CAS: 13122-18-4; Tert-Butyl Peroxy-3,5,5-Trimethylhexanoate

该化合物是一种有机过氧化物,通常用作聚合工艺中的激进起爆剂,其特点是其结构,包括一个三丁基化合物和过氧联系,在热分解时成为自由基的来源,该化合物一般没有颜色,可粉黄黄色液体,其粘度相对较低,其颜色一般不色,在正常条件下具有稳定性,但在接触热,光或污染物时可分解异体.该物质溶于有机溶剂,但水溶性有限.由于其反应性质,该物质被归类为危险物质,需要小心处理和储存,以防止意外分解.安全措施包括使用适当的个人防护设备,并确保工作场所有适当的通风.在工业应用中,该化合物主要用于生产聚合物和树脂,有助于化学工业中各种材料的合成.

⚠️危险化学品目录(2015年版) 有机过氧化物,D型
英文名称Tert-Butyl Peroxy-3,5,5-Trimethylhexanoate
中文名称叔丁基过氧化-3,5,5-三甲基己酸酯
IUPAC名称tert-butyl 3,5,5-trimethylhexaneperoxoate
其它别名Trigonox 42S
CAS编号13122-18-4
MFCD编号:MFCD00126885
EINECS号:236-050-7
FDA UNII编号:84TC2IY818
分子式:C13H26O3
分子量:230.34
产品CID: 2505992
产品分类有机原料 → 羧酸类化合物及衍生物

相似结构搜索
InChIKey: VSJBBIJIXZVVLQ-UHFFFAOYNA-N
InChI=1/C13H26O3/c1-10(9-12(2,3)4)8-11(14)15-16-13(5,6)7/h10H,8-9H2,1-7H3…
计算化学: 氢键受体数3.0氢键供体数0.0可旋转键数7.0

MSDS等安全信息

GHS象形图
GHS符号GHS02 & GHS07 & GHS09;
注释: Flame & Exclamation mark & Environment
危险类别Org. Perox. C
皮肤腐蚀/刺激类别2
皮肤致敏类别1
水生慢性毒性类别2
Org. Perox. D
皮肤致敏类别1B
水生急性毒性类别1
水生慢性毒性类别3
水生慢性毒性类别1
警示词Danger(危险)
危险描述H242 |加热可能引起火灾.
H315 |造成皮肤刺激.
H317 |可能引起皮肤过敏反应.
H411 |对水生生物有毒并具有长期持续影响.
H400 |对水生生物毒性极大.
H412 |对水生生物有害并具有长期持续影响.
H410 |对水生生物毒性极大并具有长期持续影响.
防范说明P273-P391-P501-P261-P272-P280-P302+P352-P333+P313-P321-P363-P501-P273-P501-P210-P220-P234-P280-P370+P378-P403+P235-P411-P420-P501
UN编号3105.0
危险品标志Xi-O,Xi,O
安全声明36/37/39-3/7-26-14A
危险类别码7-38
WGK Germany3

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报DrinkingWaterDirectiveREACH预注册RSIM_DWD_INVENTORY

上下游产品

3,5,5-三甲基己酸 3,5,5-Trimethylhexanoic Acid 01/10/3302

合成工艺路线路线简述

叔丁基过氧化氢,3,5,5-三甲基己酰氯置于potassium Hydroxide体系中,用水用作溶剂,以98.2%的收率获得叔丁基过氧化-3,5,5-三甲基己酸酯
参考文献:Continuous Method For Producing Acyl Peroxides
标题:Continuous Method For Producing Acyl Peroxides
摘要:本发明涉及一种生产酰基过氧化物的连续方法.根据该方法,酰氯,羧酸酐或氯甲酸酯与有机过氧化物或过氧化氢在至少两个混合反应区中串联反应,酰化合物,过氧化合物和碱的水溶液被供给到第一个反应区.第一个反应区通过热交换器包含两相反应混合物的循环,其中反应混合物被冷却.该方法能够可靠地进行反应,并具有高的空间时间收率.

海关参考信息

2905122000-异丙醇
2905143000-叔丁醇
2912110000-甲醛
2912120000-乙醛
💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:US-6610802-B2
优先权日:2001-05-29
标题 :Process for synthesis of polymer compositions, polymer compositionS obtainable by the process, and use of the same
发明人：ROOS SEBASTIAN; EISENBERG BORIS; HARPE CAROLIN
权利人:ROHMAX ADDITIVES GMBH
摘要:The present invention relates to a process for synthesis of polymer compositions with reduced catalyst content, wherein ethylenically unsaturated monomers containing less than 0.5 wt % of ethylenically unsaturated monomers with at least one carboxylic group, sulfonic acid group and/or at least one phosphonic acid group relative to the total weight of the ethylenically unsaturated monomers are polymerized by means of initiators containing a transferable group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts and, after the polymerization, the catalyst contained in the polymer is at least partly separated. For this purpose, the polymer composition is filtered, after the polymerization, in the presence of at least one filter aid which contains at least 0.5 wt %, relative to the total weight of the filter aid, of repeating units that contain at least one carboxylic acid group, sulfonic acid group and/or at least one phosphonic acid group.

专利号:US-2003060587-A1
优先权日:2001-05-29
标题:Process for synthesis of polymer compositions, polymer compositions obtainable by the process, and use of the same

专利号:RU-2586214-C2
优先权日:2011-11-17
标题 :Superabsorbent polymers capable of fast absorption and synthesis method thereof