CAS: 603-34-9; Triphenylamine

上下游产品

bromobenzene potassium diphenylamide 2-(N,N-diphenylamino)benzoic acid N,N'-ditrityl-hydrazineN,N'-ditrityl-hydrazinehexachlorobenzene perchlorotriphenylamine tris(4-nitrophenyl)amine tri(cyclohexyl)amine

丁基硫基苯置于potassium Phosphate,Bis[tris(1,1-Dimethylethyl)Phosphine]-Palladium,间氯过氧苯甲酸,Copper(I) Bromide体系中,用 二氯甲烷,乙腈 作为反应溶剂,化学反应 41.0H,反应生成 三苯胺
参考文献:苯胺与烷基(芳基)ulf盐的 Ullmann型n-芳基化反应†
标题:苯胺与烷基(芳基)ulf盐的 Ullmann型n-芳基化反应†
摘要:使用烷基(芳基)ulf三氟甲磺酸酯作为芳基化试剂,实现了钯/铜共催化的苯胺的ullmann型n-芳基化.该反应通过pd(p(t Bu)3)2 / Cui使烷基(芳基)s的c烷基-S键断裂,使c芳基-S键断裂,并以高至高收率得到了相应的n-芳基化产物.同样重要的是,苯胺与不对称的丁基(甲磺酰基)(芳基)ulf三氟甲磺酸酯的反应显示出优异的选择性,其中除了庞大的和富电子的甲磺酰基部分以外的芳基都发生了转化.
DOI:10.1039/c9Cc06535K

专利信息

专利号:US-11236029-B2
优先权日:2019-05-17
标题 :Synthesis of a triangulene ring system and derivatives thereof
发明人：JOHNSON RICHARD PETER; HOLT CARTER J
权利人:THE UNIV OF NEW HAMPSHIRE; UNIV NEW HAMPSHIRE
摘要:A three step synthesis of the 8,12-dihydro-4H-dibenzo[cd,mn]pyren-3a 2 -ylium cation (triangulenium cation) is effected by cascade cyclization of a tetra-benzyl alcohol precursor in triflic acid solution. This cation is easily observed by NMR and optical spectroscopy. Quenching of the cation into basic solutions or by hydride transfer from triethylsilane provides access to stable dihydro and tetrahydro[3]triangulenes. This route makes several [3]triangulene precursors more readily available for development of new applications in the field of molecular electronics.

专利号:US-7141702-B2
优先权日:2004-03-26
标 题 :Process for the synthesis of α-substituted acroleins
发明人：DESHPANDE RAJ M; DIWAKAR MAKARAND M; CHAUDHARI RAGHUNATH V
权利人:COUNCIL SCIENT IND RES
摘要:The present invention provides an improved process for the synthesis of α-substituted acroleins from olefins by a tandem hydroformylation and Mannich reaction sequence in the presence of syngas and formaldehyde, wherein the two catalysts are segregated into two different phases thereby preventing deactivation of the catalysts by each other, and yielding a highly selective and active catalyst.

专利号:US-9929363-B2
优先权日:2013-08-05
标题:Composition and synthesis of aggregation-induced emission materials
发明人：TANG BENZHONG; Xie ni; LAM WING YIP
权利人:UNIV HONG KONG SCI & TECH
摘要:The present subject matter relates to compositions containing and synthesis of fluorescent materials e made from tetraphenylethylene (TPE) derivative compounds exhibiting aggregation induced emission (AIE) properties. Further contemplated herein are applications for TPE derivative compounds such as electroluminescent devices since they have a high efficiency, low turn on voltage, and excellent brightness. Additionally, application of TPE derivatives exhibiting AIE properties in various fields such as OLEDs, fingerprinting and forensic technology, and various other biological and industrial sectors are discussed.

专利号:US-2007249867-A1
优先权日:2004-08-11
标题 :Method for Synthesis of Aromatic Amine
发明人：NAKASHIMA HARUE; KAWAKAMI SACHIKO
权利人:NAKASHIMA HARUE; KAWAKAMI SACHIKO
摘要:One embodiment of the present invention provides a method for synthesis of substituted secondary amine by the reaction of aniline with aryl halide by using a Pd catalyst including (t-Bu) 3 P as a ligand.

专利号:WO-2005063668-A1
优先权日:2003-12-31
标题 :Process for synthesis of alpha-substituted acroleins
发明人：DESHPANDE RAJ MADHUKAR; DIWAKAR MAKARAND MADHUKAR; CHAUDHARI RAGHUNATH VITTHAL
权利人:COUNCIL SCIENT IND RES
摘要:The present invention provides an improved process for the synthesis of α-substituted acroleins from olefins by a tandem hydroformylation and Mannich reaction sequence in the presence of syngas and formaldehyde, wherein the two catalysts are segregated into two different phases thereby preventing deactivation of the catalysts by each other, and yielding a highly selective and active catalyst.

专利号:US-2023192731-A1
优先权日:2020-05-29
标 题 :Process for the stepwise synthesis of silahydrocarbons
发明人：AUNER NORBERT; STURM ALEXANDER G; SANTOWSKI TOBIAS; FELDER THORSTEN
权利人:MOMENTIVE PERFORMANCE MAT INC
摘要:The invention relates to a process for the stepwise synthesis of silahydrocarbons bearing up to four different organyl substituents at the silicon atom, wherein the process includes at least one step a) of producing a bifunctional hydridochlorosilane by a redistribution reaction, selective chlorination of hydridosilanes with an ether/HCl reagent, or by selective chlorination of hydridosilanes with SiCl 4 , at least one step b) of submitting a bifunctional hydridochloromonosilane to a hydrosilylation reaction, at least one step c) of hydrogenation of a chloromonosilane, and a step d) in which a silahydrocarbon compound is obtained in a hydrosilylation reaction.