CAS: 1661-03-6; Magnesium Phthalocyanine

该化合物是一个全方位磷酸化合物综合体,其特点是其高热和化学稳定性,以及其强烈的蓝色绿色颜色,该化合物在可见和近红外区域表现出强烈的吸收作用,使其在染料,颜料和光电子材料中的应用具有价值,其平面大型循环结构使得-电子脱地效率较高,有助于其光化和半导体特性. (II) 也研究其由于其再氧化活动和光收获能力,在催化系统和有机光伏中的潜在用途.该化合物通常通过在镁盐存在时的卤化循环合成.

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19333-10-9 33864-99-2 27680-31-5

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CAS号91-15-6 邻苯二甲腈

合成工艺路线路线简述

  • 合成目标产物 Magnesium Phthalocyanine 主要起始原料 Phthalonitrile
  • (文献来源)合成步骤主要原料 Phthalonitrile
📜1,2-二氰基苯置于六甲基二硅氮烷,Magnesium Bromide体系中,用 N,N-二甲基甲酰胺 用作溶剂,化学反应 10.0H,以75%的收率获得酞菁镁
参考文献:Novel Synthesis Of Phthalocyanines From Phthalonitriles Under Mild Conditions
标题:Novel Synthesis Of Phthalocyanines From Phthalonitriles Under Mild Conditions
摘要:通过在 100 oc 的 Dmf 中使用金属盐和六甲基二硅氮烷 (Hmds) 进行处理,可以方便地从邻苯二腈中制备酞菁.该反应提供了一种在温和条件下制备多种金属酞菁和取代酞菁以及锌萘酞菁的新方法.
Doi:10.1055/s-2002-34237

海关参考信息

专利信息


专利号:US-2011172437-A1
优先权日:2008-04-01
标题:Perfluorophthalocyanine Molecules and Methods of Synthesis
发明人:GORUN SERGIU M; GERDES ROBERT; GERDES OLGA; LAPOK LUKASZ
权利人:NEW JERSEY TECH INST
摘要:Advantageous methods for synthesis of fluorinated phthalocyanines are provided. Typical implementation involves a reaction mixture that includes perfluoro compound that is reacted for a reaction period sufficient to yield a fluorinated phthalocyanine of formula F 64 PcM, wherein “Pcâ€? is any phthalocyanine macrocycle and “Mâ€? is hydrogen. Novel fluorinated phthalocyanine molecules/compounds are also provided herein, including specifically compounds that include fluorinated phthalocyanines wherein “Mâ€? is Cu or Vâ•?O. The fluorinated phthalocyanines have wide ranging applications, e.g., corrosion-related applications, coating-related applications, catalysis, and the production of optical and electronic materials.

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✅ COA系统入驻 | 共享模式

主要参考文献

[参考文献]: Jane P Bearinger, Et Al. Phototocatalytic Lithography Of Poly(Propylene Sulfide) Block Copolymers: Toward High-Throughput Nanolithography For Biomolecular Arraying Applications. Langmuir. 2009 Jan 20;25(2):1238-44.

合成参考文献


参考文献:10.1039/c3pp50376c
摘要:Uliana MP, Pires L, Pratavieira S, Brocksom TJ, de Oliveira KT, Bagnato VS, Kurachi C. Photobiological characteristics of chlorophyll a derivatives as microbial PDT agents. Photochemical & Photobiological Sciences. 2014 Aug 01;13(8):1137–45. doi: 10.1039/c3pp50376c.
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