CAS: 100442-89-5; (S)-2-((Tert-Butoxycarbonyl)Amino)-3-(Pyren-1-yl)Propanoic Acid

英文名称(S)-2-((Tert-Butoxycarbonyl)Amino)-3-(Pyren-1-yl)Propanoic Acid
中文名称丁氧羰基-3-(1-芘基)-L-丙氨酸
IUPAC名称(S)-2-((tert-butoxycarbonyl)amino)-3-(pyren-1-yl)propanoic acid
其它别名N-Alpha-T-Butoxycarbonyl-3-(1-Pyrenyl)-L-Alanine; Boc-Ala(1-Pyn)-Oh; Boc-Ala(1-Pyrenyl)-Oh; Boc-3-(1-Pyrenyl)-L-Alanine; 1-Pyrenepropanoic Acid, α-[[(1,1-Dimethylethoxy)Carbonyl]Amino]-, (αs)-; (2S)-2-{[(Tert-Butoxy)Carbonyl]Amino}-3-(Pyren-1-yl)Propanoic Acid; Boc-3-(1-Pyrenyl)-L-Alanine Usp/ep/bp; N-α-(T-Butoxycarbonyl)-β-(1-Pyrenyl)-L-Alanine
CAS编号100442-89-5
MFCD编号:MFCD01861375
分子式:C24H23NO4分子量:389.45
产品CID: 10282
产品分类生物化工 → 氨基酸及其衍生物 → 丙氨酸类衍生物

相似结构搜索
InChIKey: JDYATIJHVFTYFG-IBGZPJMESA-N
InChI=1S/C24H23NO4/c1-24(2,3)29-23(28)25-19(22(26)27)13-17-10-9-16-8-7-14-5-4-6-15-11-12-18(17)21(16)20(14)15/h4-12,19H,13H2,1-3H3,(H,25,28)(H,26,27)/t19-/m0/s1
计算化学: 氢键受体数4.0氢键供体数2.0可旋转键数6.0

MSDS等安全信息

上下游产品

CAS号24424-99-5 二碳酸二叔丁酯 | CAS号87147-90-8 1-pyrenylalanine | CAS号568599-06-4 diethyl 2-(1-py... | CAS号24463-15-8 1-芘甲醇 | CAS号2595-90-6 1-(溴甲基)芘

合成工艺路线路线简述

合成目标产物 Boc-3-(1-Pyrenyl)-L-Alanine 主要起始原料 Di-Tert-Butyl Dicarbonate And 1-Pyrenylalanine
(文献来源)合成步骤主要原料 Di-Tert-Butyl Dicarbonate 和 1-Pyrenylalanine

📜1-(溴甲基)芘置于氢氧化钾,Sodium Hydroxide,Aminoacylase,Sodium Hydride,三乙胺,Cobalt(II) Chloride体系中,用四氢呋喃,1,4-二氧六环,乙醇,水用作溶剂,化学反应 111.0H,反应生成丁氧羰基-3-(1-芘基)-L-丙氨酸
参考文献:A Non-Covalent Strategy For The Assembly Of Supramolecular Photocurrent-Generating Systems
标题:A Non-Covalent Strategy For The Assembly Of Supramolecular Photocurrent-Generating Systems
摘要:Three Photocurrent-Generating Thin Films Were Assembled On Gold Surfaces. Sam I Was Constructed From Molecules Consisting Of An Alkyl Disulfide Group Linked Covalently To A 12-Residue Helical Peptide And Terminated With An Alanine Residue Containing A Pyrene Chromophore. Sam I Served As A Benchmark For Multilayered Films Ii And Iii In Photocurrent Generation Experiments. Films Ii And Iii Were Assembled From Several Components That Were Linked Noncovalently By Metal-Ligand Complexation. Cyclic Voltammetry And Contact Angle Measurements Suggest That The Films Consist Of Ordered Layers With Relatively Few Defects. Photoexcitation Of Sam I By The Output Of A 350 Nm Lamp ( Approximately 0.2 Mw Power Incident On The Sample) Results In Current Generation In The Range 5-10 Na/cm2. Photoexcitation Of Ii And Iii Yields Higher Current In The Range 10-30 Na/cm2,Representing A Quantum Efficiency Of Approximately 1%. The Observation Of Comparable Or Higher Current From Noncovalently Assembled Multicomponent Films Indicates That This Method Of Assembly May Obviate The Problems Associated With The Covalent Assembly Of Devices From Large Molecules.
Doi:10.1021/ja0289548