📜碘,铁粉置于al体系中,用 Neat (No Solvent) 作为反应溶剂,化学反应生成 碘化铁(II), 参考文献:Schiefenhoevel; Binnewies; Janetzko,Zeitschrift Fur Anorganische Und Allgemeine Chemie,2001,Vol. 627,# 7,P. 1513-1517 标题:Schiefenhoevel; Binnewies; Janetzko,Zeitschrift Fur Anorganische Und Allgemeine Chemie,2001,Vol. 627,# 7,P. 1513-1517
专利信息
专利号:US-7615169-B2 优先权日:2004-09-20 标题 :Method for synthesis of colloidal nanoparticles 发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY 权利人:UNIV CALIFORNIA 摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.
专利号:US-7927516-B2 优先权日:2004-09-20 标题 :Method for synthesis of colloidal nanoparticles 发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY 权利人:UNIV CALIFORNIA 摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.
专利号:WO-2012001578-A1 优先权日:2010-06-29 标 题 :Single-step synthesis of iron oxide nanoparticles 发明人:BURDINSKI DIRK; HAEX NICOLE PETRONELLA MARTIEN 权利人:KONINKL PHILIPS ELECTRONICS NV; BURDINSKI DIRK; HAEX NICOLE PETRONELLA MARTIEN 摘要:The invention provides methods for the synthesis of iron oxide nanoparticles and the particles obtainable by these methods. The particles can be used as tracer materials for magnetic particle imaging and for Magnetic Particle Spectroscopy (MPS). The method for the synthesis of these particles comprises the steps: (i) dissolving at least one water-soluble iron salt and at least one water-soluble stabilizer in water to form a reaction batch, (ii) adding at least one base to the reaction batch to yield a pH of 10 to 13, and (iii) exposing the reaction batch to a reaction temperature T R for a defined period of time DT, wherein T R ≥ 110°C, to obtain the iron oxide nanoparticles.
专利号:US-3872101-A 优先权日:1969-04-11 标题:Synthesis of {60 , {62 -unsaturated compounds 发明人:SIDDALL JOHN E; FRIED JOHN H 权利人:ZOECON CORP 摘要:Stereospecific synthesis of Alpha , Beta -ethylenically unsaturated compounds by the reaction of an organo-copper or organo-manganese reagent with an Alpha , Beta -acetylenically unsaturated compound at a temperature of -40*C or less.
专利号:US-11713329-B2 优先权日:2018-12-10 标 题 :Intermediates useful in the preparation of halichondrin compounds and methods for preparing the same 发明人:XU WEIPING 权利人:BEIJING TIENYI LUFU PHARMATECH CO LTD 摘要:The invention relates to intermediates useful in the preparation of halichondrin compounds, methods for preparing the same and use thereof, such as halichondrins, eribulin, or their analogs. The intermediates, the methods and use thereof are used for the synthesis of the C20-C26 fragment of halichondrin compounds. The raw materials in the synthetic route of the invention are cheap and easily obtained, the sources and the qualities of the raw materials are reliable. The choice of the methods useful in the synthesis of chiral central structures are based on the structural characteristics of the reactants, thus effectively improving the synthesis efficiency, reducing the difficulties and risks of product quality control, and avoiding the use of highly toxic and expensive organotin catalysts to significantly decrease costs and improve environmental friendliness.
专利号:US-11400438-B2 优先权日:2018-12-05 标 题 :Synthesis and immobilization of a ferrous sulfite catalyst and method of degrading fluorinated organic chemicals in aqueous media 发明人:DIONYSIOU DIONYSIOS D; ABDELRAHEEM WAEL H M; NADAGOUDA MALLIKARJUNA N 权利人:UNIV CINCINNATI; THE US ADMINISTRATOR OF THE U S ENVIRONMENTAL PROTECTION AGENCY 摘要:A composition includes an aqueous solution including at least one fluorinated organic compound; and a reaction product of a source of iron(II) and a source of sulfite in the presence of water and molecular hydrogen. A method of making a catalyst includes reacting a source of iron(II) and a source of sulfite in the presence of water and molecular hydrogen. The water may include less than or equal to 1 weight percent dissolved molecular oxygen. The catalyst may be used for degrading fluorinated organic chemicals in aqueous media.
摘要:Merck Index - O'Neil MJ, Heckelman PE, Dobbelaar PH, Roman KJ (eds). The Merck Index, An Encyclopedia of Chemicals, Drugs, and Biologicals, 15th Ed. Cambridge, UK: The Royal Society of Chemistry, 2013.