CAS: 32997-62-9; Hydride,Ytterbium(3+)

📜氯化镱(III) 以 Neat (No Solvent) 用作溶剂,化学反应生成氢化镱
参考文献:Klemm,W.; Bommer,H.,Zeitschrift Fur Anorganische Und Allgemeine Chemie
标题:Klemm,W.; Bommer,H.,Zeitschrift Fur Anorganische Und Allgemeine Chemie

专利信息

专利号:US-11926589-B2
优先权日:2019-07-09
标 题 :Process for the synthesis of non-racemic cyclohexenes
发明人：REISMAN SARAH; ROMBOLA MICHAEL; LADD CAROLYN L; MCLAUGHLIN MARTIN JOHN; ZUEND STEPHAN; GOETZ ROLAND
权利人:BASF CORP; CALIFORNIA INST OF TECHN
摘要:This invention relates to a process for the synthesis of a non-racemic cyclohexene compound of formula (I) by a Diels-Alder reaction of a compound of formula (II) with a compound of formula (III) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and Y have the meanings as defined in the description in the presence of a catalyst comprising at least one m-valent metal cation M m+ wherein the metal M is selected from Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium 15 (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Thulium (Tm), Ytterbium (Yb), Lutetium (Lu), Gallium (Ga) and Indium (In), and m is an integer of 1, 2 or 3, and a chiral ligand of the formula (IV) wherein R 10a , R 10b , R 10c , R 10d , R 10a′ , R 10b′ , R 10c′ , R 10d′ , Z and Z′ have the meanings as defined in the description.

专利号:US-2024075466-A1
优先权日:2021-04-09
标 题:One-Pot Synthesis of Transition Metal-Promoted Chabazites
发明人：VAN TENDELOO LEEN; SCHUETZE FRANK-WALTER; VERHEYEN ELKE JANE JUNE
权利人:UMICORE AG & CO KG
摘要:The invention provides methods for a one-pot synthesis of molecular sieves of the CHA-type. The method uses molecular and non-molecular sieves as sources of silicon and aluminum. A first OSDA is selected from tetraethylenepentamine (TEPA) and triethy-lenepentamine (TETA). The synthesis mixture comprises a first metal selected from copper, iron and zinc. Optionally, the synthesis mixture may furthermore comprise a second OSDA and/or a second metal selected from manganese, cesium, magnesium, calcium, strontium, barium, yttrium, titanium, zirconium, niobium, iron, zinc, silver, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium and mixtures thereof. The molecular sieves of the CHA-type obtainable by the method can be used as SCR-catalytically active substances for the removal of nitrogen oxides from exhaust gases of combustion engines.

专利号:US-10661239-B2
优先权日:2016-04-29
标 题 :Catalytic reactor configuration, preparation and method of direct synthesis of ethylene through oxygen-free catalysis of methane
发明人：BAO XINHE; GUO XIAOGUANG; FANG GUANGZONG; PAN XIULIAN; MENG JINGHENG; YU QINQIN; TAN DALI
权利人:DALIAN INST CHEM & PHYSICS CAS
摘要:A reactor configuration comprises an inlet section I, a preheating section II, a transition section III, a reaction section IV and an outlet section V; except for the preheating section II and the reaction section IV, the existence of the inlet section I, the transition section III and the outlet section V depends on reaction conditions; and the process realizes no coke deposition synthesis of methane and high selectivity synthesis of ethylene. The methane conversion rate is 20-90%; ethylene selectivity is 65-95%; propylene and butylene selectivity is 5-25%; aromatic hydrocarbon selectivity is 0-30%; and coke deposition is zero.

专利号:US-5502126-A
优先权日:1993-06-17
标 题 :Process for the synthesis of isoprene butadiene rubber
发明人：BELL ANTHONY J; MATRANA BARRY A; HALASA ADEL F
权利人:GOODYEAR TIRE & RUBBER
摘要:The subject invention relates to a technique for synthesizing rubbery non-tapered, random, copolymers of 1,3-butadiene and isoprene. These rubbery copolymers exhibit an excellent combination of properties for utilization in tire sidewall rubber compounds for truck tires. By utilizing these isoprene-butadiene rubbers in tire sidewalls, tires having improved cut growth resistance can be built without sacrificing rolling resistance. Such rubbers can also be employed in tire tread compounds to improve tread wear characteristics and decrease rolling resistance without sacrificing traction characteristics. This invention more specifically discloses a process for the synthesis of isoprene-butadiene rubbers which comprises copolymerizing isoprene monomer and 1,3-butadiene monomer in an organic solvent in the presence of a catalyst system which is made by the sequential steps of (1) mixing (a) an organoaluminum hydride, (b) a member selected from the group consisting of aliphatic alcohols, cycloaliphatic alcohols, aliphatic thiols, cycloaliphatic thiols, trialkyl silanols, and triaryl silanols, and (c) optionally, 1,3-butadiene in an organic solvent to produce a modified organoaluminum catalyst component; (2) adding an organometallic compound which contains a metal from Group III-B of the Periodic System to the modified organoaluminum catalyst component to produce a Group III-B metal containing catalyst component; and (3) adding a compound which contains at least one labile halogen atom to the Group III-B metal containing catalyst component.

专利号:US-5627297-A
优先权日:1995-04-10
标 题 :Process for cleaving the by-products of the direct synthesis of alkylchlorosilanes
发明人：GILBERT LAURENT; LAROZE GILLES
权利人:RHONE POULENC CHIMIE
摘要:The process for cleaving the heavy by-products derived from the synthesis of alkylchlorosilanes, in particular C1 to C6 alkylchlorosilanes, more particularly methylchlorosilanes, in particular for the cleavage of alkylchlorodisilanes, in particular methylchlorodisilanes having from one to five chlorine atoms, is carried out by treatment with hydrochloric acid in the presence of a catalytic system which comprises at least one metal phosphate, preferably associated with a basic impregnation compound. The metal phosphate may in particular correspond to the formula: M(XPO4)y in which M represents a metal chosen from: monovalent metals, in which case X is 2H and y=1 divalent metals, in which case X is H and y=1 trivalent metals, in which case X is absent and y=1 tetravalent metals, in which case X is: H and y=2 pentavalent metals, in which case X is 0 and y=1.

专利号:WO-2024005673-A1
优先权日:2022-06-27
标题:Method for the laser synthesis of endodontic instruments from nickel-titanium
发明人：Chernyshikhin Stanislav Viktorovich; SHISHKOVSKY IGOR VLADIMIROVICH
权利人:AUTONOMOUS NON PROFIT ORGANIZATION FOR HIGHER EDUCATION “SKOLKOVO INST OF SCIENCE AND TECHNOL
摘要:A method for manufacturing a hyperelastic self-adapting file from nickel-titanium powder by 3D printing includes analyzing and preparing an initial nickel-titanium powder material; preparing a thin-walled 3D model of a self-adapting file and converting same into an STL model with a single surface, the normal vectors of which are oriented toward the build axis; splitting the model into separate layers and preparing an execution file containing the vector coordinates for laser scanning in each layer; and synthesizing the self-adapting file layer-by-layer by selective laser melting (SLM) using a nickel-titanium substrate. A file comprises a cylindrical base and a lattice structure. Provided between the lattice structure and the cylindrical base are connectors. All of the elements of the file structure have angles of more than 35° between the overhanging surfaces and the plane of the substrate. The invention makes it possible to increase the resolution of SLM for synthesizing micro-objects, to provide for powder recycling, and also to produce a personalized file for a specific tooth canal type within a short period of time.