专利号:US-6156922-A 优先权日:1995-12-28 标题 :Method for the synthesis of an aromatic derivative ortho-disubstituted by a halogen atom other than fluorine and by a cyano group 发明人:RUSSELL JAMES; GILBERT LAURENT; MAESTRO JEAN PIERRE 权利人:RHODIA CHIMIE SA 摘要:PCT No. PCT/FR96/02100 Sec. 371 Date Sep. 15, 1998 Sec. 102(e) Date Sep. 15, 1998 PCT Filed Dec. 27, 1996 PCT Pub. No. WO97/24318 PCT Pub. Date Jul. 10, 1997The present invention relates to a method for the synthesis of a halogen substituted aryl nitrile, where the halogens are selected from Cl, Br, or I, by reacting an aryl dihalide with a halogen/fluoride exchange reactant to produce a halogen substituted aryl fluoride which is then reacted with a fluoride/cyanide exchange reactant to produce the halogen substituted aryl nitrile.
专利号:US-3641020-A 优先权日:1969-01-23 标 题 :Synthesis of cyanuric fluoride 发明人:ANDERSON RICHARD W; FRICK HUGHIE R 权利人:DOW CHEMICAL CO 摘要:A PROCESS FOR THE EFFICIENT SYNTHESIS OF CYANURIC FLUORIDE IS PROVIDED. THE PROCESS COMPRISES CONTACTING CERTAIN CYANURIC HALIDES WITH SELECTED ALKALI METAL FLUORIDES IN THE PRESENCE OF A PERHALOCARBONYL COMPOUND. THE PROCESS OF THE PRESENT INVENTION PROVIDES FOR THE PRODUCTION OF CYANURIC FLUORIDE AT CONSIDERABLY REDUCED TEMPERATURES, THAN THOSE USED IN KNOWN PROCESSES.
专利号:US-5519128-A 优先权日:1993-03-31 标题:Process for the synthesis of acylated derivatives of fatty acid-transporting thiols and in particular acyl-coenzymes A and the thus obtained acyl-coenzymes A 发明人:LELLOUCHE JEAN-PAUL; LEVANNIER KARINE; MIOSKOWSKI CHARLES 权利人:COMMISSARIAT ENERGIE ATOMIQUE 摘要:The invention relates to a process for the synthesis of an acylated derivative of a fatty acid-transporting thiol such as the coenzyme A. According to this process, a silylated or stannylated thiol is prepared by reacting the thiol with a silylation or stannylation reagent in order to at least partly replace the unstable hydrogens of the thiol by SiR3 or SnR3 groups with R being an alkyl or aryl group. The silylated or stannylated thiol is then reacted in an anhydrous organic medium with an activated organic acid and a deprotection reagent able to eliminate the silyl or stannyl groups. In this way it is possible to obtain acylated derivatives of the coenzyme A, in which the acyl group can have up to 30 carbon atoms with high yields.
专利号:US-9650330-B2 优先权日:2013-12-12 标题 :Process for the synthesis of aryl sulfones 发明人:MHASKE SANTOSH BABURAO; PANDYA VIRAT 权利人:COUNCIL SCIENT IND RES 摘要:The present patent discloses a novel, efficient and transition-metal-free room temperature single step process for synthesis of aryl sulfones and substituted aryl sulfones starting from aryl substrates.
专利号:US-5354439-A 优先权日:1990-07-16 标 题 :Process for the synthesis of fluorinated derivatives 发明人:FORAT GERARD; GILBERT LAURENT; LANGLOIS BERNARD 权利人:RHONE POULENC CHIMIE 摘要:A process for the synthesis of fluorinated organic compounds and a reagent suitable for use in the process. The process is carried out by exchange with fluorides, while preferably agitating the reaction medium with ultrasonic sound.
专利号:US-8287715-B2 优先权日:2009-05-19 标题:Synthesis of boron using molten salt electrolysis 发明人:TAYLOR PATRICK R; GOMEZ JUDITH C 权利人:TAYLOR PATRICK R; GOMEZ JUDITH C; COLORADO SCHOOL OF MINES 摘要:The invention relates generally to elemental boron, particularly to elemental boron having a high purity level and to a method of recovering elemental boron by the electrolysis of a molten boron-containing electrolyte.
摘要:Witt, D., Science of Synthesis Knowledge Updates, (2011) 3, 323. 摘要:Lishchynskyi, A.; Novák, P.; Grushin, V. V., Science of Synthesis: C-1 Building Blocks in Organic Synthesis, (2013) 2, 395. 摘要:Gong, T.-J.; Ahmed, E.-A. M. A.; Fu, Y., Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis, (2019) 1, 479.