CAS: 1462-03-9; 1-Methylcyclopentanol

相似化合物

1462-96-0 1604-02-0 19550-46-0

上下游产品

methyl magnesium iodide 1-hydroxycyclopentanecarbonitrile 1-methyl-4-nitrosobenzene 1-methyl-cyclopentyl hydroperoxide methyl-cyclopentane 1-methylcyclopent-1-ene 3,5-dinitro-benzoic acid-(1-methyl-cyclopentyl ester) 1-methylcyclopentyl p-nitrobenzoate

甲基环戊烷置于水,氢气体系中,用 Gas 用作溶剂,以100%的收率获得1-甲基环戊醇
参考文献:环己基阳离子是否以稀气态存在来自放射性研究的直接证据
标题:环己基阳离子是否以稀气态存在来自放射性研究的直接证据
摘要:通过从 Cc 6/h 12/ 中提取氢阴离子获得的气态 C 6/h 11/ +/ 阳离子的异构体组成已通过允许带电物质在气体中反应进行研究水相并分析形成的中性产物.主要产物环己醇,环己酮和 1-甲基环戊醇的性质和产率,以及它们对压力和气态系统组成的依赖,为稀气态环己基阳离子的存在提供了直接证据,具有寿命超过 10-7/ S,并确认其容易重排为更稳定的 1-甲基环戊基离子.
Doi:10.1021/ja00406A008

专利信息

专利号:US-8957260-B2
优先权日:2011-02-07
标题 :Process for the oxidation of mesitol
发明人：WEYRAUCH JAN PHILIPP; WEIS MARTINE; TELES JOAQUIM HENRIQUE; EBEL KLAUS; DEGLMANN PETER
权利人:WEIS MARTINE; TELES JOAQUIM HENRIQUE; EBEL KLAUS; DEGLMANN PETER; WEYRAUCH VIVIEN ELLINOR; WEYRAUCH GUNHILD; BASF SE
摘要:The invention relates to a process for the oxidation of mesitol with singlet oxygen, which is released from hydrogen peroxide, this release taking place in the presence of a bismuth compound as catalyst. In the process, 2,4,6-trimethylquinol is formed in high yield and selectivity as product, which can be used in further reactions for the synthesis of vitamins and in particular of vitamin A and vitamin E.

专利号:WO-2010108584-A1
优先权日:2009-03-26
标题:Synthesis of n-substituted furan-2(5h)-ones
发明人：IGNATYEV NIKOLAI MYKOLA; ZLOTIN SERGEI G; SIMIRSKAYA NINA I
权利人:MERCK PATENT GMBH; IGNATYEV NIKOLAI MYKOLA; ZLOTIN SERGEI G; SIMIRSKAYA NINA I
摘要:The present invention relates to a process for preparing N-substituted furan-2(5H)-ones where the reaction medium comprises at least one Ionic Liquid, to the use of Ionic Liquids for preparing furan-2(5H)-ones, and to compounds preparable by the aforementioned process.

专利号:US-5637757-A
优先权日:1995-04-11
标 题 :One-pot synthesis of ring-brominated benzoate compounds
发明人：HILL JOHN E; FAVSTRITSKY NICOLAI A; MAMUZIC RASTKO I; BHATTACHARYA BHABATOSH
权利人:GREAT LAKES CHEMICAL CORP
摘要:A method of preparing tetrabromobenzoate compounds from tetrabromophthalic anhydride by reacting tetrabromophthalic anhydride with alcohol in the presence of a decarboxylation catalyst. The reaction may be carried out in an excess of alcohol, or with a near stoichiometric amount of alcohol by performing the reaction in an inert solvent.

专利号:WO-2010115869-A1
优先权日:2009-04-03
标 题 :Propofol phosphonyl derivatives, synthesis, and use in long acting formulations
发明人：GONNISSEN YVES RENE JOHANNA PAUL
权利人:SEPS PHARMA N V; GONNISSEN YVES RENE JOHANNA PAUL
摘要:This invention relates to compounds represented by the structural formula (I), and the salts and stereoisomers thereof, wherein: - L is a linker selected from the group consisting of -(CH 2 ) P -O-, a single bond, formula (IA), -(CH 2 ) 1-8 -O-X(O)-, and - p is an integer from 1 to 8, - each R 3 and each R 4 is independently selected from the group consisting of C 1-20 alkyl, C 3-12 alkyl, C 3-12 cycloalkyl-C 1-4 alkyl, saturated heterocyclyl and saturated heterocyclyl-C 1-4 alkyl, and - X and Y are each independently C or S(O), - Z is selected from the group consisting of O, S(O) and NR 5 , - W is selected from the group consisting of halogen, OH, S(O)H and O - M + wherein M + is a monovalent cation; and - R 5 is selected from the group consisting of hydrogen and C 1-10 alkyl. These compounds are useful pharmaceutical agents with improved oral bioavailability.

专利号:US-7847092-B2
优先权日:2004-12-15
标题:Method for preparation of F-18 containing organofluoro compounds in alcohol solvents
发明人：MOON DAE HYUK; CHI DAE YOON; KIM DONG WOOK; OH SEUNG JUN; RYU JIN-SOOK
权利人:FUTURECHEM CO LTD; ASAN FOUNDATION
摘要:The present invention relates to a method for preparation of organofluoro compounds containing radioactive isotope fluorine-18. More particularly, the present invention relates to a method for preparation of primary or secondary organofluoro compound by reacting fluorine salt containing radioactive isotope fluorine-18 with primary or secondary alkyl halide or primary or secondary alkyl sulfonate in the presence of alcohol of Chemical Formula 1 as a solvent to obtain high yield of organofluoro compound. Synthesis reaction according to the present invention may be carried out under mild condition to give high yield of the organofluoro compounds and the reaction time is decreased, and thereby is suitable for the mass production of the organofluoro compounds.

专利号:WO-9632368-A1
优先权日:1995-04-11
标题:One-pot synthesis of ring-brominated benzoate compounds