CAS: 7783-86-0; Iron(Ii) Iodide

该化合物是一种无机化合物,其特点是铁和碘的形成,一般是黑褐或黑的固体,以其离子结合而闻名,在+2氧化状态下存在铁.FeI2在水中溶解,溶解性可能受温度和其他离子的影响.该化合物经常用于各种用途,包括作为化学合成的试剂和准备其他铁化合物.铁碘化物还可能由于铁的存在而具有磁性,而铁是一种过渡性金属.在安全方面,FeI2应谨慎处理,因为它可能会刺激皮肤和眼睛,并应采取适当的安全措施避免吸入或摄入.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

iodine iron sulfur dioxide iron pentacarbonylbis{bis(diphenylphosphino)methane}di-iodoiron

合成工艺路线路线简述

    碘,铁粉置于al体系中,用 Neat (No Solvent) 作为反应溶剂,化学反应生成 碘化铁(II),
    参考文献:Schiefenhoevel; Binnewies; Janetzko,Zeitschrift Fur Anorganische Und Allgemeine Chemie,2001,Vol. 627,# 7,P. 1513-1517
    标题:Schiefenhoevel; Binnewies; Janetzko,Zeitschrift Fur Anorganische Und Allgemeine Chemie,2001,Vol. 627,# 7,P. 1513-1517

    专利信息


    专利号:US-7615169-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-7927516-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:WO-2012001578-A1
    优先权日:2010-06-29
    标 题 :Single-step synthesis of iron oxide nanoparticles
    发明人:BURDINSKI DIRK; HAEX NICOLE PETRONELLA MARTIEN
    权利人:KONINKL PHILIPS ELECTRONICS NV; BURDINSKI DIRK; HAEX NICOLE PETRONELLA MARTIEN
    摘要:The invention provides methods for the synthesis of iron oxide nanoparticles and the particles obtainable by these methods. The particles can be used as tracer materials for magnetic particle imaging and for Magnetic Particle Spectroscopy (MPS). The method for the synthesis of these particles comprises the steps: (i) dissolving at least one water-soluble iron salt and at least one water-soluble stabilizer in water to form a reaction batch, (ii) adding at least one base to the reaction batch to yield a pH of 10 to 13, and (iii) exposing the reaction batch to a reaction temperature T R for a defined period of time DT, wherein T R ≥ 110°C, to obtain the iron oxide nanoparticles.

    专利号:US-3872101-A
    优先权日:1969-04-11
    标题:Synthesis of {60 , {62 -unsaturated compounds
    发明人:SIDDALL JOHN E; FRIED JOHN H
    权利人:ZOECON CORP
    摘要:Stereospecific synthesis of Alpha , Beta -ethylenically unsaturated compounds by the reaction of an organo-copper or organo-manganese reagent with an Alpha , Beta -acetylenically unsaturated compound at a temperature of -40*C or less.

    专利号:US-11713329-B2
    优先权日:2018-12-10
    标 题 :Intermediates useful in the preparation of halichondrin compounds and methods for preparing the same
    发明人:XU WEIPING
    权利人:BEIJING TIENYI LUFU PHARMATECH CO LTD
    摘要:The invention relates to intermediates useful in the preparation of halichondrin compounds, methods for preparing the same and use thereof, such as halichondrins, eribulin, or their analogs. The intermediates, the methods and use thereof are used for the synthesis of the C20-C26 fragment of halichondrin compounds. The raw materials in the synthetic route of the invention are cheap and easily obtained, the sources and the qualities of the raw materials are reliable. The choice of the methods useful in the synthesis of chiral central structures are based on the structural characteristics of the reactants, thus effectively improving the synthesis efficiency, reducing the difficulties and risks of product quality control, and avoiding the use of highly toxic and expensive organotin catalysts to significantly decrease costs and improve environmental friendliness.

    专利号:US-11400438-B2
    优先权日:2018-12-05
    标 题 :Synthesis and immobilization of a ferrous sulfite catalyst and method of degrading fluorinated organic chemicals in aqueous media
    发明人:DIONYSIOU DIONYSIOS D; ABDELRAHEEM WAEL H M; NADAGOUDA MALLIKARJUNA N
    权利人:UNIV CINCINNATI; THE US ADMINISTRATOR OF THE U S ENVIRONMENTAL PROTECTION AGENCY
    摘要:A composition includes an aqueous solution including at least one fluorinated organic compound; and a reaction product of a source of iron(II) and a source of sulfite in the presence of water and molecular hydrogen. A method of making a catalyst includes reacting a source of iron(II) and a source of sulfite in the presence of water and molecular hydrogen. The water may include less than or equal to 1 weight percent dissolved molecular oxygen. The catalyst may be used for degrading fluorinated organic chemicals in aqueous media.
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    合成参考文献


    摘要:Merck Index - O'Neil MJ, Heckelman PE, Dobbelaar PH, Roman KJ (eds). The Merck Index, An Encyclopedia of Chemicals, Drugs, and Biologicals, 15th Ed. Cambridge, UK: The Royal Society of Chemistry, 2013.
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