CAS: 1095-03-0; Triphenyl Borate

该化合物是一种有机化合物,其特征是存在一个附于一个宝藏的苯基组,其典型特征是无色的黄色液体或固态,视其纯度和形态而定.该化合物因其在有机合成中的试剂作用而闻名,特别是在形成酯类和各种化学反应中的催化剂的作用.苯基在乙醇和乙醇等有机溶剂中表现出中等溶解性,但由于其氢恐惧性苯基组而较少溶于水中.其化学结构允许形成各种子体的复合体,使其在化学协调方面有用.此外,苯基酸可以参与水解反应,导致在一定条件下形成苯醇和醋酸.在处理该化合物时,应采取安全防范措施,因为它可能会对皮肤和眼睛产生刺激.总的来说,苯基酸是一种多种化合物,在实验室和工业环境中都具有应用.

结构式图片

相似化合物

7359-58-2 2665-12-5

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

tri-n-propyl borate phenol triacetoxyborane phenylchlorosulfatetributyl borane o-Hydroxyethylbenzene 4-Ethylphenol tripropylborane

合成工艺路线路线简述

  • 合成目标产物 Triphenyl Borate 主要起始原料 Sulfurous Acid Diphenyl
  • (文献来源)合成步骤主要原料 Sulfurous Acid Diphenyl
Phenyl Chlorosulphinate置于三氯化硼体系中,用 二氯甲烷 用作溶剂,化学反应生成三苯基硼酸酯
参考文献:Notes
标题:Notes
摘要:
Doi:10.1039/jr9620001505

海关参考信息

专利信息


专利号:US-2013150622-A1
优先权日:2011-12-12
标题:Stereoselective synthesis of tapentadol and its salts
发明人:FANDRICK DANIEL ROBERT; RODRIGUEZ SONIA; YANG BING-SHIOU
权利人:BOEHRINGER INGELHEIM INT; BOEHRINGER INGELHEIM INT
摘要:A process for the synthesis of a salt of tapentadol.

专利号:WO-9507882-A1
优先权日:1993-09-14
标 题:Synthesis of amido acids from carboxylic acid esters and amino acid salts
发明人:HEINZMAN STEPHEN WAYNE; DUPONT JEFFREY SCOTT
权利人:PROCTER & GAMBLE
摘要:Chemical synthesis of amido acids, and their conversion to amido acid phenyl ester sulfonates for use as bleach activators, starting from carboxylic acid esters and amino acid salts.

专利号:WO-2024018354-A1
优先权日:2022-07-18
标题 :A process for the synthesis of 4-alkoxy-3-hydroxypicolinic acids and intermediates thereof
发明人:MAL SANJIB; SARKAR PARANTAP; PATRA PRANAB KUMAR; KLAUSENER ALEXANDER GUENTHER MARIA
权利人:PI INDUSTRIES LTD
摘要:The present invention discloses a process for the synthesis of 4- alkoxy-3-hydroxypicolinic acids of formula (I) from 2-picolinic acid. The present invention further discloses a process for preparation of compounds of formula (iii) from compounds of formula (ii). The present invention also discloses novel intermediate compounds of formula (iii).

专利号:US-5534642-A
优先权日:1993-09-14
标题 :Synthesis of amido acids from carboxylic acids and lactams
发明人:HEINZMAN STEPHEN W; DUPONT JEFFREY S; TETTENHORST WILLIAM C
权利人:PROCTER & GAMBLE
摘要:Chemical synthesis of amido acids, and their conversion to amido acid phenyl ester sulfates for use as bleach activators, starting from carboxylic acids and lactams.

专利号:US-8192762-B2
优先权日:2005-06-01
标题 :Preparation of soluble and colloidal molecularly imprinted polymers by living polymerization
发明人:KARIM KHALKU; PILETSKY SERGEY ANATOLIYOVICH; PILETSKA OLENA VOLODIMIRIVNA; TURNER ANTHONY PETER FRANCIS; CHIANELLA IVA; GUERRIERO ANTONIO RICARDO LEONARDO
权利人:KARIM KHALKU; PILETSKY SERGEY ANATOLIYOVICH; PILETSKA OLENA VOLODIMIRIVNA; TURNER ANTHONY PETER FRANCIS; CHIANELLA IVA; GUERRIERO ANTONIO RICARDO LEONARDO; UNIV CRANFIELD
摘要:The present invention describes a method for synthesis of relatively low molecular weight imprinted polymers using living polymerization, and their application in analytical chemistry, pharmacology, medicine and the food industry. Specifically the low-molecular weight polymers are synthesized by the polymerization of functional monomers in the presence of a template, such as a biological receptor, enzyme, nucleic acid, cell, virus, microorganism, tissue sample or drug using living initiator. The conditions of living polymerization ensure a relatively small size of synthesized molecules. Synthesized in this way molecules (dimers, oligomers, polymers, or their mixture) have a higher affinity to the template than the original monomers and can rebind it in vitro and/or in vivo. As a further aspect of the present invention, polymers synthesized as described above can be used as drugs in pharmacology and medicine, as receptor-specific ligands in analytical chemistry (sensors, assays), and for separations in the biotechnology, pharmaceutical and food industries.

专利号:US-4041068-A
优先权日:1976-06-29
标题:Synthesis of oxalate esters by catalytic oxidative carbonylation of borate esters
发明人:ZEHNER LEE R; ZAJACEK JOHN G
权利人:ATLANTIC RICHFIELD CO
摘要:A process for the preparation of oxalate esters by the catalytic oxidative carbonylation of orthoborate, metaborate and polyborate esters or mixtures thereof with carbon monoxide and oxygen or an oxygen-containing gas in the presence of a metal salt catalyst, an amine base and at least a catalytic amount of an alcohol. Preferably a catalytic amount of particular metal oxidizing salts are employed along with a catalytic amount of an amine salt compound which may be formed in situ by the addition of an acid. Alternatively various counterions and ligands of the metal salt catalysts may be employed.
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主要参考文献

参考标题:Stereocontrolled Construction Of Tetrasubstituted Tetrahydrofurans: Synthesis Of 2,5-Anhydro D-Glucitol
作者:Biswanath Das,Duddukuri Nandan Kumar |发布日期:2010.11
摘要:A Highly Stereoselective Construction Of 2,3,4,5-Tetrasubstituted Tetrahydrofurans Has Been Accomplished By An Unusual Intramolecular 5-Endo-Tet Cyclization Of 2,3-Epoxy Alcohols Involving Hydroxyl Nucleophile. The Method Has Been Utilized For The Synthesis Of 2,5-Anhydro D-Glucitol Through Two Different Approaches Starting From The Chiral Molecule, L(+)-Diethyl Tartarate Or From The Non-Chiral Compound

合成参考文献


摘要:Aggarwal, V. K.; McGarrigle, E. M.; Shaw, M. A., Science of Synthesis: Stereoselective Synthesis, (2011) 2, 339.
摘要:Tauchert, M. E., Science of Synthesis: C-1 Building Blocks in Organic Synthesis, (2013) 1, 313.
摘要:Jana, A.; Małecki, P.; Grela, K., Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis, (2016) 2, 58.
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