专利号:US-6350875-B1 优先权日:1999-08-16 标 题:Synthesis of cyclooctatetraene derivatives and their use as electron transporters in organic light emitting diodes 发明人:WEBER WILLIAM P; LU PING; THOMPSON MARK E; HONG HAIPING 权利人:UNIV SOUTHERN CALIFORNIA 摘要:The synthesis of asymmetric tetrasubstituted cyclooctatetraenes (“COTsâ€?) and the use of said compounds in organic light emitting diodes is reported, wherein said COTs represent a class of wide gap electron transporters that are readily deposited in vacuum.
专利号:US-8987451-B2 优先权日:2012-01-03 标题 :Synthesis of cyclometallated platinum(II) complexes 发明人:TSAI JUI-YI; KOTTAS GREGG; YEAGER WALTER 权利人:UNIVERSAL DISPLAY CORP 摘要:A single-step method of making tetradentate platinum complexes is disclosed. The method advantageously allows the formation of a platinum complex in a single step, even with sterically hindered ligands, without the use of highly reactive intermediates. The compounds made by the disclosed method are useful in OLED applications.
专利号:US-2024215280-A1 优先权日:2022-10-31 标 题:In situ core/shell perovskite nanocrystal material, method of preparation thereof, and light emitting device comprising the same 发明人:LEE TAE-WOO; KIM JOO SUNG 权利人:SEOUL NAT UNIV R&DB FOUNDATION; PEROLED CO LTD 摘要:The present inventive concept relates to an in situ core/shell perovskite nanocrystal film formed by an in situ nanocrystal synthesis process, a method for producing the same, and a light emitting device comprising the same as a light-emitting layer. The in situ core/shell perovskite nanocrystal film formed by the in situ nanocrystal synthesis process according to the present inventive concept exhibits a strong charge confinement effect by nanocrystal formation, and can simultaneously greatly improve the luminescence efficiency and lifetime by maintaining the fast charge transport capability of polycrystalline perovskite.
专利号:US-2019036041-A1 优先权日:2014-10-28 标 题:Organometallic Iridium Complex, Light-Emitting Element, Light-Emitting Device, Electronic Device, Lighting Device, and Synthesis Method of Organometallic Iridium Complex 发明人:INOUE HIDEKO; YAMAGUCHI TOMOYA; SEO SATOSHI; YAMADA YUI 权利人:SEMICONDUCTOR ENERGY LAB 摘要:A high-purity organometallic iridium complex is provided. The organometallic iridium complex includes iridium and a plurality of ligands cyclometallated to the iridium. Each of the plurality of ligands includes a heteroaromatic ring having a coordinatable nitrogen atom. In LC analysis of the organometallic iridium complex, an impurity which has a monochlorinated ligand among the plurality of ligands is 0.1% or less by quantitating using peak area count with a PDA detector.
专利号:EP-4471014-A1 优先权日:2023-05-29 标 题 :Derivate of quinoxaline with thermally activated delayed fluorescence 发明人:SERDIUK ILLIA; MONKA MICHAL; GRZYWACZ DARIA 权利人:UNIV GDANSKI 摘要:The invention relates to the triarylamine derivatives of quinoxaline with thermally activated delayed fluorescence (TADF) bearing heavy atoms and methods of their synthesis. The emitters are characterized by spectral and photophysical properties with improved TADF parameters as compared to their analogues reported before. The disclosed emitters can convert triplet excitons into singlet ones faster and with higher efficiency. The emitters cover orange, red, and/or near infrared (NIR) spectral ranges. Furthermore, the mixtures of new emitters with fluorescent dopants exhibit narrowband NIR emission preserving fast triplet-singlet exciton conversion.The invention concerns functional organic materials which exhibit TADF and can be potentially used for the electroluminescence applications, e.g. in organic light emitting diodes (OLED), and/or applications of materials with long-lived excited states, e.g. photosensibilization, photocatalysis, and/or other fields where excited triplet states or excitons play important role.
专利号:US-2013172561-A1 优先权日:2012-01-03 标 题:Synthesis of cyclometallated platinum(ii) complexes
[参考文献]: Chloé De Perre, Et Al. A Simultaneous Extraction Method For Organophosphate, Pyrethroid, And Neonicotinoid Insecticides In Aqueous Samples. Arch Environ Contam Toxicol. 2015 May;68(4):745-56. [参考文献]: Gabriela Morin, Et Al. A Rhesus Rhadinovirus Viral Interferon (Ifn) Regulatory Factor Is Virion Associated And Inhibits The Early Ifn Antiviral Response. J Virol. 2015 Aug;89(15):7707-21. [参考文献]: Jinxiang Dai, Et Al. Olig1 Acetylation And Nuclear Export Mediate Oligodendrocyte Development. J Neurosci. 2015 Dec 2;35(48):15875-93. [参考文献]: Johannes G M Rack, Et Al. The Phd Finger Of P300 Influences Its Ability To Acetylate Histone And Non-Histone Targets. J Mol Biol. 2014 Dec 12;426(24):3960-3972. [参考文献]: Khushbu K Modi, Et Al. Sodium Benzoate, A Metabolite Of Cinnamon And A Food Additive, Upregulates Ciliary Neurotrophic Factor In Astrocytes And Oligodendrocytes. Neurochem Res. 2015 Nov;40(11):2333-47.
合成参考文献
参考文献:10.1055/s-0039-1690759 摘要:Ban J, Lim M, Shabbir S, Baek J, Rhee H. Site-Specific Synthesis of Carbazole Derivatives through Aryl Homocoupling and Amination. Synthesis. 2019 Nov 26;52(06):917–27. doi: 10.1055/s-0039-1690759. 参考文献:10.1007/978-3-030-63713-2_63 摘要:Fresta E, Costa RD. Applying Ionic Transition Metal Complexes to Light-Emitting Electrochemical Cells. 2022. In: Springer Handbooks. 参考文献:10.1007/s40843-022-2350-7 摘要:Ban C, Yin Y, Luo X, Liu Z, Chen K, Tang M, Dong X, Zhang D, Li Z, Wu Y, Liu J, Huang W. Light-/steam-driven polymeric crosslinking with porous multistructure pattern for ultrastable and fast-speed memory. Sci. China Mater. 2023 Feb 06;66(5):2023–31. doi: 10.1007/s40843-022-2350-7. 参考文献:10.1007/s00214-023-02966-1 摘要:Mandal S, Datta A. DFT calculations predict that inverted geometries at carbon can be stabilized within multi-component co-crystals. Theor Chem Acc. 2023 Feb 23;142(3). doi: 10.1007/s00214-023-02966-1. 参考文献:10.1055/a-1904-0582 摘要:Qian L, Liao J, Tao L. Catalytic Asymmetric [3+3] Cycloaddition of Activated Isocyanides with Azomethine Imines. Synlett. 2022 Aug 12;33(19):1873–8. doi: 10.1055/a-1904-0582.