOPMENT CORP
摘要:A liquid phase synthesis of C-alkyl-triethylenediamines involves heating to elevated temperatures of from about 200° C to 300° C a suitable N-(2-hydroxyalkyl) piperazine feedstock in the presence of a catalytic amount of a pentavalent acidic phosphorus compound and then recovering the C-alkyl-triethylenediamine product from the resulting reaction product mixture.

专利号:US-3720736-A
优先权日:1970-03-17
标 题 :Process for the synthesis of dihydrocarbonphosphinates
发明人：QUICK J; VENEZKY D
权利人:US NAVY
摘要:A PROCESS FOR THE SYNTHESIS OF A DIHYDROCARBONPHOSPHINATE WHEREIN A DIHYDROCARBONAHALOPHOSPHINE IS OXIDIZED IN THE PRESENCE OF A DIHYDROCARBON SULFOXIDE, SUCH AS DIMETHYLSULFOXIDE, AND THE REACTION MIXTURE THEREOF IS REACTED WITH AN APPROPRIATE ALCOHOL TO FORM THE DESIRED ESTER.