专利号:WO-2013112823-A1 优先权日:2012-01-25 标题 :Heterophase synthesis of metal-coordinated framework materials for particle size control 发明人:AHN DONGCHAN; LEE JEONG YONG 权利人:DOW CORNING 摘要:Various embodiments of the present invention relate to a method of preparing coordination polymer crystals, and to the crystals produced thereby. The method includes providing a composition. The composition includes Component (i), a metal-containing compound that is a source of one or more metal ions; Component (ii), a bridging ligand-containing compound that is a source of one or more bridging ligands; Component (iii), a first liquid in which (i) and (ii) are soluble; and Component (iv), a second liquid immiscible with the first liquid. The method includes mixing the composition to form an emulsion. The method also includes maintaining the emulsion for a time sufficient to produce a crystalline coordination polymer. Various embodiments also provide methods of making membranes and membranes made thereby wherein the membrane-forming composition includes the coordination polymer crystals, including methods of making membranes wherein coordination polymer crystals form in the membrane or in the membrane-forming composition before, during, or after curing of the membrane-forming composition. Various embodiments also provide methods of gas separation using the membranes.
专利号:US-3676442-A 优先权日:1968-11-22 标 题:Synthesis of pyrazines 发明人:BONZOM ALBERT; TRAMIER BERNARD 权利人:AQUITAINE PETROLE 摘要:Hydrocarbon substituted pyrazines are prepared by the reaction of an ammonium compound having NH4 or NH2 groups with an acetylene compound having an oxygen atom linked to the acetylenic unit, the reaction being conducted in an acid medium, preferably containing formic acid or a formate.
专利号:WO-2023114200-A2 优先权日:2021-12-14 标题 :Methods for the synthesis of complement factor d inhibitors and intermediates thereof
专利号:US-2017137437-A1 优先权日:2014-06-30 标题:Synthesis of halichondrin analogs and uses thereof
专利号:US-3113132-A 优先权日:1961-03-17 标 题:Synthesis of chlorinated alkylpyrazines 发明人:BAXTER GEORGE E; LEVIS JR WILLIAM W 权利人:WYANDOTTE CHEMICALS CORP
专利号:RU-2194703-C2 优先权日:1997-07-17 标题:Hypoglycemic medicinal agent comprising pyrazine derivatives, novel derivatives of pyrazine and methods of their synthesis
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