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CAS号354999-84-1 1-Chloro-3,3,3-... | CAS号26885-67-6 Z-1-甲氧基-3,3,3-三氟丙烯 | CAS号932395-40-9 3,3,3-trifluoro... | CAS号2240-88-2 3,3,3-三氟丙-1-醇 | CAS号936107-87-8 1,1'-Oxybis(3,3... | CAS号126015-38-1 (E)-1-ethoxy-3,... | CAS号661-54-1 3,3,3-三氟-1-丙炔 | CAS号116586-94-8 3,3,3-三氟丙醛二甲基乙缩醛 | CAS号41463-83-6 3,3,3-氟丙酰氯 | CAS号19256-25-8 3,3,3-trifluoro... | CAS号2516-99-6 3,3,3-三氟丙酸 | CAS号431-54-9 3,3,3-trifluoro... | CAS号82107-24-2 2,2-dichloro-3,... | CAS号64-18-6 甲酸 | CAS号353-50-4 氟光气 | CAS号75-89-8 三氟乙醇 | CAS号75-90-1 三氟乙醛 | CAS号52222-73-8 4-(三氟甲基)-1H-吡唑1,1-Dipropoxy-3,3,3-Trifluoropropane置于盐酸,溶剂黄146体系中,用 水 作为反应溶剂,化学反应 6.0H,以96.4%的收率获得产物3,3,3-三氟丙醛
参考文献:3,3,3-三氟丙醛的制备方法
标题:3,3,3-三氟丙醛的制备方法
摘要:本发明公开了一种3,3,3-三氟丙醛的制备方法,该方法在三口烧瓶中加入1,1-二烷氧基-3,3,3-三氟丙烷(Cf3Ch2Ch(Or)2),乙酸和催化剂,升温至90oc~140°C,搅拌下反应2H~8H.其中1,1-二烷氧基-3,3,3-三氟丙烷cf3Ch2Ch(Or)2中r为ch3,C2H5C3H7,C4H9,C5H11,C6H13,C7H15,C8H17,C9H19,C10H21;所用催化剂为硫酸,盐酸,对甲苯磺酸,甲基磺酸,三氟乙酸;其中1,1-二烷氧基-3,3,3-三氟丙烷:乙酸:催化剂的摩尔比为1:2~2.5:0.1~0.6.
专利信息
专利号:WO-2017089470-A1
优先权日:2015-11-27
标 题:Process for the synthesis of aryldiazonium salts using nitrogen oxides in oxygen-containing gas streams, especially from industrial waste gases
发明人:HOFMANN DAGMAR; HOFMANN JOSEFA; HEINRICH MARKUS
权利人:Friedrich-Alexander-Universität Erlangen-Nürnberg
摘要:The present invention relates to a process for the synthesis of aryldiazonium salts using nitrogen oxides in oxygen-containing gas streams, especially from industrial waste gases.
专利号:US-2013338369-A1
优先权日:2011-03-07
标 题 :Process for the Synthesis of Aminobiphenylene
发明人:HEINRICH MARKUS; PRATSCH GERALD
权利人:HEINRICH MARKUS; PRATSCH GERALD; BASF SE
摘要:The present invention relates to a process for the synthesis of 2-aminobiphenylene and derivatives thereof by reacting a benzene diazonium salt with an aniline compound under basic reaction conditions.
专利号:US-2004147789-A1
优先权日:2000-02-11
标题 :Allyl esters substituted by a difluoromethylene group, their process of synthesis and their use, and a process for functionalizing a double bond
发明人:ROQUES NICOLAS
权利人:RHODIA CHIMIE SA
摘要:This invention provides compounds of formula: n n n in which R f is a radical that carries a perfluoromethylene group, which group ensures bonding to the remainder of the molecule; R1 and R3, which can be the same or different, are chosen from among hydrogen and alkyl or aryl radicals; Ψ is an electroattractor group such that Ψ-O—H is an acid whose pKa (in water) is at most equal to 8, advantageously 6, and preferably 5. These compounds are useful for the synthesis of nitrogen-containing heterocyclic compounds.
专利号:US-8772301-B2
优先权日:2009-12-18
标题 :Compounds for treating disorders mediated by metabotropic glutamate receptor 5, and methods of use thereof
发明人:HARDY LARRY WENDELL; HEFFERNAN MICHELE L R; WU FRANK XINHE; SPEAR KERRY L; SARASWAT LAKSHMI D
权利人:HARDY LARRY WENDELL; HEFFERNAN MICHELE L R; WU FRANK XINHE; SPEAR KERRY L; SARASWAT LAKSHMI D; SUNOVION PHARMACEUTICALS INC
摘要:Provided herein are compounds and methods of synthesis thereof. The compounds set forth herein are useful for the treatment, prevention, and/or management of various disorders, such as neurological disorders, neurodegenerative disorders, neuropsychiatric disorders, disorders of cognition, learning or memory, gastrointestinal disorders, lower urinary tract disorder, and cancer. Compounds set forth herein modulate the activity of metabotropic glutamate receptor 5 (mGluR5) in the central nervous system or the periphery. Pharmaceutical formulations containing the compounds and their methods of use are also provided herein.
专利号:EP-2546229-A1
优先权日:2011-07-15
标 题:Method for synthesising aminobiphenyls
发明人:HEINRICH MARKUS; PRATSCH GERALD
权利人:UNIV FRIEDRICH ALEXANDER ER
摘要:The present invention describes a process for the synthesis of 2-aminobiphenyls and derivatives thereof. This method is inexpensive to carry out and based on selective implementation. Functionalized biphenyl compounds are of great interest in particular as pharmaceuticals and crop protection agents and as precursors of such active substances. The process for preparing a compound of formula 3 is characterized in that a compound of formula 1 is reacted with a compound of formula 2.
专利号:WO-2012120003-A1
优先权日:2011-03-07
标 题 :Process for the synthesis of aminobiphenylene