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CAS号29636-75-7 3-bromopropiophenone | CAS号74-89-5 氨基甲烷 | CAS号30379-59-0 甲基氨基甲酸苄酯 | CAS号10035-10-6 氢溴酸 | CAS号64-19-7 冰醋酸 | CAS号100-39-0 溴化苄 | CAS号71-43-2 苯 | CAS号60-29-7 乙醚 | CAS号7726-95-6 溴素 | CAS号703-85-5 2,4,6-tribromo-...

📜甲胺置于氢溴酸,溶剂黄146体系中,用 水 作为反应溶剂,化学反应 2.0H,以98%的收率获得产物甲胺氢溴酸盐
参考文献:Ch3Nh3Pbbr3钙钛矿纳米晶体作为用于荧光共振能量转移的高效光收集天线
标题:Ch3Nh3Pbbr3钙钛矿纳米晶体作为用于荧光共振能量转移的高效光收集天线
摘要:混合钙钛矿作为高性能光伏设备,发光二极管,光电探测器,存储设备和传感器的低成本材料已经引起了广泛的研究兴趣.发现由于量子约束效应而显示出强烈发光的纳米晶形式的钙钛矿材料特别适合于大多数这些应用.然而,尚未探索钙钛矿纳米晶体作为光收集天线在人工光合作用系统中可能的应用的潜在用途.在本工作中,我们研究了发光甲基铵溴化铅(ch 3 Nh 3 Pbbr 3)的钙钛矿纳米晶体,使用荧光染料(若丹明b,若丹明101和尼罗红)作为能量受体.我们的研究表明,Ch 3 Nh 3 Pbbr 3纳米晶体是一种出色的光收集天线,从纳米晶体到荧光染料的荧光共振能量转移非常有效.此外,发现能量转移效率高度依赖于锚定基团的数目和染料与纳米晶体表面的结合能力.这些观察结果可能对基于钙钛矿的采光设备及其在人工光合作用系统中的可能使用产生重大影响.
DOI:10.1002/asia.201601672

专利信息

专利号:US-7786324-B2
优先权日:2005-02-03
标 题 :Method for producing borazine compound
发明人：YAMAMOTO TETSUYA; KAMIYAMA TAKUYA
权利人:NIPPON CATALYTIC CHEM IND
摘要:In a synthesis of a borazine compound by a reaction of an alkali boron hydride represented by ABH 4 (A represents lithium atom, sodium atom or potassium atom) and an amine salt represented by (RNH 3 ) n X (R represents a hydrogen atom or an alkyl group, X represents a sulfate group or a halogen atom, and n is 1 or 2), or b) diborane (B 2 H 6 ) and an amine represented by RNH 2 (R represents a hydrogen atom or an alkyl group), a water content of raw material is controlled below a prescribed value; mixed solvents containing solvents each having a prescribed boiling point are used as a solvent for reaction; or a raw material is gradually fed to a reactor in a reaction. Or, a borazine compound is subjected to distillation purification treatment and filtration treatment. By such a method, a high purity of borazine compound can be produced safely and in a high yield.

专利号:US-11680035-B2
优先权日:2020-08-03
标 题 :Hole transport material, synthesis thereof, and solar cell
发明人：LIU YUHANG; ZAKEERUDDIN SHAIK MOHAMMED; GRAETZEL MICHAEL; BAUER MICHAEL; BÄUERLE PETER
权利人:ECOLE POLYTECHNIQUE FED LAUSANNE EPFL
摘要:The organic small molecule 4,4′,4″,4′″-(5,5-dimethoxycyclopenta-1,3-diene-1,2,3,4-tetrayl)tetrakis(N,N-bis(4-methoxyhenyl)aniline (CPDA 1), shows electrochemical properties very close to spiro-OMeTAD indicating a high compatibility with PSC systems for its use as a hole transport material (HTM). The implementation of the cyclopentadiene dimethyl acetale core helps to red shift the absorption onset of the films as well as provide a flexible spatial configuration of the molecule, which is essential for optimum film forming properties. Transient and steady state emission analysis as well as hole mobility measurements indicate that the new HTM allows a better charge extraction, transport and separation than the spiro-OMeTAD reference compound. PSCs based on the new CPDA 1 show a PCE close to 23% with lower hysteresis than its analogue. Stability studies performed under ambient, heated and humid conditions all showed that CPDA 1 is over-performing spiro-OMeTAD. Furthermore the production cost of CPDA 1 is about 10 times lower than that of spiro-OMeTAD, contributing to render PSCs more affordable.

专利号:US-10538540-B2
优先权日:2016-06-29
标 题:Perovskite core-shell nanocrystals
发明人：SUM TZE CHIEN; CHEN WEIQIANG; MHAISALKAR SUBODH GAUTAM; MATHEWS NRIPAN; VELDHUIS Sjoerd Antonius; BHAUMIK SAIKAT
权利人:UNIV NANYANG TECH
摘要:Provided is a nanocrystal comprising a core comprised in a shell, wherein the core comprises a first material of a perovskite structure comprising a first organic cation not exceeding a molar weight of about 45 g/mol, a first divalent metal and a first counter anion, and, wherein the shell comprises a second material of a perovskite structure comprising a second organic cation having a molar weight between about 74 g/mol and about 187 g/mol, optionally the first organic cation, a second divalent metal and a second counter anion. Provided is further a matrix having the nanocrystal as defined above encapsulated therein. Provided is further a process for the synthesis of a nanocrystal comprising a core comprised in a shell, the process comprising a) preparing a precursor solution containing at least one divalent metal, a first organic cation not exceeding a molar weight of about 45 g/mol, a second organic cation having a molar weight between about 74 g/mol and about 187 g/mol, and at least one counter anion in a polar aprotic solvent; and b) subjecting the precursor solution to a non-polar solvent to form the nanocrystal.

专利号:CA-2728987-C
优先权日:2008-05-16
标 题 :Green synthesis of nanometals using plant extracts and use thereof

专利号:CA-3072159-C
优先权日:2017-08-10
标题 :Method for synthesis of films made of light-absorbing material with perovskite-like structure

专利号:US-2012055873-A1
优先权日:2008-05-16
标题 :Green synthesis of nanometals using plant extracts and use thereof