CAS: 1931-60-8; 2-Methylidenebutanedioyl Dichloride

该化合物是一种有机化合物,其特征为二氯化功能组,附于一种丁二二烯酸脊椎,其典型特征是无色的黄色淡液,以其反应性闻名,特别是有机合成中的碳化物剂;两个氯原子的存在增强了其电子生殖性,使其在各种化学反应中有用,包括形成酯和胺化物;该化合物对水体敏感,在水中可进行水解,释放盐酸并形成相应的酸;必须谨慎处理2-甲基丁二氯化物,因为它具有腐蚀性,并在接触时对健康造成危害;在实验室环境中,该物质经常被用于合成更复杂的有机分子和制作聚合物;在与该化学品合作时,适当的安全措施,包括使用个人防护设备,至关重要.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

2-methylenesuccinic acid itaconic acid anhydride2-Methylene-succinic acid 4-(11-bromo-undecyl) ester 1-[11-((S)-2-dimethylamino-3-phenyl-propoxycarbonyl)-undecyl] ester 2-(Chloro-dimethyl-silanylmethyl)-succinic acid 4-(11-bromo-undecyl) ester 1-[11-((S)-2-dimethylamino-3-phenyl-propoxycarbonyl)-undecyl] ester Itaconsaeure-diamid

合成工艺路线路线简述

  • 合成目标产物 Itaconyl Chloride 主要起始原料 Itaconic Anhydride
  • (文献来源)合成步骤主要原料 Itaconic Anhydride
📜衣康酸酐置于五氯化磷体系中,化学反应生成衣康酰氯
参考文献:Petri,Chemische Berichte,1881,Vol. 14,P. 1636
标题:Petri,Chemische Berichte,1881,Vol. 14,P. 1636

海关参考信息

专利信息


专利号:US-4000358-A
优先权日:1968-12-19
标题:Unsaturated ester-amides of halogenated alkenes
发明人:D ALELIO GAETANO F
权利人:ALELIO GAETANO F D
摘要:This invention deals with new unsaturated esteramides of alpha , beta -unsaturated polycarboxylic acids derived from halogenated alcohols of the formula wherein R is a divalent hydrocarbon moiety having at least one and no more than 10 carbon atoms, X is a member selected from the class of bromine and chlorine, and R' is a member selected from the class of hydrogen, X and a monovalent hydrocarbon containing at least one and no more than 20 carbon atoms. Typical esteramides are the maleates, fumarates, itaconates and citraconates. These monomers possess fire-retardant properties and are useful for the synthesis of polymers and copolymers.

专利号:US-3950392-A
优先权日:1968-12-19
标题:Unsaturated ester-amides of halogenated alkenes
发明人:D ALELIO GAETANO F
权利人:ALELIO GAETANO F D
摘要:This invention deals with new unsaturated ester-amides of alpha , beta -unsaturated polycarboxylic acids derived from halogenated alcohols of the formula XX ¦¦ HO-R-C=C-R' wherein R is a divalent hydrocarbon moiety having at least one and no more than 10 carbon atoms, X is a member selected from the class of bromine and chlorine, and R' is a member selected from the class of hydrogen and a monovalent hydrocarbon containing at least one and no more than 20 carbon atoms. Typical ester-amides are the maleates, fumarates, itaconates and citraconates. These monomers possess fire-retardant properties and are useful for the synthesis of polymers and copolymers.

专利号:US-2011223112-A1
优先权日:2010-03-14
标题:Unsaturated polyester coated magnetic ultra-fine particles for biological applications
发明人:MORTEZA MAHMOUDI; IMANI MOHAMMAD; SIMCHI ABDOLREZA
权利人:IRAN POLYMER AND PETROCHEMICAL INST
摘要:Unsaturated polyesters e.g. poly (ethylene glycol fumarate) (PEGF) were developed as new coating materials for iron oxide nanoparticles. Different strategies were adopted in their synthesis to provide different characteristics including solubility, molecular weight and structure also degrees of unsaturation. After synthesis of the nanoparticles; the material was applied as a coating on them. These materials were applicable without further processing, however, coatings were cured via thermal, redox or photo initiated crosslinking on the nanoparticles to provide rigid shells on the surface of nanoparticles.

专利号:US-5138023-A
优先权日:1991-10-11
标题 :Unsaturated polyesters and crosslinked membranes therefrom for aromatics/saturates separation
发明人:SARTORI GUIDO; HO W S WINSTON; NOONE ROBERT E
权利人:EXXON RESEARCH ENGINEERING CO
摘要:The present invention describes a method for the synthesis of unsaturated aliphatic polyesters, their crosslinking by thermal treatment and the use of the corresponding crosslinked membranes to separate aromatics from saturates.

专利号:US-5180496-A
优先权日:1991-10-11
标 题 :Unsaturated polyesters and crosslinked membranes therefrom for aromatics/saturates separation
发明人:SARTORI GUIDO; HO W S WINSTON; NOONE ROBERT E
权利人:EXXON RESEARCH ENGINEERING CO
摘要:The present invention describes a method for the synthesis of unsaturated aliphatic polyesters, their crosslinking by thermal treatment and the use of the corresponding crosslinked membranes to separate aromatics from saturates.

专利号:US-3965148-A
优先权日:1972-08-16
标题 :Perfluoroalkyl alcohols
发明人:KLEINER EDUARD K; FALK ROBERT A
权利人:CIBA GEIGY CORP
摘要:Perfluoroalkyl group containing alcohols are disclosed with utility as intermediates for the synthesis of oil and water repellent fluorochemicals. The alcohols are obtained by the addition of mercaptoalcohols to perfluoroalkyl group containing esters of fumaric, maleic, citraconic, mesaconic, itaconic, methylene malonic or aconitic acids.

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合成参考文献


摘要:U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals., NX#02912
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