CAS: 16274-34-3; 1-Hydroxy-2-Prenylnaphthalene
该化合物是一种有机化合物,其特性是其氯化萘结构,代之以氢氧基组和异丙烯侧链.该化合物的特点是一个环,该环具有芳香特性,并存在一个氢氧(OH)组,表明它是一种酒精,有可能影响其溶性与再活性.从异丙烯衍生出的异丙烯组增加了化合物的复杂性,并可能影响其生物活动和相互作用.一般而言,此类化合物具有各种特性,包括潜在的抗氧化活动,而且可能对有机合成,药用化学和材料科学等领域感兴趣.其具体应用和行为将取决于进一步的研究,包括其再活性,稳定性和与其他物质的互动.与许多有机化合物一样,在与该物质打交道时,应当考虑安全数据和处理预防措施.
- 英文名称1-Hydroxy-2-Prenylnaphthalene
- 中文名称2-异戊烯基-1-萘酚
- IUPAC名称2-(3-methylbut-2-en-1-yl)naphthalen-1-ol
- 其它别名2-(3-Methylbut-2-En-1-yl)Naphthalen-1-Ol; 1-Hydroxy-2-Prenylnaphthalene; 2-(3-Methyl-2-Butenyl)-1-Naphthol; 2-Prenyl-1-Naphthol; 1-Naphthalenol, 2-(3-Methyl-2-Buten-1-yl)-; 2-(3-Methyl-2-Buten-1-yl)-1-Naphthol
- CAS编号16274-34-3
- MFCD编号:MFCD20261052
- 分子式:C15H16O分子量:212.29
- 产品CID: 823630
- 产品分类天然产物 → 酚类
物理性质
MSDS等安全信息
上下游产品
1,2-Dihydroxynaphthalene prenyl bromide Dimethylallene α-naphthol 3,4-dihydro-2,2-dimethyl-2H-naphtho[1,2-b]-pyran合成工艺路线路线简述
- 合成目标产物 1-Hydroxy-2-Prenylnaphthalene 主要起始原料 1-Naphthol And Isoprene
- (文献来源)合成步骤主要原料 1-Naphthol 和 Isoprene
📜1-Naphthyl Prenyl Ether置于bismuth(Lll) Trifluoromethanesulfonate体系中,用 甲苯 用作溶剂,化学反应 6.5H,以72%的收率获得2-异戊烯基-1-萘酚
参考文献:Bismuth Triflate Catalyzed [1,3] Rearrangement Of Aryl 3-Methylbut-2-Enyl Ethers
标题:Bismuth Triflate Catalyzed [1,3] Rearrangement Of Aryl 3-Methylbut-2-Enyl Ethers
摘要:我们开发了一种高效的三酸铋催化 3-甲基丁-2-烯基芳基醚 [1,3] 重排反应.该反应进行迅速,并能以中等至非常好的收率(高达 86%)得到相应的对位和正位苯酚和萘酚.
Doi:10.1055/s-2006-950326
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2902600000-乙苯
2902902000-精萘 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-9272260-B2
优先权日:2009-08-14
标 题 :Methods of synthesis and purification by use of a solid support
发明人：HAMMOND GERALD B; XU BO
权利人:HAMMOND GERALD B; XU BO; UNIV LOUISVILLE RES FOUND
摘要:Disclosed herein are novel methods of using polymeric adsorbent resin for chemical synthesis and the purification of product therefrom. Also disclosed herein is a novel method of using silica gel for the combination of chemical reaction and chromatography into a single step. The methods disclosed herein increase the efficiency of chemical synthesis processes. Accordingly, the utility of the methods disclosed herein includes the ability to automate chemical synthesis and purification of the resulting products.
专利号:US-2011077393-A1
优先权日:2009-08-14
标题:Methods of synthesis and purification by use of a solid support
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
参考标题:Benzannulation For The Regiodefined Synthesis Of 2-Alkyl/aryl-1-Naphthols: Total Synthesis Of Arnottin I作者:Dipakranjan Mal,Amit Kumar Jana,Prithiba Mitra,Ketaki Ghosh |发布日期:2011.5.6
摘要:The Annulation Of Phthalides With α-Alkyl/arylacrylates In The Presence Of Lda/lhmds Is Shown To Directly Give Alkyl/aryl-1-Naphthols. The Method Involving A Novel Dealkoxycarbonylation Obviates The Regiochemical Issues In The Synthesis Of Polysubstituted Naphthalenes, And It Forms The Key Step In A Three-Step Total Synthesis Of Arnottin I, A Naphthobenzopyranone Natural Product.
合成参考文献
参考文献:10.1055/s-2006-950326
摘要:Ollevier T, Mwene-Mbeja T. Bismuth Triflate Catalyzed [1,3] Rearrangement of Aryl 3-Methylbut-2-enyl Ethers. Synthesis. 2006 Dec;2006(23):3963–6. doi: 10.1055/s-2006-950326.
参考文献:10.1007/978-3-030-14796-9_13
摘要:Coscolín C, Bargiela R, Martínez-Martínez M, Alonso S, Bollinger A, Thies S, Chernikova TN, Hai T, Golyshina OV, Jaeger K, Yakimov MM, Golyshin PN, Ferrer M. Hydrocarbon-Degrading Microbes as Sources of New Biocatalysts. 2019. In: Taxonomy, Genomics and Ecophysiology of Hydrocarbon-Degrading Microbes.
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