CAS: 6287-38-3; 3,4-Dichlorobenzaldehyde

上下游产品

CAS号1805-32-9 3,4-二氯苄醇 | CAS号5331-92-0 3,4-二氯苯甲醛肟 | CAS号1162648-58-9 3,4-Cl2-Ph-CH2OTMS | CAS号2039-83-0 3,4-二氯苯乙烯 | CAS号3084-17-1 5-Chloro-2-hydr... | CAS号7157-27-9 2,5-dichlor°Cyc... | CAS号16588-34-4 4-氯-3-硝基苯甲醛 | CAS号6425-25-8 3,5-dichloro-N-... | CAS号95-75-0 3,4-二氯甲苯 | CAS号75-17-2 甲醛肟(10%的水溶液,约2.... | CAS号101349-83-1 3-chloro-4-meth... | CAS号55513-17-2 1-(3,4-二氯苄基)哌嗪 | CAS号32598-13-3 3,3',4,4'-四氯联苯 | CAS号1805-32-9 3,4-二氯苄醇 | CAS号51-44-5 3,4-二氯苯甲酸 | CAS号41421-27-6 5-(3,4-二氯苯基)-1H-四唑 | CAS号2039-83-0 3,4-二氯苯乙烯 | CAS号18989-80-5 2,6-Bis(3,4-dic... | CAS号17947-66-9 1-(3,4-Dichloro... | CAS号22966-16-1 2-Propen-1-one,...

3,4-二氯氯苄置于苯并[c]噌啉,Sodium Iodide体系中,用 N,N-二甲基甲酰胺 作为反应溶剂,以85%的收率获得产物3,4-二氯苯甲醛
参考文献:肼-O2氧化还原对作为有机催化氧化的平台:苯并[c] Cinnoline催化的烷基卤化物氧化为醛类
标题:肼-O2氧化还原对作为有机催化氧化的平台:苯并[c] Cinnoline催化的烷基卤化物氧化为醛类
摘要:描述了一种有机催化氧化平台,该平台利用了肼快速自氧化为二氮烯的能力.在涉及亲核攻击,质变和水解的新型机理范式中,显示出可商购的苯并[C]肉桂啉催化烷基卤化物氧化为醛.仅使用不定形的氧气和水就容易发生水解和再氧化事件.显示了对可行底物范围的调查,以及对这种催化方式有深入了解的机理和计算研究.
DOI:10.1002/anie.201807134

专利信息

专利号:US-6121054-A
优先权日:1997-11-19
标 题 :Method for separation of liquid and solid phases for solid phase organic syntheses
发明人：LEBL MICHAL
权利人:TREGA BIOSCIENCES INC
摘要:A simple, efficient apparatus and method for separation of solid and liquid phases useful in methods of high-throughput combinatorial organic synthesis of large libraries or megaarrays of organic compounds is disclosed. The apparatus and method are useful, whether as part of an automated, robotic or manual system for combinatorial organic synthesis. In a preferred embodiment, an apparatus and method of removal of liquid phase from solid phase compatible with microtiter plate type array(s) of reaction vessels is disclosed.

专利号:US-5783577-A
优先权日:1995-09-15
标题 :Synthesis of quinazolinone libraries and derivatives thereof
发明人：HOUGHTEN RICHARD A; OSTRESH JOHN M
权利人:TREGA BIOSCIENCES INC
摘要:The present invention provides synthetic combinatorial libraries of organic compounds based on the quinazolinone ring.

专利号:US-5175302-A
优先权日:1987-07-13
标 题 :Nucleophilic fluoroalkylation of aldehydes
发明人：STAHLY G PATRICK
权利人:ETHYL CORP
摘要:Aryl difluoromethyl sulfone adds to aldehydes under phase transfer conditions to give novel substituted alcohols of the general formula n n RCH(OH)CF.sub.2 SO.sub.2 Ar (I) n n wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.

专利号:US-4837327-A
优先权日:1987-07-13
标 题 :Process for nucleophilic fluoroalkylation of aldehydes
发明人：STAHLY G PATRICK
权利人:ETHYL CORP
摘要:Aryl difluoromethyl sulfone adds to alkehydes under phase transfer conditions to give novel substituted alcohols of the general formula n n RCH(OH)CF.sub.2 SO.sub.2 Ar (I) n n wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.

专利号:US-4999429-A
优先权日:1989-01-09
标 题 :Process for the preparation of α,α,β-1-trifluoro-1-olefinic derivatives
发明人：STAHLY G PATRICK
权利人:ETHYL CORP
摘要:Aryl difluoromethyl sulfone adds to aldehydes under phase transfer conditions to give novel substituted alcohols of the general formula n n RCH(OH)CF.sub.2 SO.sub.2 Ar (I) n n wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.

专利号:US-9206196-B1
优先权日:2014-07-11
标 题 :Derivatives of benzoxazino quinoline, benzoxazino isoquinoline and processes for their preparation
发明人：BIJU AKKATTU THANKAPPAN; BHUNIA ANUP; SHANMUGAM DHANASEKARAN
权利人:COUNCIL SCIENT IND RES
摘要:Novel benzoxazino quinoline derivatives of Formula (I) and benzoxazino isoquinoline derivatives of Formula (II) are provided: n n n n n n n n n n Also provided is a transition-metal-free multicomponent reaction of arynes, N-heterocycles, and carbonyl compounds leading to the diastereoselective synthesis of benzoxazino quinoline derivatives of Formula (I) and benzoxazino isoquinoline derivatives of formula (II) in good yields proceeding via 1,4-zwitterionic intermediates. The compounds possess anti-malarial activity.