CAS: 3351-32-4; 2-Methylchrysene

该化合物是一种多环芳烃,其特点是其复合引信环结构,由四根引信贝内内环和附在第二个位置上的一组甲基组成,在室温下,该化合物一般没有色素,可粉黄固态,以其疏水性闻名,使其在水中无法溶解,但在有机溶剂中可溶解.2-甲基丙烯对环境化学很感兴趣,因为它在化石燃料中出现,并具有作为污染物的潜力.该化合物还因其诱变性和致癌性特性而得到承认,使人们担心其对人类健康和环境的影响.该化合物可以在有机材料的不完全燃烧过程中形成,例如汽车排放和工业加工过程中.该化合物存在于各种基质中,包括空气,土壤和沉积物中,已经进行了研究,以评估环境污染和人类接触风险.与许多多多全氟辛基苯一样,适当的处理和处置对于减轻与接触相关的健康风险至关重要.

结构式图片

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1705-85-7 218-01-9 3351-31-3

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1-乙烯萘 1-Vinylnaphthalene 826-74-4

合成工艺路线路线简述

    📜2-Bromo-5-Methyl Benzenediazonium Tetrafluoroborate置于magnesium体系中,化学反应生成2-甲基屈
    参考文献:795.多环芳烃的合成.第四部分.方便地合成丙烯和三种甲基丙烯
    标题:795.多环芳烃的合成.第四部分.方便地合成丙烯和三种甲基丙烯
    摘要:
    Doi:10.1039/jr9610004079

    海关参考信息

    专利信息


    专利号:US-2003162992-A1
    优先权日:2001-12-14
    标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides
    发明人:WATANABE KYOICHI A; DU JINFA
    摘要:The present invention is an efficient process for the manufacture of α-acyloxyacetaldehyde, a key intermediate in the synthesis of 1,3-oxathiolane and 1,3-dioxolane nucleosides.

    专利号:US-8729310-B2
    优先权日:2009-09-22
    标题:Halogenated diarylamine compound and synthesis method thereof
    发明人:OSAKA HARUE; INOUE HIROTO
    权利人:OSAKA HARUE; INOUE HIROTO; SEMICONDUCTOR ENERGY LAB
    摘要:An object is to provide a new halogenated diarylamine compound serving as a source material for synthesis of a variety of diarylamine compounds and triarylamine compounds and a synthesis method of the new halogenated diarylamine compound. A halogenated diarylamine compound represented by the following general formula (G1) and a synthesis method thereof are provided. Note that a variety of diarylamine compounds and triarylamine compounds can be synthesized using the halogenated diarylamine compound represented by the following general formula (G1).

    专利号:US-5821387-A
    优先权日:1997-12-22
    标题 :Polyarenes from aryl ketones with application to synthesis of crisnatol mesylate
    发明人:ARCHIBALD THOMAS G; BARNARD JAMES C; HUANG DER-SHING
    权利人:AEROJET GENERAL CO
    摘要:Alkyl-substituted polyarenes of the formula ##STR1## in which R is alkyl and Ar res is an aryl residue, are prepared from aryl ketones by reaction of the latter with 1-cyclohexenyloxytrimethylsilane in the presence of a Friedel-Crafts catalyst. When R is methyl and Ar res is a naphthyl residue, the reaction serves as a step in a reaction scheme leading to crisnatol mesylate, a pharmaceutical useful in the treatment of brain cancer.

    专利号:CA-2470202-A1
    优先权日:2001-12-14
    标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides

    专利号:WO-03051298-A2
    优先权日:2001-12-14
    标 题:Preparation of intermediates useful in the synthesis of antiviral nucleosides

    专利号:EP-1461041-A4
    优先权日:2001-12-14
    标 题:PREPARATION OF INTERMEDIATES SUITABLE FOR THE SYNTHESIS OF ANTIVIRAL NUCLEOSIDES

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:The Preparation Of Derivatives Of Chrysene By Means Of The Robinson-Mannich Base Synthesis Of Unsaturated Ketones
    作者:A. L. Wilds,C. H. Shunk |发布日期:1943.3

    合成参考文献


    参考文献:10.1007/s00216-017-0224-y
    摘要:Große Brinkhaus S, Thiäner JB, Achten C. Ultra-high sensitive PAH analysis of certified reference materials and environmental samples by GC-APLI-MS. Analytical and Bioanalytical Chemistry. 2017 Feb 15;409(11):2801–12. doi: 10.1007/s00216-017-0224-y.
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