CAS: 23996-25-0; 2-Ethyl-4-Methyl-1H-Imidazole-1-Propanenitrile

相似化合物

23996-16-9 2258-25-5 23996-55-6

2-乙基-4-甲基咪唑,丙烯腈置于c22H48N4(4+)*4Ho(1-)体系中,用 Neat (No Solvent) 用作溶剂,化学反应 1.17H,以87%的收率获得1-氰乙基-2-乙基-4-甲基咪唑
参考文献:在无水/无溶剂条件下使用 [ch]Oh 和 [n-丁基乌洛托品]Oh 作为碱性离子液体将 N-杂环与 α,β-不饱和化合物进行 Aza-Michael 加成的有效方案
标题:在无水/无溶剂条件下使用 [ch]Oh 和 [n-丁基乌洛托品]Oh 作为碱性离子液体将 N-杂环与 α,β-不饱和化合物进行 Aza-Michael 加成的有效方案
摘要:摘要 目前的工作强调使用设计和合成的碱性离子液体 [n-丁基乌洛托品]Oh 和市售的氢氧化胆碱 [ch]Oh 水溶液作为催化剂进行 N-杂环的 Aza-Michael 加成的绿色方法. α,β-不饱和化合物在室温下.这些催化剂的突出特点包括使用低浓度的两种催化剂以及低成本和可生物降解的 [ch]Oh,[正丁基乌洛托品]Oh 显着提高了高底物/催化剂比,从而以高产率和纯度获得所需的产品在大多数情况下.此外,两种催化剂都可循环使用,最多可回收五次.图形概要
Doi:10.1080/00397911.2018.1546401

专利信息

专利号:US-2002161219-A1
优先权日:2001-02-21
标 题:Non-enzymatic large scale synthesis of RNA
发明人：KANAVARIOTI ANASTASSIA; DEAMER DAVID W; MONNARD PIERRE-ALAIN M; BERNASCONI CLAUDE F
摘要:This invention pertains to the development of methods that accomplish efficient, non-enzymatic, nucleic acid-directed (e.g. RNA-directed) nucleic acid (e.g. RNA) synthesis. In certain embodiments the methods provide conditions that favor oligouridylate synthesis with excellent yield and, at least, up to 30% regioselectivity favoring the RNA linkage. The methods preferably involve contacting, in the presence of lead ions (Pb 2+ ) and/or tin ions (Sn 2+ ) and, optionally, magnesium ions (Mg 2+ ), a template nucleic acid with a nucleotide derivatized with an imidazolide.

专利号:US-10385167-B2
优先权日:2015-02-13
标题:Process for the synthesis of polyoxazolidinone compounds with high stability
发明人：MÃœLLER THOMAS ERNST; Gürtler Christoph; BASU SUSMIT; RANGHEARD CLAUDINE; RIVILLO DAVID; LEITNER WALTER; Köhler Burkhard
权利人:COVESTRO DEUTSCHLAND AG
摘要:The present invention relates to polyoxazolidinone compounds, a method for the production of polyoxazolidinone compounds, comprising the step of reacting a biscarbamate compound with a bisepoxide compound in the presence of a mono-carbamate, a mono-isocyanate and/or a mono-epoxide compound as chain regulator and a suitable base having a pK b value of ≤9 as catalyst. The invention further relates to the use of polyoxazolidinone compounds with high thermal stability.

专利号:US-4658009-A
优先权日:1985-03-14
标题:Novel 2-substituted-4,6-diamino-s-triazine/isocyanuric acid adduct, process for synthesis of said adduct and process for curing polyepoxy resin with said adduct
发明人：KAMAGATA KAZUO; YAMADA TOSHIAKI; SAWA NATSUO
权利人:SHIKOKU CHEM
摘要:Disclosed is a 2-substituted-4,6-diamino-s-triazine/isocyanuric acid adduct represented by the following formula: (1) wherein R stands for an alkyl group having 2 to 20 carbon atoms, an unsubstituted or cyano group-substituted aryl group, or a group of the formula R1-CH2CH2- in which R1 stands for an alkoxy group having up to 20 carbon atoms, an acyloxy group, an amino group, an N-substituted amino group, a benzotriazolyl group or a 2-alkylimidazolyl-(4)-dithiocarbonyl group, or by the following formula: (2) wherein R2 stands for an alkylene group which may have an intervening imino or phenylene group. When this adduct is used for curing a polyepoxy resin, a cured product having good heat resistance, insulating property and adhesion and an excellent migration-preventing effect is formed.

专利号:CN-102675559-B
优先权日:2012-05-22
标题:A method for in-situ synthesis of inorganic nanoparticle hybrid epoxy-based vacuum pressure impregnation resin

专利号:US-2010121022-A1
优先权日:2006-10-17
标 题 :1,3-dipolar cycloaddition of azides to alkynes
发明人：MUSA OSAMA M; SRIDHAR LAXMISHA M; YUAN-HUFFMAN QINGWEN WENDY
权利人:MUSA OSAMA M; SRIDHAR LAXMISHA M; YUAN-HUFFMAN QINGWEN WENDY
摘要:A process for the bulk polymerization, in the absence of any solvent, of a reactant containing azide functionality and a reactant containing a terminal alkyne functionality, in the presence of Cu (I) catalyst or in the presence of a Cu(II) catalyst without a reducing agent, is described. Polymerization can be achieved at temperatures less than 100° C., which is suitable for low temperature cures. A controlled synthesis for low molecular weight oligomers is disclosed.

专利号:EP-3256508-B1
优先权日:2015-02-13
标题:Process for the synthesis of polyoxazolidinone compounds with high stability