专利号:US-11400438-B2 优先权日:2018-12-05 标 题 :Synthesis and immobilization of a ferrous sulfite catalyst and method of degrading fluorinated organic chemicals in aqueous media 发明人:DIONYSIOU DIONYSIOS D; ABDELRAHEEM WAEL H M; NADAGOUDA MALLIKARJUNA N 权利人:UNIV CINCINNATI; THE US ADMINISTRATOR OF THE U S ENVIRONMENTAL PROTECTION AGENCY 摘要:A composition includes an aqueous solution including at least one fluorinated organic compound; and a reaction product of a source of iron(II) and a source of sulfite in the presence of water and molecular hydrogen. A method of making a catalyst includes reacting a source of iron(II) and a source of sulfite in the presence of water and molecular hydrogen. The water may include less than or equal to 1 weight percent dissolved molecular oxygen. The catalyst may be used for degrading fluorinated organic chemicals in aqueous media.
专利号:US-4273947-A 优先权日:1979-01-31 标 题:Hydrogenation of fluorine-containing carboxylic acids 发明人:NOVOTNY MIROSLAV 权利人:ALLIED CHEM 摘要:A process is described for the heterogeneous hydrogenation of fluorine-containing alkyl, cycloalkyl, and benzene carboxylic acids to the corresponding primary alcohols. The hydrogenation can be carried out in the liquid or vapor phase in the presence of a solid rhodium or iridium catalyst, employed as the metal, metallic oxide, or mixture thereof. In the liquid phase, the hydrogenation can be carried out batchwise under mild conditions of temperature and pressure, preferably at about 50°-150° C. and about 5-15 atmospheres, in an atmosphere containing hydrogen gas. A preferred embodiment is the hydrogenation of trifluoroacetic acid in the liquid phase to 2,2,2-trifluoroethanol, said alcohol being useful as an intermediate in the synthesis of the anesthetic, isoflurane, CF 3 CHClOCHF 2 .
专利号:US-8999189-B2 优先权日:2010-03-09 标 题 :Ferroelectric fluoride compositions and methods of making and using same 发明人:HALASYAMANI P SHIV; CHANG HONG-YOUNG 权利人:HALASYAMANI P SHIV; CHANG HONG-YOUNG; UNIV HOUSTON SYSTEM 摘要:A method for synthesis of a ferroelectric material characterized by the general formula A x B y F z where A is an alkaline earth metal, B is transition metal or a main group metal, x and y each range from about 1 to about 5, and z ranges from about 1 to about 20 comprising contacting an alkaline earth metal fluoride, a difluorometal compound and a fluoroorganic acid in a medium to form a reaction mixture; and subjecting the reaction mixture to conditions suitable for hydrothermal crystal growth.
专利号:CN-104795537-B 优先权日:2015-04-19 标 题 :A solid phase synthesis of Co2+, Cu2+ doped bismuth fluoride lithium ion battery positive electrode material and its preparation method
专利号:CN-104795539-B 优先权日:2015-04-19 标 题:A liquid-phase synthesis of Cu2+, Fe3+-doped lamellar bismuth fluoride lithium-ion battery cathode material and its preparation method
专利号:CN-104795537-A 优先权日:2015-04-19 标 题 :A solid phase synthesis of Co2+, Cu2+ doped bismuth fluoride lithium ion battery positive electrode material and its preparation method
参考文献:10.1007/s00216-011-5238-2 摘要:Samy S, Robinson J, Hays MD. An advanced LC-MS (Q-TOF) technique for the detection of amino acids in atmospheric aerosols. Analytical and Bioanalytical Chemistry. 2011 Jul 16;401(10):3103–13. doi: 10.1007/s00216-011-5238-2. 参考文献:10.1021/es2001985 摘要:Awad E, Zhang X, Bhavsar SP, Petro S, Crozier PW, Reiner EJ, Fletcher R, Tittlemier SA, Braekevelt E. Long-term environmental fate of perfluorinated compounds after accidental release at Toronto airport. Environ Sci Technol. 2011 Oct 01;45(19):8081–9. doi: 10.1021/es2001985.