CAS: 80-07-9; 4,4'-Sulfonylbis(Chlorobenzene)

• 英文名称4,4'-Sulfonylbis(Chlorobenzene)
• 中文名称4,4'-二氯二苯砜
• IUPAC名称4,4'-sulfonylbis(chlorobenzene)
• 其它别名双(4-氯苯基)砜; P-Chlorophenyl Sulfone
• CAS编号80-07-9
• MFCD编号:MFCD00000619
• EINECS号:201-247-9
• FDA UNII编号:5U49794253
• 分子式:C12H8Cl2O2S
• 分子量:287.16
• 产品CID: 2362100
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• InChIKey: GPAPPPVRLPGFEQ-UHFFFAOYSA-N
• InChI=1S/C12H8Cl2O2S/c13-9-1-5-11(6-2-9)17(15,16)12-7-3-10(14)4-8-12/h1-8H…
• 计算化学: 氢键受体数2.0氢键供体数0.0可旋转键数2.0

物理性质

• 熔点143-146  °C(文献)
• 沸点419.9±0.0 °C at 760 mmHg
• 闪点211.2±24.6 °C
• 密度1.4±0.1 g/cm3
• PSA:34.14
• LogP:3.8262
• 折射率1.610
• 蒸汽压0.0±0.9 mmHg at 25°C
• 溶解性Chloroform (Slightly), Methanol (Slightly)
• 敏感性易受潮
• 外观形态白色细粉末
• 储存条件密封, 常温干燥保存
• 产品应用该化合物用于制作耐温硬聚合物,如PES或UDEL,通过与双酚A和双酚S聚合. 此外,二氯聚合物在管道,打印机墨盒和汽车引信中找到应用.

MSDS等安全信息

• GHS象形图
• GHS符号GHS08 & GHS07 & GHS09;
  注释: Health hazard & Exclamation mark & Environment
• 危险类别严重眼刺激 类别2
  水生慢性毒性 类别2
  生殖毒性 类别2
  vPvB
  水生急性毒性 类别1
  水生慢性毒性 类别1
  水生慢性毒性 类别4
• 警示词Warning(警告)
• 危险描述H319 |造成严重眼刺激.
  H411 |对水生生物有毒并具有长期持续影响.
  H361fd |怀疑会影响生育能力. 怀疑对胎儿造成损害.
  EUH441 |Strongly accumulates in the environment and living organisms including in humans
  H400 |对水生生物毒性极大.
  H410 |对水生生物毒性极大并具有长期持续影响.
  H413 |可能对水生生物造成长期有害影响.
• 防范说明P264-P273-P280-P391-P501
• 危险等级9
• UN编号3077.0
• 危险品标志Xi,C
• 风险等级Harmful/Corrosive/Moisture Sensitive
• 包装等级Ⅲ
• 安全声明22-24/25-37/39-26
• 危险类别码36/37/38
• WGK Germany2

欧盟法规

上下游产品

合成工艺路线路线简述

• 5181-10-2 = 80-07-9
  反应条件:1.1 Reagents: Sodium Bromate Catalysts: 1-Butyl-3-Methylimidazolium Hydrogen Sulfate Solvents: Water; 30 Min,80 °C
  标题:The Highly Selective Metal-Free Oxidation Of Sulfides,Tellurides And Phosphines Using Sodium Bromate In The Presence Of Recyclable Ionic Liquid [bmim]Hso4,At 80 °.
  作者:Rajeswari,M.; Et Al
  参考文献:Journal Of Chemical Research 日期:2016 卷标:40(7) 页码:442-444]
  
  5181-10-2 = 80-07-9
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: Diphenyl Disulfide,Palladium Solvents: Methanol,Water; 6 H,100 °C
  标题:Synthesis And Nano-Pd Catalyzed Chemoselective Oxidation Of Symmetrical And Unsymmetrical Sulfides
  作者:Li,Xing; Et Al
  参考文献:Organic & Biomolecular Chemistry 日期:2019 卷标:17(11) 页码:3048-3055]
  
  14752-66-0 = 80-07-9
  反应条件:1.1 Reagents: Cupric Acetate Solvents: Acetonitrile; Rt -> 60 °C; 3 H,60 °C
  标题:Synthesis Of Biarylsulfones By Homo-Coupling Of Sodium Arylsulfinate
  作者:Zhang,Siyi; Et Al
  参考文献:Huaxue Tongbao 日期:2014 卷标:77(12) 页码:1240-1243]
  
  = 80-07-9 [标题:Reaction Conditions
  标题:Synthesis And Reactions Of Arylcarboxylic Fluorosulfonic Acid Anhydrides
  作者:Effenberger,Franz; Et Al
  参考文献:Chemische Berichte 日期:1981 卷标:114(5) 页码:1967-71]
  
  98-60-2 = 80-07-9
  反应条件:1.1 Catalysts: Trifluoromethanesulfonic Acid; 24 H,160 °C
  标题:Triflic-Acid-Catalyzed Friedel-Crafts Reaction For The Synthesis Of Diaryl Sulfones
  作者:Falconnet,Alban; Et Al
  参考文献:European Journal Of Organic Chemistry 日期:2022 卷标:2022(26)]
  
  5181-10-2 = 80-07-9
  反应条件:1.1 Reagents: Water,Selectfluor Solvents: Acetonitrile; 12 H,Rt
  标题:Switchable Synthesis Of Sulfoxides,Sulfones And Thiosulfonates Through Selectfluor-Promoted Oxidation With H2O As O-Source
  作者:Guo,Xuqiang; Et Al
  参考文献:Synthesis 日期:2022 卷标:54(8) 页码:1996-2004]
  
  14752-66-0 = 80-07-9
  反应条件:1.1 Reagents: Oxygen Catalysts: Cupric Acetate Solvents: Acetonitrile; 3 H,60 °C
  标题:Synthesis Of Symmetrical Diaryl Sulfones By Homocoupling Of Sodium Arylsulfinates
  作者:Peng,Yao
  参考文献:Journal Of Chemical Research 日期:2014 卷标:38(5) 页码:265-268]
  
  2751-25-9 = 80-07-9
  反应条件:1.1 Catalysts: Cupric Acetate Solvents: N-Methyl-2-Pyrrolidone; Rt -> 100 °C; 3 H,100 °C
  标题:Cu(Oac)2 Mediated Homo-Coupling With Arylsulfonyl Hydrazides To Synthesize Biarylsulfone
  作者:Wang,Jianwei; Et Al
  参考文献:Youji Huaxue 日期:2014 卷标:34(4) 页码:767-773]
  
  4547-68-6 = 80-07-9
  反应条件:1.1 Reagents: Trifluoromethanesulfonic Acid Solvents: Dichloromethane; 3 H,Rt1.2 Reagents: Water; Rt
  标题:Regiospecific Cleavage Of S-N Bonds In Sulfonyl Azides: Sulfonyl Donors
  作者:Zhang,Zhiguo; Et Al
  参考文献:Journal Of Organic Chemistry 日期:2019 卷标:84(7) 页码:3919-3926]
  
  98-66-8 = 80-07-9 [标题:Reaction Conditions
  标题:Preparation Of Bis(4-Chlorophenyl)Sulfone
  参考文献:Germany]
  
  98-66-8 = 80-07-9 [标题:Reaction Conditions
  标题:Diaryl Sulfones
  参考文献:World Intellectual Property Organization]
  
  14752-66-0 + 26018-88-2 = 80-07-9
  反应条件:1.1 Solvents: 1-Butyl-3-Methylimidazolium Tetrafluoroborate; 2 - 3 H,40 °C; 40 °C -> Rt
  标题:Ionic Liquid-Accelerated Arylation Of Sodium Arenesulfinates With Diaryliodonium Salts Used For The Synthesis Of Diaryl Sulfones
  作者:Wang,Feng-Yan; Et Al
  参考文献:Journal Of Chemical Research 日期:2003 卷标:(10) 页码:620-621]
  
  = 80-07-9
  反应条件:1.1 Reagents: Sulfur Trioxide
  标题:Preparation Of Bis(4-Chlorophenyl)Sulfone
  参考文献:Germany]
  
  14752-66-0 + 1679-18-1 = 80-07-9
  反应条件:1.1 Reagents: Tetraethylammonium Tetrafluoroborate Solvents: Acetonitrile,Water; 5 H,Rt
  标题:Catalyst-Free Electrochemical Sulfonylation Of Organoboronic Acids
  作者:Yao,Weiwei; Et Al
  参考文献:Journal Of Organic Chemistry 日期:2023 卷标:88(4) 页码:2296-2305]
  
  14874-70-5 + 14752-66-0 + 46449-60-9 = 80-07-9
  反应条件:1.1 Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: Dimethylformamide1.2 Reagents: Ammonium Chloride Solvents: Water1.3 Solvents: Diethyl Ether
  标题:Hypervalent Iodine In Synthesis. Part 67. A Convenient Method For The Synthesis Of Diaryl Sulfones By Palladium-Catalysed Arylation Of Sodium Arenesulfinates With Diaryliodonium Salts
  作者:Zhou,Tao; Et Al
  参考文献:Journal Of Chemical Research 日期:2000 卷标:(10) 页码:474-475]
  
  106-39-8 = 80-07-9
  反应条件:1.1 Reagents: Diisopropylethylamine,Potassium Pyrosulfite Catalysts: Palladium Diacetate,Tri-Tert-Butylphosphonium Tetrafluoroborate Solvents: Dimethylformamide; Rt -> 100 °C; 20 H,100 °C
  标题:Palladium-Catalyzed One-Step Synthesis Of Symmetrical Diaryl Sulfones From Aryl Halides And A Sulfur Dioxide Surrogate
  作者:Tanaka,Hiromichi; Et Al
  参考文献:Chemistry Letters 日期:2019 卷标:48(8) 页码:760-763]
  
  10506-59-9 + 98-66-8 = 80-07-9 [标题:Reaction Conditions
  标题:Methyl Arylsulfonyl Sulfates,Intermediates In The Synthesis Of Aromatic Sulfones
  作者:Joly,Robert; Et Al
  参考文献:Recueil Des Travaux Chimiques Des Pays-Bas Et De La Belgique 日期:1959 卷标:78 页码:527-33]
  
  80-40-0 = 80-07-9 [标题:Reaction Conditions
  标题:Composition Of The Reaction Mixture In The Synthesis Of 4-Methyl-4'-Chlorodiphenyl Sulfone Studied By Using Sulfur-35 Trioxide
  作者:Andrashchuk,N. P.; Et Al
  参考文献:Zhurnal Organicheskoi Khimii 日期:1992 卷标:28(3) 页码:540-4]
  
  455-32-3 = 80-07-9
  反应条件:1.1 Reagents: Sulfur Trioxide2.1 -
  标题:Synthesis And Reactions Of Arylcarboxylic Fluorosulfonic Acid Anhydrides
  作者:Effenberger,Franz; Et Al
  参考文献:Chemische Berichte 日期:1981 卷标:114(5) 页码:1967-71

海关参考信息

• 2903919090-氯苯
  2930909099-其他有机硫化合物
  2904990090-其他烃的磺化、硝化、亚硝化衍生物
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

专利信息

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管