CAS: 629-23-2; Tetradecan-3-One

相似化合物

45206-91-5 540-08-9 462-18-0

上下游产品

CAS号17642-48-7 (+/-)-1-Tetrade... | CAS号112-54-9 十二醛 | CAS号3344-77-2 12-溴-1-十二烷醇 | CAS号81819-07-0 12-bromododecanal | CAS号101999-60-4 14-bromo-1-tetr... | CAS号557-91-5 1,1-二溴乙烷 | CAS号111-82-0 月桂酸甲酯 | CAS号594-02-5 1,1-Diiodoethane | CAS号1653-32-3 3-十四醇

📜3-十四醇置于2,2,6,6-四甲基哌啶氧化物,Copper(II) Nitrate Trihydrate,氧气体系中,用 1,2-二氯乙烷 作为反应溶剂,化学反应 48.0H,以89%的收率获得产物乙基十一基酮
参考文献:铜催化的以氧气为氧化剂氧化醇制备醛或酮类化合物的方法和应用
标题:铜催化的以氧气为氧化剂氧化醇制备醛或酮类化合物的方法和应用
摘要:本发明公开了一种铜催化的以氧气为氧化剂氧化醇制备醛或酮类化合物的方法,在室温下,以铜盐,氮氧自由基为催化剂,以氧气或空气作为氧化剂,在有机溶剂中反应4~48小时,高效地将醇类化合物氧化为对应的醛或酮类化合物.本发明方法操作简单,避免使用对设备有腐蚀性的氯化物,原料和试剂易得,反应条件温和,底物普适性广,官能团兼容性好,分离纯化方便,整个过程对环境友好,不存在污染,是一种适合工业化生产的方法.

专利信息

专利号:US-2003158422-A1
优先权日:2000-02-04
标 题:Synthesis of 3,6-dialkyl-5,6-dihydro-4-hydroxy-pyran-2-one

专利号:US-2003158423-A1
优先权日:2000-02-04
标 题:Synthesis of 3,6-dialkyl-5,6-dihydro-4-hydroxy-pyran-2-one

专利号:US-2003171602-A1
优先权日:2000-02-04
标 题 :Synthesis of 3,6-dialkyl-5,6-dihydro-4-hydroxy-pyran-2-one

专利号:US-4430346-A
优先权日:1981-05-11
标 题 :Novel carcinostatic substance and process for synthesis thereof
发明人：UMEZAWA HAMAO; TAKEUCHI TOMIO; KONDO SHINICHI; IINUMA HIRONOBU; IKEDA DAISHIRO; NAKAMURA TERUYA; FUJII AKIO
权利人:BRISTOL MYERS CO
摘要:The novel compound represented by the general formula (I) ##STR1## (wherein R represents a hydrogen atom, an alkanoyl group of 1 to 14 carbon atoms, or an arylcarbonyl group), and an acid addition salt thereof [on condition that when R is a hydrogen atom, the hydrochloride exhibits an optical rotation of [α] D 22 -1° ±2° (c, 2 water)] has antitumor activity in experimental animals.

专利号:US-6545165-B1
优先权日:2000-02-04
标 题 :Synthesis of 3,6-dialkyl-5,6-dihydro-4-hydroxy-pyran-2-one

专利号:US-6743927-B2
优先权日:2000-02-04
标题:Synthesis of 3,6-dialkyl-5,6-dihydro-4-hydroxy-pyran-2-one