CAS: 13986-26-0; Zirconium(Iv)Iodide

该化合物是一种无机化合物,其特点是其深褐色和黑晶表面,由和碘组成,在+4氧化状态下有;该化合物以高反应性而著称,特别是在水分存在的情况下,导致水解,形成氧化和碘化;ZrI4通常是通过在高温下用碘直接反应而合成的.它有各个领域的应用,包括材料科学和作为合成其他化合物的前体.该化合物的熔点相对较高,在有机溶剂中溶解,因此在某些化学反应中有用.由于它具有再活性,处理ZrI4需要谨慎,因为它能够释放有害碘蒸气.适当的安全措施,包括使用个人防护设备,并在通风良好的地区工作,在处理该物质时至关重要.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

zirconium iodine hydrogen iodide zirconium(IV) oxidezirconium(IV) oxide sulfur zirconium silicon tetraiodide

合成工艺路线路线简述

    📜Iodozirconic Acid 以 Neat (No Solvent) 用作溶剂,化学反应生成碘化锆(Iv)
    参考文献:Chauvenet,E.; Davidowicz,J.,Comptes Rendus Hebdomadaires Des Seances De L'Academie Des Sciences,1929,Vol. 189,P. 408-409
    标题:Chauvenet,E.; Davidowicz,J.,Comptes Rendus Hebdomadaires Des Seances De L'Academie Des Sciences,1929,Vol. 189,P. 408-409

    专利信息


    专利号:US-7098354-B2
    优先权日:2002-10-25
    标 题:Racemoselective synthesis of rac-diorganosilylbis(2-methylbenzo[e]indeyl)zirconium compounds
    发明人:DAMRAU HANS-ROBERT; MUELLER PATRIK; GARCIA VALERIE; SIDOT CHRISTIAN; TELLIER CHRISTIAN; LELONG JEAN-FRANCOIS
    权利人:BASELL POLYOLEFINE GMBH
    摘要:The present invention relates to a specific process for the diastereoselective synthesis of rac-diorganosilylbis(2-methylbenzo[e]indenyl)zirconium compounds of the formula I, n nby reacting the silyl-bridged bisindenyl ligand with a dihalozirconium bis(3,5-di-tert-butylphenoxide)-base adduct to form the diorganosilylbis(2-methylbenzo[e]indenyl)zirconium bis(3,5-di-tert-butylphenoxide) and subsequently replacing the phenoxide groups by X using suitable replacement reagents to give the compound of the formula I; where the substituents X can be identical or different and are each F, Cl, Br, I or linear, cyclic or branched C 1-10 -alkyl; and the substituents R can be identical or different and are each linear, cyclic or branched C 1-10 -alkyl or C 6-10 -aryl; and also to the use of these compounds as catalysts.

    专利号:US-9079164-B2
    优先权日:2012-03-26
    标题:Single reaction synthesis of texturized catalysts
    发明人:WOODFIELD BRIAN F; SMITH STACEY; SELCK DAVID; BARTHOLOMEW CALVIN H; MA XUCHU; XU FEN; OLSEN REBECCA E; ASTLE LYNN
    权利人:UNIV BRIGHAM YOUNG
    摘要:Methods are described for making a texturized catalyst. The textural promoter may be a high-surface area, high-porosity, stable metal oxide support. The catalyst is manufactured by reacting catalyst precursor materials and support materials in a single, solvent deficient reaction to form a catalyst. The catalyst may be particles or a coating or partial coating of a support surface.

    专利号:US-9896523-B2
    优先权日:2015-06-26
    标题 :Ziegler-Natta catalyst synthesis and process thereof
    发明人:SINGH GURMEET; KUMAR NARESH; KAUR SUKHDEEP; BANTU BHASKER; KAPUR GURPREET SINGH; SHASHIKANT
    权利人:INDIAN OIL CORP LTD
    摘要:The present invention describes a process of preparing a catalyst for olefin polymerization comprising: (i) treating a magnesium metal with an organohalide along with an internal donor to obtain a reaction mixture having solid component (A); (ii) treating the reaction mixture having solid component (A) with an acyl halide to obtain a reaction mixture having solid component (B); and (iii) treating the reaction mixture having solid component (B) of step (ii) with a transition metal compound to obtain the catalyst. The present invention also relates to a process for preparation of a catalyst system from said catalyst and preparation of a polyolefins from the catalyst system.

    专利号:US-2017312313-A1
    优先权日:2016-04-28
    标 题 :Synthesis of ultra-small ceria-zirconia nanoparticles and ceria-zirconia nano complex and its application as a therapeutic agent for sepsis

    专利号:US-7973193-B2
    优先权日:2003-10-02
    标题:Method for producing ester condensed product
    发明人:ISHIHARA KAZUAKI; YAMAMOTO HISASHI
    权利人:JAPAN SCIENCE & TECH AGENCY
    摘要:The present invention is to provide a method for preparing an ester condensate and a catalyst therefore; wherein the method enables synthesis of enormous amounts of ester condensates comprising a specific structure in good yield, by a reaction of carboxylic acid and alcohol in equimolar amounts, while generation of by-products is prevented; wherein the catalyst exhibits good catalytic efficiency as a catalyst for use, the use of the catalyst in small amount is sufficient, and the catalyst is reusable and can be used repeatedly; therefore, the method for preparing an ester condensate of the present invention and the catalyst therefore can be applied to industrial methods which are preferable in view of green chemistry. Esterification reaction is performed by using a catalyst comprising a zirconium(IV) compound and/or a hafnium(IV) compound and an iron compound and a gallium compound. It is preferable that the zirconium(IV) compound is a compound represented by Zr(OH) a (OR 1 ) b , wherein, R 1 represents an acyl group or an alkyl group, and each of a and b is 0 or any one of integers of 1 to 4 and the relationship of a+b=4 is satisfied, and a zirconium(IV) halide.

    专利号:WO-2019045418-A1
    优先权日:2017-08-28
    标题 :An organic zinc catalyst, an organic zinc catalyst prepared by the method, and a method for producing a polyalkylene carbonate resin using the catalyst
    发明人:BANG JUNGUP; PARK KYOSUNG; PARK SEUNG YOUNG; HWANG GYO HYUN; CHOI BYUNG HEE; KIM SUNG-KYOUNG; BANG YONGJU
    权利人:LG CHEMICAL LTD
    摘要:The present invention relates to a method for producing an organic zinc catalyst used in the synthesis of a polyalkylene carbonate resin, an organic zinc catalyst provided therefrom, and a method for producing a polyalkylene carbonate resin using the catalyst. The organic zinc catalyst according to the present invention may contain Zr in a certain amount on the surface through a simple process and exhibit improved catalytic activity over conventional processes in the polymerization process for the production of polyalkylene carbonate resin.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Negishi, E.-i.; Takahashi, T., Science of Synthesis, (2003) 2, 693.
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